|
|
|
题名
|
作者
|
年代
|
出处
|
被引量
|
| 1 | Preparation and anisotropic thermophysical properties of SiC honeycomb/Al-Mg-Si composite via spontaneous infiltration显示文摘The SiC honeycomb/Al-Mg-Si composite with interpenetrated microstructure was prepared by spontaneous infiltration of Al-8 wt%Mg-7 wt%Si alloy into directional porous SiC honeycomb served as reinforcement. The microstructure and anisotropic thermophysical properties of this composite were also examined. The results showed that the initial microstructure of the SiC honeycomb can be retained and the as-prepared SiC honeycomb/Al-Mg-Si composite exhibited significantly anisotropic characteristics. Meanwhile, the alloying treatment on the Al matrix can avoid the generation of Al4C3 and promote the wettability between Al and SiC.Particularly,the directional porous SiC honeycomb with such a low ceramic content(19 vol.%) made it possible for the composite to have a higher thermal conductivity(138.3 W/(m?K)) in the axial direction and a lower coefficient of thermal expansion(11.40 × 10^-6/K) in the radial direction.The influences of the SiC honeycomb reinforcement on the anisotropic thermophysical properties were also studied by the theoretical models in comparing with the experimental results. | Zhejian Zhang Zhongqi Shi Biguo Yang Bangzhi Ge Xiaoyu Zhang Yajie Guo | 2019 | Progress in Natural Science:Materials International2019，29，2： | 3 |
| 2 | Influences of 1-methylcyclopropene-containing papers on the metabolisms of membrane lipids in Anxi persimmons during storage显示文摘Objectives:The aim of this work was to analyse the effects of 1-methylcyclopropene(1-MCP)treatment on the metabolisms of membrane lipids in postharvest Anxi persimmons during storage.Materials and methods:Anxi persimmon(Diospyros kaki L.f.cv.Anxi)fruits were treated by paper containing 1-MCP with a concentration of 1.35μl/l.The cellular membrane permeability was analysed by the electric conductivity meter.The activities of lipoxygenase(LOX),phospholipase(PLD)and lipase were determined by spectrophotometry.The component and relative amounts of membrane fatty acids were determined using gas chromatograph(GC).Results:The 1-MCP-treated Anxi persimmons manifested a lower electrolyte leakage rate,lower LOX,PLD and lipase activities,higher levels of unsaturated fatty acids(USFAs),higher ratio of USFAs to saturated fatty acids(SFAs)(U/S),higher index of USFAs(IUFA),but lower levels of SFAs.Conclusions:The degradation and the metabolisms of membrane lipids could be suppressed by 1-MCP treatment,which might be accountable for the delaying softening of postharvest Anxi persimmons during storage. | Hui Wang Guo Chen Lili Shi Hetong Lin Yihui Chen Yifen Lin Zhongqi Fan | 2020 | Food Quality and Safety2020，4，3： | 2 |
| 3 | Synthesis of nearly spherical AlN particles by an in-situ nitriding combustion route显示文摘Spherical AlN powders with micrometer size have attracted great attention owing to their good fluidity and dispersity. However, the industrial preparation methods usually require high temperature and long soaking time, which lead to the high cost and limit the wide application of the products. Herein, nearly spherical AlN particles with the average size of 2.5 μm were successfully synthesized via an in-situ combustion synthesis method. The effect of N_(2) pressure, NH_(4)Cl content, and Al particle size on the combustion reaction procedure, phase composition, and microstructure of the products was systematically investigated. The results showed that the decreased N_(2) pressure, increased NH_(4)Cl content, and Al particle size led to the decreasing of combustion temperature and speed, which further affected the morphology of the products. As a result, low N_(2) pressure(0.2 MPa), a small amount of NH4Cl(0.5 wt%), and fine Al particles(~2.5 μm) contributed to a moderate combustion temperature and facilitated the formation of nearly spherical AlN particles. In addition, based on the gas-releasing assisted quenching experiments and thermo-kinetic analysis, a two-step growth mechanism for the nearly spherical AlN particles was rationally proposed. The present method shows the advantages of low cost and high efficiency for preparing nearly spherical AlN particles, which can be used as raw materials for electronic substrates and fillers for packaging materials. | Zhilei Wei Kang Li Bangzhi Ge Chaowei Guo Hongyan Xia Yajie Guo Zhongqi Shi | 2021 | Journal of Advanced Ceramics2021，10，2： | 2 |
| 4 | Synthesis of LiFePO4/C cathode material from ferric oxide and organic lithium salts 显示文摘 | Shi Zhongqi Huang Ming Huai Yongjian | 2011 | Eleetrochim Acta2011，56，11： | 1 |
| 5 | Influence of Climate on Soil Organic Carbon in Chinese Paddy Soils显示文摘Soil organic carbon(SOC) is a major component of the global carbon cycle and has a potentially large impact on the greenhouse effect. Paddy soils are important agricultural soils worldwide, especially in Asia. Thus, a better understanding of the relationship between SOC of paddy soils and climate variables is crucial to a robust understanding of the potential effect of climate change on the global carbon cycle. A soil profile data set(n = 1490) from the Second National Soil Survey of China conducted from 1979 to 1994 was used to explore the relationships of SOC density with mean annual temperature(MAT) and mean annual precipitation(MAP) in six soil regions and eight paddy soil subgroups. Results showed that SOC density of paddy soils was negatively correlated with MAT and positively correlated with MAP(P < 0.01). The relationships of SOC density with MAT and MAP were weak and varied among the six soil regions and eight paddy soil subgroups. A preliminary assessment of the response of SOC in Chinese paddy soils to climate indicated that climate could lead to a 13% SOC loss from paddy soils. Compared to other soil regions, paddy soils in Northern China will potentially more sensitive to climate change over the next several decades. Paddy soils in Middle and Lower Yangtze River Basin could be a potential carbon sink. Reducing the climate impact on paddy soil SOC will mitigate the positive feedback loop between SOC release and global climate change. | WANG Dandan YAN Yechao LI Xinhui SHI Xuezheng ZHANG Zhongqi David C WEINDORF WANG Hongjie XU Shengxiang | 2017 | Chinese Geographical Science2017，27，3： | 1 |
| 6 | Effects of weak boundary phases (WBP) on the microstructure and mechanical properties of pressureless sintered Al2O3/h-BN machinable composites 显示文摘 | SHI Zhongqi WANG Jiping QIAO Guanjun | 2008 | Mater Sci EngA2008，492，： | 1 |
| 7 | Preparation of Eu 2+ -doped AlN phosphors by plasma activated sintering显示文摘 | Zhongqi Shi Wanli Yang Shujie Bai Guanjun Qiao Zhihao Jin | 2011 | Ceramics International2011，，6： | 1 |
| 8 | Sliding wear behavior of mesocarbon microbeads based carbon materials显示文摘 | Hongyan Xia Jiping Wang Zhongqi Shi Guiwu Liu Guanjun Qiao | 2011 | Wear2011，，： | 1 |
| 9 | Preparation of unidirectional porous AlN ceramics via the combination of freeze casting and combustion synthesis显示文摘Unidirectional porous AlN ceramics(UP-AlNs)have attracted great attention for their wide applications in catalyst supports,filters and composite reinforcements.However,traditional fabrication processes usually require high temperature and long production cycle.Herein,UP-AlNs were successfully fabricated via the combination of tertiary butyl alcohol(TBA)-based freeze casting and combustion synthesis route using Al and AlN powders as raw materials.The microstructure,open porosity,thermal conductivity and compressive strength of UP-AlNs can be manipulated by synergistically regulating the AlN diluent content and Al/AlN solid loading of the freezing slurries.The optimal UP-AlNs exhibited controllable structure wavelength(λ)and open porosity in a wide range of 21.1-47.1μm and 54.2%-86.0%,respectively.In addition,the corresponding products also possessed anisotropic thermal conductivity and compressive strength.This novel route for the fabrication of UP-AlNs has the advantages of low cost,energy-saving and high efficiency,which shows significant promise for industrial applications. | Zhilei Wei Zhejian Zhang Xiaoyu Zhang Zhiyuan Li Tao Li Jiabin Hu Shunjian Xu Zhongqi Shi | 2022 | Journal of Materials Science & Technology2022，，5： | 1 |
| 10 | Preparation and Application Progress of Porous Alumina显示文摘Porous alumina ceramics are widely used in various fields because of their unique characteristics in structure and properties.This article mainly provided an overview of preparation techniques of porous alumina ceramics;besides,the principles and the characteristics of pore-forming agents processes,gel-casting processes,freeze-casting processes,anodizing processes and other common processes in obtaining the required properties of porous alumina ceramics were introduced.Meanwhile,the relevant applications and the performance of porous alumina ceramics were described.The research prospects of porous alumina ceramics were put forward based on the research status at the end of this paper. | WANG Tao WANG Bo HOU Baoqiang SHI Zhongqi YANG Jun XIA Hongyan WANG Jiping WANG Hongjie YANG Jianfeng | 2020 | China's Refractories2020，29，4： | 1 |
| 11 | Reactive consolidation of layered-ternary Ti2A1N ceramics by spark plasma sintering of a Ti/AlN powder mixture显示文摘 | LIU Yi SHI Zhongqi WANG Jiping | 2011 | J Euro Ceram Soc2011，31，5： | 1 |
| 12 | Preparation of SiC coated graphite composite powders by nitriding combustion synthesis显示文摘Ceramic-coated graphite powders are considered as effective raw materials to fabricate three-dimensional continuous ceramic skeleton-reinforced graphite matrix composites which can overcome their inherent poor densification and improve their mechanical and antioxidation properties.However,the morphology and thickness regulation of ceramic coatings on graphite particles are still a great challenge.Herein,SiC-coated graphite(graphite@SiC)powders were prepared by nitriding combustion synthesis using Si and graphited mesocarbon microbead(MCMB)as raw powders with polytetrafluoroethylene(PTFE)as a promoter.The effects of the PTFE content and the Si/MCMB molar ratio on the phase composition and coating morphology were investigated.The phase transition and microstructure evolution of a combustion synthesis(CS)process were revealed by a gas-released quenching experiment.When the Si/MCMB molar ratio was 1:3 and the PTFE content was 10 wt%,the thickness of the SiC coating synthesized under 2 MPa N_(2)reached 1.14μm.The corresponding sintered graphite@SiC composite had relative density of 99.2%and flexural strength of 231 MPa,accompanied by a significant improvement in high-temperature antioxidation properties.The as-synthesized graphite@SiC powders with good sinterability and antioxidation properties show great promise for applications in the nuclear industry and other extreme fields. | Biao Zhang Wenqi Xie Huaizhi Lin Zhilei Wei Zhichao Xiao Kai He Zhongqi Shi | 2023 | Journal of Advanced Ceramics2023，12，10： | 0 |
| 13 | Enrichment of nervonic acid in Acer truncatum Bunge oil by combination of two-stage molecular distillation,one-stage urea complexation and five-stage solvent crystallization显示文摘Nervonic acid is the world’s first and only potent substance that can repair damaged nerve fibers and promote nerve cell regeneration with high nutritional value.The wide variety of fatty acids in plant oils and fats with similar structures makes the large-scale separation and purification of high-purity nervonic acid very difficult.A new combined process of molecular distillation,urea inclusion and solvent crystallization was established to prepare high-purity nervonic acid with the mixed fatty acids obtained after saponification and acidification of Acer truncatum Bunge oil as raw materials.First,according to the difference in the mean free path of fatty acids,molecular distillation was used to separate and remove C16 saturated fatty acid of palmitic acid and four C18-C20 fatty acids of stearic,oleic,linoleic,and linolenic acids.The content of C16-C20 fatty acids decreased from 72.92% to 19.22% after two-stage molecular distillation processes,in which the contents of saturated fatty acid of palmitic acid decreased to about 0.5%.Then,according to the difference in carbon chain length and saturation of fatty acid,the contents of C22-C24 saturated fatty acids of tetracosanoic and docosanoic acids decreased to 0.21% and 0.07% by urea inclusion with urea/free fatty acid preparation by saponification(SPOMFs)ratio as 0.6.In addition,all saturated fatty acids were basically separated.Finally,according to the difference in the solubility of fatty acids in solvents,the C18-C20 unsaturated fatty acids of oleic,linoleic,and linolenic acids and C22 unsaturated fatty acid of erucic acid were removed by solvent crystallization.The content of C18-C20 unsaturated fatty acids decreased to less than 5% with pentanol as the solvent after the first stage solvent crystallization.The content of erucic acid decreased to 3.47% with anhydrous ethanol as the solvent after the second to fifth stage solvent crystallization.The combined process of molecular distillation,urea inclusion and low temperature crystallization innovatively adopted an efficient,simple and easy-toindustrial solvent crystallization method to separate erucic and nervonic acids,obtaining nervonic acid with purity of 96.53% and final yield of 47.99%. | Yingxi Gao Jiayi Shi Jie Wang Fan Zhang Shichao Tian Zhiyong Zhou Zhongqi Ren | 2023 | Chinese Journal of Chemical Engineering2023，59，7： | 0 |
| 14 | Spatial confinement effects of laser-induced breakdown spectroscopy at reduced air pressures显示文摘Spatial confinement is a simple and cost-effective method for enhancing signal intensity and improving the detection sensitivity of laser-induced breakdown spectroscopy(LIBS).However,the spatial confinement effects of LIBS under different pressures remains a question to be studied,because the pressure of the ambient gas has a significant influence on the temporal and spatial evolution of plasma.In this study,spatial confinement effects of LIBS under a series of reduced air pressures were investigated experimentally,and the plasma characteristics under different air pressures were studied.The results show that the reduced air pressure can lead to both earlier onset and weakening of the enhancement effect of the spatial confinement on the LIBS line intensity.When the air pressure drops to 0.1 kPa,the enhancement effect of the emission intensity no longer comes from the compression of the reflected shock wave on the plasma,but from the cavity’s restriction of the plasma expansion space.In conclusion,the enhancement effect of spatial confinement technology on the LIBS is still effective when the pressure is reduced,which further expands the research and application field of spatial confinement technology. | Zhongqi Hao Zhiwei Deng Li Liu Jiulin Shi Xingdao He | 2022 | Frontiers of Optoelectronics2022，15，2： | 0 |
| 15 | Continuous SiC skeleton reinforced highly oriented graphite flake composites with high strength and specific thermal conductivity显示文摘Highly oriented graphite-based composites have attracted great attention because of their high thermal conductivity(TC),but the low mechanical properties caused by the inhomogeneous distribution and discontinuity of reinforcements restrict the wide applications.Herein,continuous SiC ceramic skeleton reinforced highly oriented graphite flake(SiC/GF)composites were successfully prepared by combining vacuum filtration and spark plasma sintering.The effect of SiC concentration on the microstructure,flexural strength,and thermophysical properties of the composites was investigated.The GF grains in the composites exhibited high orientation with a Lotgering factor of>88%when the SiC concentration was≤30 wt%,and the SiC skeleton became continuous with the SiC concentration reaching 20 wt%.The formation of continuous SiC skeleton improved the flexural strength of the composites effectively while keeping the TC in a high level.Especially,the composites with 30 wt%SiC exhibited the flexural strength up to 105 MPa,and the specific TC reaching 0.118 W·m^(2)·K^(−1)·kg-1.The composites with excellent flexural strength and thermophysical properties showed significant promise for thermal management applications. | Xiaoyu ZHANG Wenqi XIE Lan SUN Zhilei WEI Zhejian ZHANG Yuanyuan ZHU Jiabin HU Shenghe WANG Zhongqi SHI | 2022 | Journal of Advanced Ceramics2022，11，3： | 0 |
| 16 | Anisotropic, biomorphic cellular Si_(3)N_(4) ceramics with directional well-aligned nanowhisker arrays based on wood-mimetic architectures显示文摘Inspired by the transport behavior of water and ions through the aligned channels in trees,we demonstrate a facile,scalable approach for constructing biomorphic cellular Si_(3)N_(4) ceramic frameworks with well-aligned nanowhisker arrays on the surface of directionally aligned microchannel alignments.Through a facile Y(NO_(3))_(3) solution infiltration into wood-derived carbon preforms and subsequent heat treatment,we can faultlessly duplicate the anisotropic wood architectures into free-standing bulk porous Si_(3)N_(4) ceramics.Firstly,α-Si3N4 microchannels were synthesized on the surface of CB-templates via carbothermal reduction nitridation(CRN).And then,homogeneous distributed Y–Si–O–N liquid phase on the walls of microchannel facilitated the anisotropicβ-Si3N4 grain growth to form nanowhisker arrays.The dense aligned microchannels with low-tortuosity enable excellent load carrying capacity and thermal conduction through the entire materials.As a result,the porous Si_(3)N_(4) ceramics exhibited an outstanding thermal conductivity(TC,k_(R)≈6.26 W·m^(−1)·K^(−1)),a superior flexural strength(σ_(L)≈29.4 MPa),and a relative high anisotropic ratio of TC(k_(R)/k_(L)=4.1).The orientation dependence of the microstructure–property relations may offer a promising perspective for the fabrication of multifunctional ceramics. | Songsong XU Xiaonan ZHOU Qiang ZHI Junjie GAO Liucheng HAO Zhongqi SHI Bo WANG Jianfeng YANG Kozo ISHIZAKI | 2022 | Journal of Advanced Ceramics2022，11，4： | 0 |
| 17 | Enhanced figure of merit for famatinite Cu_(3)SbSe_(4)via band structure tuning and hierarchical architecture显示文摘The p-type Te-free Cu_(3)SbSe_(4)with famatinite structure is a potential candidate for thermoelectric materials due to the low cost and eco-friendly constituent elements.However,its strong bipolar effect and high lattice thermal conductivity(klat)are the main challenges for its performance enhancement.Herein,we report a new strategy to enhance its figure of merit zT~0.86 at 673 K for Cu_(3)Sb_(0.95)Fe_(0.05)Se_(2.8)S_(1.2)via band structure tuning and hierarchical architecture.Firstly,S substituted Se atoms in lattice can widen the band gap to alleviate the bipolar effect.Secondly,Fe doping in Sb site significantly increases the density of states,thus increasing the carrier effective mass,and obtaining a remarkably high Seebeck coefficient of~560 mV/K at 300 K.Moreover,the induced hierarchical architecture defects resulting in a minimum klat of~0.48 W·m^(-1)·K^(-1)at 673 K.Consequently,the improved Seebeck coefficient combined with low thermal conductivity leads to an enhanced zT. | Lijun Zhao Haolin Ye Xinmeng Wu Jian Yang Lihua Yu Zhongqi Shi Shahid Hussain Guanjun Qiao Junhua Xu Bangzhi Ge Li Wang Chongjian Zhou | 2023 | Journal of Materiomics2023，9，6： | 0 |
您所在的机构暂未开通此部分的功能，请联系管理员