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| 1 | Composition and flux of nutrients transport to the Changjiang Estuary显示文摘Based on the results of water sample measurements of nutrient concentrations at th e Datong Station of the Changjiang River from 1998 to 1999, combined w ith historical data of water quality, seasonal variations of nutrient concentrations and nutrient transports are discussed.The following results have been obtained: (1) the fluxes of the nitrate nitrogen, ammonium nitrogen and nitrite nitrogen increased by time-series from 1962 to 1990 , even if runoff volume had a little variation; (2) the concentrations and fluxes of the dissolved inorganic nitrogen (DIN) and dissolved in organic phosphorus (DIP) increased notably with time, but those of the dissolved silicon (DSI) decreased pronouncedly; and (3) the concentration s and fluxes changed synchronously with time between the Datong Station a nd the Changjiang Estuary. | ZHANG Shen,JI Hongbing,YAN Weijin,DUAN Shuiwang(Inst. of Geographic Sciences and Natural Resources Research, Beijing 100101, China) | 2003 | Journal of Geographical Sciences2003，13，1： | 13 |
| 2 | A highly durable catalyst based on CoxMn3-xO4 nanosheets for low-temperature formaldehyde oxidation显示文摘为不稳定的有机化合物(VOC ) 的氧化的划算的催化剂对精力变换应用和环境保护批评。这个过程的主要瓶颈是能氧化的有效、稳定、划算的催化剂的发展在低温度的 HCHO。这里,一致地由锰钴氧化物 nanosheet 数组组成的先进材料在一件碳纺织品上盖住被与帖子退火相结合的一个简单阳极的电极淀积方法成功地制作处理,和罐头直接为 HCHO 作为高效的催化材料被使用消除。得益于增加的表面氧种类和改进氧化还原作用性质,同样准备的锰钴氧化物 nanosheets 为 HCHO 氧化显示出实质地更高的催化活动。催化剂完全在象 100 一样低的温度把 HCHO 变换成公司 2 | Yongchao Huang Kaihang Ye Haibo Li Wenjie Fan FengyiZhao Yuanming Zhang Hongbing Ji | 2016 | Nano Research2016，9，12： | 10 |
| 3 | Carbon and nitrogen isotopes analysis and sources of organic matter in the upper reaches of the Chaobai River near Beijing,China显示文摘The carbon and nitrogen isotopes in the surface sediments,plants,and soil in the upper reaches of the Chaobai River have been researched.The results showed 27.75‰-21.58‰ and 1.32‰-6.74‰ for carbon and nitrogen isotopic ratios in the surface sediments,respectively.The sources of sedimentary organic matter in this area are soil organic matter,aquatic vascular plants,and riverine plankton,respectively,and a significant contributor to sediment in the Chaohe River,the Baihe River,and the Miyun Reservoir areas is soil organic matter.Furthermore,part of sedimentary organic matter in the Miyun Reservoir is attributed to the input from the Chaohe River and the Baihe River,the other is from C4 vegetation growing around individual point stations at the Miyun Reservoir.Compared with the situation in Hebei Province,the contribution of soil organic matter decreased significantly and river plankton and aquatic vascular plants increased significantly in Beijing municipal areas.This study reveals that the source of organic matter has a close relationship with the soil erosion. | LU FengYun LIU ZhuQing JI HongBing | 2013 | Science China Earth Sciences2013，56，2： | 6 |
| 4 | Bi-, Y-Codoped TiO2 for Carbon Dioxide Photocatalytic Reduction to Formic Acid under Visible Light Irradiation显示文摘 | Pengju Du Tongming Su Xuan Luo Xiantai Zhou Zuzeng Qin Hongbing Ji Jianhua Chen | 2018 | Chinese Journal of Chemistry2018，36，6： | 5 |
| 5 | Bevacizumab biosimilar LY01008 compared with bevacizumab(Avastin)as first-line treatment for Chinese patients with unresectable,metastatic,or recurrent non-squamous non-small-cell lung cancer:A multicenter,randomized,double-blinded,phase Ⅲ trial显示文摘Background:Previous studies have demonstrated the preclinical pharmacological and toxicological consistency,and clinical pharmacokinetic equivalence of bevacizumab biosimilar LY01008 with reference bevacizumab(Avastin).This randomized controlled trial aimed to compare the efficacy and safety of LY01008 with Avastin in first-line treatment of Chinese patients with advanced or recurrent non-squamous non-small cell lung cancer(NSCLC).Methods:StageⅢB-ⅣNSCLC patients with evaluable lesions,good physical status,and adequate organ functions from 67 centers across China were randomized in a ratio of 1:1 to receive LY01008 or Avastin 15 mg/kg intravenously in combination with paclitaxel/carboplatin(combined treatment)for 4-6 cycles,followed by maintenance monotherapy with LY01008 until disease progression,intolerable toxicity,or death.The primary endpoint was objective response rate(ORR)in accordance with Response Evaluation Criteria in Solid Tumors(RECIST)version 1.1 confirmed by independent radiological review committees(IRRC).Secondary endpoints included disease control rate(DCR),duration of response(DoR),progression-free survival(PFS),overall survival(OS),and safety.This study was registered in Clinical Trials.gov(NCT03533127).Results:Between December 15^(th),2017,and May 15^(th),2019,a total of 649 patients were randomized to the LY01008(n=324)or Avastin(n=325)group.As of September 25th,2019 for primary endpoint analysis,589 patients received ORR evaluation,with a median number of combined treatment cycles of 5(range 1-6)andmedian duration of treatment of 3.0(range 0.0-5.1)months.ORRof responseevaluable patients in the LY01008 and Avastin groups were 48.5% and 53.0%,respectively.The stratified ORR ratio was 0.91(90%CI 0.80-1.04,within the prespecified equivalence margin of 0.75-1.33).Up to May 15^(th),2020,with a median follow-up of 13.6(range 0.8-28.4)months,no notable differences in DCR,median DoR,median PFS,median OS,and 1-year OS rate were observed between the LY01008 and Avastin groups.There were no clinically meaningful differences in safety and immunogenicity across treatment groups.Conclusions:LY01008 demonstrated similarity to Avastin in terms of efficacy and safety in Chinese patients with advanced or recurrent non-squamous NSCLC.LY01008 combined with paclitaxel/carboplatin is expected to become a new treatment option for unresectable,metastatic,LY01008 and Avastin groups.There were no clinically meaningful differences in safety and immunogenicity across treatment groups.Conclusions:LY01008 demonstrated similarity to Avastin in terms of efficacy and safety in Chinese patients with advanced or recurrent non-squamous NSCLC.LY01008 combined with paclitaxel/carboplatin is expected to become a new treatment option for unresectable,metastatic,or recurrent non-squamous NSCLC patients in the first-line setting. | Yuankai Shi Kaijian Lei Yuming Jia Bingqiang Ni Zhiyong He Minghong Bi Xicheng Wang Jianhua Shi Ming Zhou Qian Sun Guolei Wang Dongji Chen Yongqian Shu Lianke Liu Zhongliang Guo Yong Liu Junquan Yang Ke Wang Ke Xiao LinWu Tienan Yi Debin Sun Mafei Kang Tianjiang Ma Yimin Mao Jinsheng Shi Tiegang Tang Yan Wang Puyuan Xing Dongqing Lv Wangjun Liao Zhiguo Luo Bin Wang Xiaohong Wu Xiaoli Zhu Shuhua Han Qisen Guo Rongyu Liu Zhiwei Lu Jianyong Zhang Jian Fang Changlu Hu Yinghua Ji Guolong Liu Hong Lu Dedong Wu Junhong Zhang Shuyang Zhu Zheng Liu Wensheng Qiu Feng Ye Yan Yu Yanqiu Zhao Qinhong Zheng Jun Chen Zhanyu Pan Yiping Zhang Wenjuan Lian Bo Jiang Bo Qiu Guojun Zhang Hua Zhang Yanju Chen Yuan Chen Hongbing Duan Manxiang Li Shengming Liu Lijun Ma Hongming Pan Xia Yuan Xueli Yuan Yulong Zheng Emei Gao Li Zhao Shumin Wang Can Wu | 2021 | Cancer Communications2021，41，9： | 5 |
| 6 | Cumene Liquid Oxidation to Cumene Hydroperoxide over CuO Nanoparticle with Molecular Oxygen under Mild Condition显示文摘CuO nanoparticle 经由湿化学方法被综合并且被 X 光检查描绘衍射(XRD ) ,氮吸附解吸附作用,和扫描电子显微镜学(SEM ) 。有分子的氧的 cumene 的催化氧化在 CuO nanoparticle 上被学习。催化剂作为与常规方法, CuO/Al2O3,或同类的铜催化剂在可比较的反应条件下面准备的 CuO 相比显示出显著地更高的活动。用在为 7 h 的 358 K 的 0.25 g CuO nanoparticle 催化剂和 0.1 摩尔 cumene 的 cumene 变换, cumene 水疗院过氧化物(CHP ) 收益,和选择分别地是 44.2% , 41.2% 和 93.2% 。催化剂能被再循环。在 6 个再循环的实验以后,催化活动的损失都没被观察。 | Meiying Zhang Lefu Wang Hongbing Ji Bing Wu Xiaoping Zeng | 2007 | Journal of Natural Gas Chemistry2007，16，4： | 4 |
| 7 | Preparation of Ni/bentonite catalyst and its applications in the catalytic hydrogenation of nitrobenzene to aniline显示文摘Ni supported on bentonite was prepared by the impregnation method with different nickel contents, applied to the hydrogenation of nitrobenzene to aniline in a fixed-bed reactor, and it was characterized by X-ray diffraction(XRD), H_2-temperature programmed reduction(H_2-TPR), and X-ray photoelectron spectrometry(XPS). The results showed that Ni/bentonite catalyst with 20 wt% nickel content provided a higher conversion of nitrobenzene and selectivity of aniline compared to other catalysts. Ni O was the precursor of the active component of the catalyst, and the small crystallite size as well as the highly dispersed Ni O on the Ni/bentonite-20 catalyst, contributed to the catalytic performance. The hydrogenation of nitrobenzene was carried out at 300 °C with a H_2 gaseous hourly space velocity of 4800 ml·(g cat)^(-1)·h^(-1)and a nitrobenzene liquid hourly space velocity of4.8 ml·(g cat)^(-1)·h^(-1)over Ni/bentonite-20. A 95.7% nitrobenzene conversion and 98.8% aniline selectivity were obtained. While the nitrobenzene liquid hourly space velocity was 4.8 ml·(g cat)^(-1)·h^(-1), the yield of aniline was more than 95.0% during a 10-hour reaction. | Yuexiu Jiang Xiliang Li Zuzeng Qin Hongbing Ji | 2016 | Chinese Journal of Chemical Engineering2016，24，9： | 4 |
| 8 | U-shaped association between telomere length and esophageal squamous cell carcinoma risk: a case-control study in Chinese population显示文摘在由维持 chromosomal 正直并且阻止染色体的生物变老的一个关键角色结束的 Telomeres 玩熔化。流行病学的研究建议了 telomere 长度的内部个人的差别能影响倾向到多重癌症,但是关于食道的有鳞的房间癌(ESCC ) 的证据仍然是不明确的。几 telomere 在白种人的长度相关的单个核苷酸多型性(TLSNP ) 在染色体宽的协会研究被报导了。然而,在 ESCC 开发的 telomere 长度和 TL-SNPs 的效果是不清楚的。因此,我们进行了盒子控制研究(1045 个 ESCC 案例和 1433 控制) 在中国人口评估在 telomere 长度, TL-SNPs,和 ESCC 风险之间的协会。作为结果, ESCC 案例显示出全面更短的相对 telomere 长度(RTL )( 中部:1.34 ) 比控制(中部:1.50, P < 0.001 ) 。更有趣地,一个明显的非线性的U字形的协会在 RTL 和 ESCC 风险之间被观察( P < 0.001 )与比率(95%信心间隔)等于到 2.40 的机会( 1.843.14 ), 1.36 ( 1.031.79 ), 1.01 ( 0.761.35 ),并且 1.37 ( 1.031.82 )为个人在第一(最短),第二,第三,并且 第5 (最长) quintile 分别地,在是的 第4 quintile 与那些相比引用组。没有重要协会在八报导 TL-SNPs 和 ESCC 危险性之间被观察。这些调查结果建议短或极其长的 telomeres 可以是为在中国人口的 ESCC 的风险因素。 | Jiangbo Du Wenjie Xue Yong Ji Xun Zhu Yayun Gu Meng Zhu Cheng Wang Yong Gao Juncheng Dai Hongxia Ma Yue Jiang Jiaping Chen Zhibin Hu Guangfu Jin Hongbing Shen | 2015 | Frontiers of Medicine2015，9，4： | 4 |
| 9 | Cytochrome P450 Enzyme-Copper Phosphate Hybrid Nano-Flowers with Superior Catalytic Performances for Selective Oxidation of Sulfides显示文摘 | Xiaohui He Long Chen Qian He Huajian Xiao Xiantai Zhou Hongbing Ji | 2017 | Chinese Journal of Chemistry2017，35，5： | 4 |
| 10 | Loopy belief propagation based data association for extended target tracking显示文摘The data association problem of multiple extended target tracking is very challenging because each target may generate multiple measurements.Recently,the belief propagation based multiple target tracking algorithms with high efficiency have been a research focus.Different from the belief propagation based Extended Target tracking based on Belief Propagation(ET-BP)algorithm proposed in our previous work,a new graphical model formulation of data association for multiple extended target tracking is proposed in this paper.The proposed formulation can be solved by the Loopy Belief Propagation(LBP)algorithm.Furthermore,the simplified measurement set in the ET-BP algorithm is modified to improve tracking accuracy.Finally,experiment results show that the proposed algorithm has better performance than the ET-BP and joint probabilistic data association based on the simplified measurement set algorithms in terms of accuracy and efficiency.Additionally,the convergence of the proposed algorithm is verified in the simulations. | Zhenzhen SU Hongbing JI Yongquan ZHANG | 2020 | Chinese Journal of Aeronautics2020，33，8： | 3 |
| 11 | The first finding of superhigh concentration of REE-rich bed in carbonate rock weathering crusts and its siginificance显示文摘THE Pingba soil profile developed on the bedrock Triassic dolomitite and morphologically located in uplandin karst terrain in Central Guizhou, China was proven to be in-situ dolomitite weathering pedogeneticproduct. Continuous sampling method was used for taking samples from man-made excavated pit fromthe Pingba profile. REE for samples was measured on ELEMENT ICP-MS in the Institute of Geochemistry, CAS. The standard reference samples GSR-6 and GSS-1,4,7 were used to monitor the precisionof REE measurement. The measurement error was less than ≤10%. For PB-T1 sample, the coefficientof variation (CV) of three analytical run precision is: La, Ce, Pr, Nd, Ho, Er≤10%; Sm, Eu, Dy,Tm≤15%; Y, Lu, Gd, Tb≤20%. | JI Hongbing, WANG Shijie, ZHOU Dequan, OUYANG Ziyuan and SUN Chengxing State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, China | 1999 | Chinese Science Bulletin1999，44，S2： | 3 |
| 12 | Ni/bentonite catalysts prepared by solution combustion method for CO_2 methanation显示文摘A 20 wt% Ni/bentonite catalyst was prepared by a solution combustion synthesis (SCS), which exhibited higher activity for the CO_2methanation than that of an impregnation method (IPM), and the catalyst prepared by SCS showed a CO_2 conversion of 85% and a CH4selectivity of 100% at 300 °C, atmospheric pressure, and 3600 ml·(g cat)-1·h-1, and the catalyst exhibited stable within a 110-h reaction. The results showed higher me- tallic Ni dispersion, smaller Ni particle size, larger specific surface area and lower reduction temperature in the Ni/ bentonite prepared by SCS than that of IPM. And the Ni/bentonite prepared by the SCS moderated the interaction between NiO and bentonite. | Yuexiu Jiang Tongxia Huang Lihui Dong Zuzeng Qin Hongbing Ji | 2018 | Chinese Journal of Chemical Engineering2018，26，11： | 3 |
| 13 | Tannic Acid as a Polyphenol Material-Assisted Synthesis of Cyclic Carbonates Using CO2 as a Feedstock: Kinetic Characteristic and Mechanism Studies显示文摘 | Rongchang Luo Wuying Zhang Xiantai Zhou Hongbing Ji | 2017 | Chinese Journal of Chemistry2017，35，5： | 3 |
| 14 | Mechanically activated starch magnetic microspheres for Cd(Ⅱ)adsorption from aqueous solution显示文摘Magnetic starch microspheres(AAM-MSM)were synthesized via an inverse emulsion graft copolymerization by using mechanically activated cassava starch(MS)as a crude material,acrylic acid(AA)and acrylamide(AM)as graft copolymer monomers,and methyl methacrylate(MMA)as the dispersing agent and used as an adsorbent for the removal of Cd(Ⅱ)ions from aqueous solution.Fourier-transform infrared spectroscopy(FT-IR),X-ray photoelectron spectroscopy(XPS),scanning electron microscopy(SEM),and vibrating sample magnetometry(VSM)were used to characterize the AAM-MSM adsorbent.The results indicated that AA,AM,and MMA were grafted to the MS,and the Fe_(3)O_(4) nanoparticles were encapsulated in the AAM-MSM adsorbent microspheres.The adsorbent exhibited a smooth surface,uniform size,and good sphericity because of the addition of the MMA and provided more adsorption sites for the Cd(Ⅱ)ions.The maximum adsorption capacity of Cd(Ⅱ)on the AAM-MSM was 39.98 mg·g^(-1).The adsorbents were superparamagnetic,and the saturation magnetization was 16.7 A·m^(2)·kg^(-1).Additionally,the adsorption isotherms and kinetics of the adsorption process were further investigated.The process of Cd(Ⅱ)ions adsorbed onto the AAM-MSM could be described more favorably by the pseudo-second-order kinetic and Langmuir isothermal adsorption models,which suggested that the chemical reaction process dominated the adsorption process for the Cd(Ⅱ)and chemisorption was the rate-controlling step during the Cd(Ⅱ)removal process. | Xinling Xie Xiaona Zhao Xuan Luo Tongming Su Youquan Zhang Zuzeng Qin Hongbing Ji | 2021 | Chinese Journal of Chemical Engineering2021，34，5： | 3 |
| 15 | Recyclable bifunctional aluminum salen catalyst for CO2 fixation:the efficient formation of five-membered heterocyclic compounds显示文摘A variety of unique Al(salen) complexes functionalized by imidazolium-based ionic liquid(IL) moieties with the salen ligand at the two sides of 3,3′-position have been successfully prepared, rather than familiar 5,5′-position reported previously.The catalytic activity obtained by these bifunctional catalysts could be superior to those of the binary type catalysts in the formation of five-membered heterocyclic compounds from the cycloaddition reaction of CO_2 and three-membered heterocyclic compounds(including terminal epoxides and N-substituted aziridines), presumably due to the distinguished intramolecularly synergistic catalysis, which might lead to perform the cycloaddition reaction at ambient conditions and retain excellent yield and unprecedented chemo-or regioselectivity. Moreover, the polyether-based trifunctional Al(salen) catalysts with the best catalytic performance could be regenerated and reused at least eight times without any obvious decreases in catalytic activity. Finally,the kinetic investigation suggested the structure of catalysts had important influences on the catalytic activity, thereby proposing the possible reaction mechanism. | Rongchang Luo Zhi Yang Wuying Zhang Xiantai Zhou Hongbing Ji | 2017 | Science China Chemistry2017，60，7： | 2 |
| 16 | Kinetics, thermodynamics, and equilibrium of As(Ⅲ),Cd(Ⅱ), Cu(Ⅱ) and Pb(Ⅱ) adsorption using porous chitosan bead-supported MnFe_(2)O_(4) nanoparticles显示文摘A novel porous nanocomposite,cross-linked chitosan and polyethylene glycol(PEG) bead-supported MnFe_(2) O_(4) nanoparticles(CPM),was developed as an efficient adsorbent to remove metalloid(As(Ⅲ))and heavy metals(Cd(Ⅱ),Cu(Ⅱ),and Pb(Ⅱ)).The characteristics of CPM showed a porous structure,well dispersed MnFe_(2) O_(4),and several of hydroxyl and amino groups(-OH,-NH_(2)).Batch experiments demonstrated that the best adsorption property of As(Ⅲ),Cd(Ⅱ),Cu(Ⅱ),and Pb(Ⅱ) was achieved within 8 h with maximum adsorption capacities of 9.90,9.73,43.94,and 11.98 mg/g,respectively.Competitive and synergistic effects(particularly precipitation) were included in the co-adsorption mechanism of As(Ⅲ) and heavy metals.Thereinto,As(Ⅲ) was partly oxidized by MnFe_(2) O_(4) to As(V),and both were coordinated on MnFe_(2) O_(4) nanoparticles.Pb(Ⅱ) could also bind to MnFe_(2) O_(4) by ion exchange and electrostatic attraction.Furthermore,Cd(Ⅱ) and Cu(Ⅱ) tended to be coordinated on chitosan.Therefore,CPM can serve as a remediation material for water and soil co-contaminated with As(Ⅲ) and heavy metals. | Hongxia Li Hongbing Ji Xinglan Cui Xiaokui Che Qidong Zhang Juan Zhong Rongzhen Jin Lei Wang Yi Luo | 2021 | International Journal of Mining Science and Technology2021，31，6： | 2 |
| 17 | Quasi-continuous synthesis of cobalt single atom catalysts for transfer hydrogenation of quinoline显示文摘Improving the transfer hydrogenation of N-heteroarenes is of key importance for various industrial pro-cesses and remains a challenge so far.We reported here a microcapsule-pyrolysis strategy to quasi-continuous synthesis S,N co-doped carbon supported Co single atom catalysts(Co/SNC),which was used for transfer hydrogenation of quinoline with formic acid as the hydrogen donor.Given the unique ge-ometric and electronic properties of the Co single atoms,the excellent catalytic activity,selectivity and stability were observed.Benefiting from the quasi-continuous synthesis method,the as-obtained cata-lysts provide a reference for the large-scale preparation of single atom catalysts without amplification ef-fect.Highly catalytic performances and quasi-continuous preparation process,demonstrating a new and promising approach to rational design of atomically dispersed catalysts with maximum atomic efficiency in industrial. | Liyun Huang Hao Zhang Yujie Cheng Qingdi Sun Tao Gan Qian He Xiaohui He Hongbing Ji | 2022 | Chinese Chemical Letters2022，33，5： | 2 |
| 18 | Single Cu atom dispersed on S,N-codoped nanocarbon derived from shrimp shells for highly-efficient oxygen reduction reaction显示文摘Recently,Cu-based single-atom catalysts(SACs)have garnered increasing attention as substitutes for platinum-based catalysts in the oxygen reduction reaction(ORR).Therefore,a facile,economical,and efficient synthetic methodology for the preparation of a high-performance Cu-based SAC electrocatalyst for the ORR is extremely desired,but is also significantly challenging.In this study,we propose a ball-milling method to synthesize isolated metal SACs embedded in S,N-codoped nanocarbon(MNSDC,M=Cu,Fe,Co,Ni,Mn,Pt,and Pd).In particular,the Cu-NSDC SACs exhibit high electrochemical activity for the ORR with half-wave potential(E_(1/2))of 0.84 V(vs.reversible hydrogen electrode(RHE),20 mV higher than Pt/C)in alkaline electrolyte,excellent stability,and electrocatalytic selectivity.Density functional theory(DFT)calculations demonstrated that the desorption of OH*intermediates was the rate-determining step over Cu-NSDC.This study creates a pathway for high-performance ORR single atomic electrocatalysts for fuel cell applications and provides opportunities to convert biowaste materials into commercial opportunities. | Hao Zhang Qingdi Sun Qian He Ying Zhang Xiaohui He Tao Gan Hongbing Ji | 2022 | Nano Research2022，15，7： | 2 |
| 19 | Improved Parameter Estimation for Chirp Signals Based on Cyclostationarity显示文摘 | JIN Yan JI Hongbing | 2008 | Chinese Journal of Electronics2008，17，2： | 2 |
| 20 | Influence of Zr, Ce, and La on Co_3O_4 catalyst for CO_2 methanation at low temperature显示文摘The Co_3O_4 and Zr-,Ce-,and La-Co_3O_4 catalysts were prepared,characterized,and applied to produce CH_4 from CO_2 catalytic hydrogenation in low temperature as 140–220°C.The results indicated that the addition of Zr,Ce,or La to the Co_3O_4 decreased the crystallite sizes of Co and the outer-shell electron density of Co^(3+),and increased the specific surface area,which would provide more active sites for the CO_2 methanation.Especially,the addition of Zr also changed the reducing state of Co_3O_4 via an obvious change in the interaction between Co_3O_4 and ZrO_2.Furthermore,Zr doped into the Co_3O_4 increased the basic intensity of the weak and medium basic sites,as well as the amount of Lewis acid sites,and Br?nsted acid sites were also found on the Zr-Co_3O_4 surface.The introduction of Zr,Ce,or La favored the production of CH_4,and the Zr-Co_3O_4catalyst exhibited the highest CO_2 conversion(58.2%)and CH_4 selectivity(100%)at 200°C,and 0.5 MPa with a gaseous hourly space velocity of 18,000 ml·g^(-1)_(cat)·h^(-1),and the catalytic activity of CO_2methanation for the Zr-,Ce-,and La-Co_3O_4 exhibited more stable than Co_3O_4 in a 20-h reaction. | Yuwen Zhou Yuexiu Jiang Zuzeng Qin Qinruo Xie Hongbing Ji | 2018 | Chinese Journal of Chemical Engineering2018，26，4： | 2 |
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