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| 1 | Metal organic frameworks derived single atom catalysts for electrocatalytic energy conversion显示文摘The development of efficient and cost-effective catalysts to catalyze a wide variety of electrochemical reactions is key to realize the large-scale applicati on of ren ewable and clean en ergy tech no logies.Owing to the maximum atom-utilization efficie ncy and unique electronic and geometric structures,single atom catalysts(SACs)have exhibited superior performance in various catalytic systems.Recently,assembled from the function alized orga nic lin kers and metal no des,metal-organic frameworks(MOFs)with ultrafi ne porosity have received treme ndous attention as precursors or self-sacrificing templates for preparing porous SACs.Here,the recent advances toward the synthesis strategies for using MOF precursors/templates to con struct SACs are systematically summarized with special emphasis on the types of central metal sites.The electrochemical applications of these recently emerged MOF-derived SACs for various energy-conversion processes,such as oxygen reduction/evolution reaction(ORR/OER),hydrogen evolution reaction(HER),and CO2 reduction reaction(CO2RR),are also discussed and reviewed.Fin ally,the curre nt challe nges and prospects regardi ng the developme nt of MOF-derived SACs are proposed. | Tingting Sun Lianbin Xu Dingsheng Wang Yadong Li | 2019 | Nano Research2019，12，9： | 63 |
| 2 | Modulating the local coordination environment of single-atom catalysts for enhanced catalytic performance显示文摘The local coordination environment of catalysts has been investigated ftor an extended period to obtain enhanced catalytic performance.Especially with the advancement of single-atom catalysts(SACs),research on the coordination environment has been advanced to the atomic level.The surrounding coordination atoms of central metal atoms play important roles in their catalytic activity,selectivity and stability.In recent years,remarkable improvements of the catalytic performance of SACs have been achieved by the tailoring of coordination atoms,coordination numbers and second-or higher-coordination shells,which provided new opportunities for the further development of SACs.In this review,the characterization of coordination environment,tailoring of the local coordination environment,and their related adjustable catalytic performance will be discussed.We hope this review will provide new insights on further research of SACs. | Xinyuan Li Hongpan Rong Jiatao Zhang Dingsheng Wang Yadong Li | 2020 | Nano Research2020，13，7： | 70 |
| 3 | Single-atom catalysis enables long-life, high-energy lithium-sulfur batteries显示文摘With high energy density and low material cost,lithium sulfur batteries(LSBs)emerge quite expeditiously as a fascinating energy storage system over the past decade.Broad applications of LSBs ranging from electric vehicles to stationary grid storage seem rather bright in recent literatures.However,there still exist many pressing challenges to be addressed because we do not yet fully understand and control the electrode-electrolyte interface chemistries during battery operation,such as polysulide shuttling and poor utilization of active sulfur.Single-atom catalysts(SACs)pave new possibilities of tackling the tough issues due to their decent applicability in the atomic-level identification of structure-activity relationships and reaction mechanism,as well as their structural tunability with atomic precision.This review comprehensively summarizes the very recent advances in utilization of highly active SACs for LSBs by stating and discussing the related publications,which involves catalyst synthesis routes,battery pertormance,catalytic mechanisms,optimization strategies,and promises to achieve long-lite,high-energy LSBs.We see that endeavors to employ SACs to modify sulfur cathode have allowed efficient polysulfide conversion and confinement,leading to the minimization of shuttle effect.Parallel efforts are being devoted to extending the scope of SACs to cell separator and lithium metal anode in order to unlock the full potential of LSBs.We also obtain mechanistic insights into battery chemistries and nature of SACs in their strong interactions with polysulfides through advanced in situ characterizations documented.Overall,acceleration in the development of LSBs by introducing SACs is noticeable,and this cutting edge needs more attentions to further promoting the design of better LSBs. | Zechao Zhuang Qi Kang Dingsheng Wang Yadong Li | 2020 | Nano Research2020，13，7： | 46 |
| 4 | Single-atom site catalysts for environmental catalysis显示文摘In recent decades,the environmental protection and long-term sustainability have become the focus of attention due to the increasing pollution generated by the intense industrialization.To overcome these issues,environmental catalysis has increasingly been used to solve the negative impact of pollutants emission on the global environment and human health.Supported platinum-metal-group(PGM)materials are commonly utilized as the state-of-the-art catalysts to eliminate gaseous pollutants but large quantities of PGMs are required.By comparison,single-atom site catalysts(SACs)have attracted much attention in catalysis owing to their 100%atom efficiency and unique catalytic performances towards various reactions.Over the past decade,we have witnessed burgeoning interests of SACs in heterogeneous catalysis.However,to the best of our knowledge,the systematic summary and analysis of SACs in catalytic elimination of environmental pollutants has not yet been reported.In this paper,we summarize and discuss the environmental catalysis applications of SACs.Particular focus was paid to automotive and stationary emission control,including model reaction(CO oxidation,NO reduction and hydrocarbon oxidation),overall reaction(three-way catalytic and diesel oxidation reaction),elimination of volatile organic compounds(formaldehyde,benzene,and toluene),and removal/decomposition of other pollutants(Hg0 and SO3).Perspectives related to further challenges,directions and design strategies of single-atom site catalysts in environmental catalysis were also provided. | Ningqiang Zhang Chenliang Ye Han Yan Lingcong Li Hong He Dingsheng Wang Yadong Li | 2020 | Nano Research2020，13，12： | 38 |
| 5 | Early Paleozoic granite in Nujiang River of northwest Yunnan in southwestern China and its tectonic implications显示文摘沿着在西方的云南的中国缅甸边阶的 Nujiang 区域收到了很多注意并且被认为是西藏的高原的向东南的逃跑的重要隧道。这条隧道被红 River-Ailao 山左文字的 strick 滑倒差错在这条隧道以内在西方在东方和英雄传奇 Gaoligong 正确文字的 strick 滑倒差错毗邻,它仍然不对贡尚·布洛克哪个构造单位合适清楚。尽管一些研究人员建议它是 Sundaland 岩层的北方结束,它的构造定义是相当模糊的。这篇论文报导我们 U-Pb 同位素的 geochronological 在贡尚·布洛克以内在 Gudang 片麻岩的花岗石上学习的新锆石。这研究在理解起源和西北的云南的构造环境起一个重要作用。 | SONG ShuGuang JI JianQing WEI ChunJing SU Li ZHENG YaDong SONG Biao ZHANG LiFei | 2007 | Chinese Science Bulletin2007，52，17： | 31 |
| 6 | Controlling N-doping type in carbon to boost single-atom site Cu catalyzed transfer hydrogenation of quinoline显示文摘Single-atom site(SA)catalysts on N-doped carbon(CN)materials exhibit prominent performance for their active sites being M-Nx.Due to the commonly random doping behaviors of N species in these CN,it is a tough issue to finely regulate their doping types and clarify their effect on the catalytic property of such catalysts.Herein,we report that the N-doping type in CN can be dominated as pyrrolic-N and pyridinic-N respectively through compounding with different metal oxides.It is found that the proportion of distinct doped N species in CN depends on the acidity and basicity of compounded metal oxide host.Owing to the coordination by pyrrolic-N,the SA Cu catalyst displays an enhanced activity(two-fold)for transfer hydrogenation of quinoline to access the valuable molecule tetrahydroquinoline with a good selectivity(99%)under mild conditions.The higher electron density of SA Cu species induced by the predominate pyrrolic-N coordination benefits the hydrogen transfer process and reduces the energy barrier of the hydrogenation pathway,which accounts for the improved catalytic effeciency. | Jian Zhang Caiyan Zheng Maolin Zhang Yajun Qiu Qi Xu Weng-Chon Cheong Wenxing Chen Lirong Zheng Lin Gu Zhengpeng Hu Dingsheng Wang Yadong Li | 2020 | Nano Research2020，13，11： | 29 |
| 7 | Nanocrystals:Solution-Based Synthesis and Applications as Nanocatalysts显示文摘Nanocrystals are emerging as key materials due to their novel shape-and size-dependent chemical and physical properties that differ drastically from their bulk counterparts.The main challenges in this field remain rationally controlled synthesis and large scale production.This article reviews recent progress in our laboratory related to solution-based synthesis of various nanostructures,including zero-dimensional(0-D)nanocrystals,1-D nanowires and nanorods,hollow structures,and superlattice materials.On the other hand,the essential goal for nanoresearchers is to achieve industrial applications of nanostructured materials.In the past decades,these fascinating materials have been widely used in many promising fields such as nanofabrication,nanodevices,nanobiology,and nanocatalysis.Herein,we focus on their applications as nanocatalysts and try to illustrate the main problems and future directions in this area based on our recent endeavors in catalytic applications of nanocrystals. | Dingsheng Wang Ting Xie Yadong Li | 2009 | Nano Research2009，2，1： | 28 |
| 8 | Size and shape control of LiFePO4 nanocrystals for better lithium ion battery cathode materials显示文摘锂铁磷酸盐(LiFePO4 ) 是为锂离子电池,而是低电子电导率和单个散开隧道的潜在的高效率阴极材料因为锂离子在这材料的合成期间要求好粒子尺寸和形状控制。在这份报纸,有不同尺寸和形状的六 LiFePO4 nanocrystals 成功地在乙烯乙二醇被综合了。形成 LiFePO4 nanocrystals 与的增加顺序 Fe-PO4-Li 帮助主要 { 010 } 暴露的脸,并且增加 LiOH 的数量在粒子尺寸导致减少。六个不同 LiFePO4 粒子的电气化学的表演证明最有希望的 LiFePO4 nanocrystals 任何一个有占优势 { 010 } 脸暴露或高特定的区域,用小铁(II ) 氧化。 | Caiyun Nan Jun Lu Lihong Li Lingling Li Qing Peng Yadong Li | 2013 | Nano Research2013，6，7： | 25 |
| 9 | Investigation of the aeroacoustic behavior and aerodynamic noise of a high-speed train pantograph显示文摘As one of the main aerodynamic noise sources of high-speed trains, the pantograph is a complex structure containing many components, and the flow around it is extremely dynamic, with high-level turbulence. This study analyzed the near-field unsteady flow around a pantograph using a large-eddy simulation(LES) with high-order finite difference schemes. The far-field aerodynamic noise from a pantograph was predicted using a computational fluid dynamics(CFD)/Ffowcs Williams-Hawkings(FW-H) acoustic analogy. The surface oscillating pressure data were also used in a boundary element method(BEM) acoustic analysis to predict the aerodynamic noise sources of a pantograph and the far-field sound radiation. The results indicated that the main aerodynamic noise sources of the pantograph were the panhead, base frame and knuckle. The panhead had the largest contribution to the far-field aerodynamic noise of the pantograph. The vortex shedding from the panhead generated tonal noise with the dominant peak corresponding to the vortex shedding frequency and the oscillating lift force exerted back on the fluid around the panhead.Additionally, the peak at the second harmonic frequency was associated with the oscillating drag force. The contribution of the knuckle-downstream direction to the pantograph aerodynamic noise was less than that of the knuckle-upstream direction of the pantograph, and the average sound pressure level(SPL) was 3.4 dBA. The directivity of the noise radiated exhibited a typical dipole pattern in which the noise directivity was obvious at the horizontal plane of θ=0°,the longitudinal plane of θ=120°,and the vertical plane of θ=90°. | ZHANG YaDong ZHANG JiYe LI Tian ZHANG Liang | 2017 | Science China(Technological Sciences)2017，60，4： | 25 |
| 10 | Cenozoic uplift of the Tibetan Plateau:Evidence from the tectonic-sedimentary evolution of the western Qaidam Basin显示文摘Geologists agree that the collision of the Indian and Asian plates caused uplift of the Tibet Plateau.However,controversy still exists regarding the modes and mechanisms of the Tibetan Plateau uplift.Geology has recorded this uplift well in the Qaidam Basin.This paper analyzes the tectonic and sedimentary evolution of the western Qaidam Basin using sub-surface seismic and drill data. The Cenozoic intensity and history of deformation in the Qaidam Basin have been reconstructed based on the tectonic developments,faults growth index,sedimentary facies variations,and the migration of the depositional depressions.The changes in the sedimentary facies show that lakes in the western Qaidam Basin had gone from inflow to still water deposition to withdrawal.Tectonic movements controlled deposition in various depressions,and the depressions gradually shifted southeastward.In addition,the morphology of the surface structures in the western Qaidam Basin shows that the Cenozoic tectonic movements controlled the evolution of the Basin and divided it into(a) the southern fault terrace zone, (b) a central Yingxiongling orogenic belt,and(c) the northern fold-thrust belt;divided by the XI fault (Youshi fault) and Youbei fault,respectively.The field data indicate that the western Qaidam Basin formed in a Cenozoic compressive tectonic environment caused by the India—Asia plate collision. Further,the Basin experienced two phases of intensive tectonic deformation.The first phase occurred during the Middle Eocene—Early Miocene(Xia Ganchaigou Fm.and Shang Ganchaigou Fm.,43.8—22 Ma),and peaked in the Early Oligocene(Upper Xia Ganchaigou Fm.,31.5 Ma).The second phase occurred between the Middle Miocene and the Present(Shang Youshashan Fm.and Qigequan Fm., 14.9—0 Ma),and was stronger than the first phase.The tectonic—sedimentary evolution and the orientation of surface structures in the western Qaidam Basin resulted from the Tibetan Plateau uplift,and recorded the periodic northward growth of the Plateau.Recognizing this early tectonic—sedimentary evolution supports the previous conclusion that northern Tibet responded to the collision between India and Asia shortly after its initiation.However,the current results reveal that northern Tibet also experienced another phase of uplift during the late Neogene.The effects of these two stages of tectonic activity combined to produce the current Tibetan Plateau. | Yadong Wang Jianjing Zheng Weilin Zhang Shiyuan Li Xingwang Liu Xin Yang Yuhu Liu | 2012 | Geoscience Frontiers2012，3，2： | 23 |
| 11 | Atomically dispersed Au_1 catalyst towards efficient electrochemical synthesis of ammonia显示文摘Tremendous efforts have been devoted to explore energy-efficient strategies of ammonia synthesis to replace Haber–Bosch process which accounts for 1.4% of the annual energy consumption. In this study,atomically dispersed Au_1 catalyst is synthesized and applied in electrochemical synthesis of ammonia under ambient conditions. A high NH_4^+ Faradaic efficiency of 11.1% achieved by our Au_1 catalyst surpasses most of reported catalysts under comparable conditions. Benefiting from efficient atom utilization, an NH_4^+ yield rate of 1,305 lg h^(-1) mg_(Au)^(-1) has been reached, which is roughly 22.5 times as high as that by supported Au nanoparticles. We also demonstrate that by employing our Au_1 catalyst, NH4+can be electrochemically produced directly from N_2 and H_2 with an energy utilization rate of 4.02 mmol kJ^(-1). Our study provides a possibility of replacing the Haber–Bosch process with environmentally benign and energy-efficient electrochemical strategies. | Xiaoqian Wang Wenyu Wang Man Qiao Geng Wu Wenxing Chen Tongwei Yuan Qian Xu Min Chen Yan Zhang Xin Wang Jing Wang Jingjie Ge Xun Hong Yafei Li Yuen Wu Yadong Li | 2018 | Science Bulletin2018，63，19： | 22 |
| 12 | Recent advances in the precise control of isolated single-site catalysts by chemical methods显示文摘The search for constructing high-performance catalysts is an unfailing topic in chemical fields. Recently, we have witnessed many breakthroughs in the synthesis of single-atom catalysts(SACs) and their applications in catalytic systems. They have shown excellent activity, selectivity, stability, efficient atom utilization and can serve as an efficient bridge between homogeneous and heterogenous catalysis. Currently, most SACs are synthesized via a bottom-up strategy; however, drawbacks such as the difficulty in accessing high mass activity and controlling homogeneous coordination environments are inevitably encountered, restricting their potential use in the industrial area. In this regard, a novel top-down strategy has been recently developed to fabricate SACs to address these practical issues. The metal loading can be increased to 5% and the coordination environments can also be precisely controlled. This review highlights approaches to the chemical synthesis of SACs towards diverse chemical reactions, especially the recent advances in improving the mass activity and well-defined local structures of SACs. Also, challenges and opportunities for the SACs will be discussed in the later part. | Zhijun Li Dehua Wang Yuen Wu Yadong Li | 2018 | National Science Review2018，5，5： | 21 |
| 13 | Surface Active Sites on Co_(3)O_(4) Nanobelt and Nanocube Model Catalysts for CO Oxidation显示文摘CO oxidation has been performed on Co_(3)O_(4) nanobelts and nanocubes as model catalysts.The Co_(3)O_(4) nanobelts which have a predominance of exposed{011}planes are more active than Co_(3)O_(4) nanocubes with exposed{001}planes.Temperature programmed reduction of CO shows that Co_(3)O_(4) nanobelts have stronger reducing properties than Co_(3)O_(4) nanocubes.The essence of shape and crystal plane effect is revealed by the fact that turnover frequency of Co3+sites of{011}planes on Co_(3)O_(4) nanobelts is far higher than that of{001}planes on Co_(3)O_(4) nanocubes. | Linhua Hu Keqiang Sun Qing Peng Boqing Xu Yadong Li | 2010 | Nano Research2010，3，5： | 21 |
| 14 | Theoretical and experimental investigation on bridge-borne noise under moving high-speed train显示文摘Bridge-borne noise pollution caused by train-induced bridge vibration has attracted more and more attentions due to its low-frequency characteristic.In order to investigate the numerical simulation technique of bridge-borne noise and noise reduction methods,a simply supported prestressed concrete (PC) box-girder bridge is adopted for study.Based on train-track-bridge interaction theory,the dynamic response of the bridge under a moving high-speed train is calculated in time-domain and assumed as the sound source of bridge-borne noise.Then bridge-borne noise is estimated according to boundary element method (BEM) in frequency-domain.The time-frequency transform is conducted by fast Fourier transformation (FFT).The validity of the numerical simulation technique is verified through comparison with field measurement results.Furthermore,noise reduction methods are proposed and corresponding effects are discussed.Results show that the proposed numerical simulation method is feasible and accurate in assessing bridge-borne noise.The dominant frequencies of bridge vibration and bridgeborne noise range from 40 Hz to125 Hz and from 31.5 Hz to 100 Hz,respectively.The peak frequency of bridge-borne noise near the bottom plate is 63 Hz.Increasing the thickness of deck plate,adjusting the inclination of webs to 0°-12°,strengthening the boundary constraints and adding a longitudinal clapboard are very effective noise control measures. | ZHANG Xun LI XiaoZhen LIU QuanMin WU JinFeng LI YaDong | 2013 | Science China(Technological Sciences)2013，56，4： | 20 |
| 15 | Cobalt single atom site catalysts with ultrahigh metal loading for enhanced aerobic oxidation of ethylbenzene显示文摘The oxidation of hydrocarbons to produce high value-added compounds(ketones or alcohols)using oxygen in air as the only oxidant is an efficient synthetic strategy from both environmental and economic views.Herein,we successfully synthesized cobalt single atom site catalysts(Co SACs)with high metal loading of 23.58 wt.%supported on carbon nitride(CN),which showed excellent catalytic properties for oxidation of ethylbenzene in air.Moreover,Co SACs show a much higher turn-over frequency(19.6 h^(−1))than other reported non-noble catalysts under the same condition.Comparatively,the as-obtained nanosized or homogenous Co catalysts are inert to this reaction.Co SACs also exhibit high selectivity(97%)and stability(unchanged after five runs)in this reaction.DFT calculations reveal that Co SACs show a low energy barrier in the first elementary step and a high resistance to water,which result in the robust catalytic performance for this reaction. | Yu Xiong Wenming Sun Yunhu Han Pingyu Xin Xusheng Zheng Wensheng Yan Juncai Dong Jian Zhang Dingsheng Wang Yadong Li | 2021 | Nano Research2021，14，7： | 20 |
| 16 | Hydroformylation of alkenes over rhodium supported on the metal-organic framework ZlF-8显示文摘 | Chao Hou Guofeng Zhao Yongjun Ji Zhiqiang Niu Dingsheng Wang Yadong Li | 2014 | Nano Research2014，7，9： | 18 |
| 17 | Porphyrin-like Fe-N4 sites with sulfur adjustment on hierarchical porous carbon for different rate-determining steps in oxygen reduction reaction显示文摘We developed a strategy based on coordination polymer to synthesize singleatom site Fe/N and S-codoped hierarchical porous carbon (Fe1/N,S-PC).The as-obtained Fe1/N,S-PC exhibited superior oxygen reduction reaction (ORR) performance with a half-wave potential (Ev2,0.904 V vs.RHE) that was better than that of commercial Pt/C (E1/2,0.86 V vs.RHE),single-atom site Fe/N-doped hierarchical porous carbon (Fe1/N-PC) without S-doped (E1/2,0.85 V vs.RHE),and many other nonprecious metal catalysts in alkaline medium.Moreover,the Fe1/N,S-PC revealed high methanol tolerance and firm stability.The excellent electrocatalytic activity of Fe1/N,S-PC is attributed to the synergistic effects from the atomically dispersed porphyrin-like Fe-N4 active sites,the heteroatom codoping (N and S),and the hierarchical porous structure in the carbon materials.The calculation based on density functional theory further indicates that the catalytic performance of Fe1/N,S-PC is better than that of Fe1/N-PC owing to the sulfur doping that yielded different rate-determining steps. | Konglin Wu Xin Chen Shoujie Liu Yuan Pan Weng-Chon Cheong Wei Zhu Xing Cao Rongan Shen Wenxing Chen Jun LUO Wensheng Yan Lirong Zheng Zheng Chen Dingsheng Wang Qing Peng Chen Chen Yadong Li | 2018 | Nano Research2018，11，12： | 18 |
| 18 | Au/LaVO_(4)Nanocomposite:Preparation,Characterization,and Catalytic Activity for CO Oxidation显示文摘The size of the gold particles is a very important parameter to get active catalysts.This paper reports a novel colloidal deposition method to prepare Au/LaVO_(4)nanocomposite catalyst with monodispersed Au colloids and uniform LaVO_(4)nanoplates in nonpolar solvent.Monodispersed Au colloids with tunable size(such as 2,5,7,11,13,and 16 nm)and LaVO_(4)nanocrystals with well-defi ned shapes were pre-synthesized assisted with oleic acid/amine.During the following immobilization process,the particle size and shape of Au and LaVO_(4)were nearly preserved.As-prepared Au/LaVO_(4)nanocomposite showed high catalytic activity for CO oxidation at room temperature.Since sizes of gold particles were well-defi ned before the immobilization process,size effect of gold particles was easy to be investigated and the results show that 5-nm Au/LaVO_(4)nanocomposite has the highest activity for CO oxidation.This synthetic method can be extended further for the preparation of other composite nanomaterials. | Junfeng Liu Wei Chen Xiangwen Liu Kebin Zhou Yadong Li | 2008 | Nano Research2008，1，1： | 16 |
| 19 | One-step accurate synthesis of shell controllable CoFe2O4 hollow microspheres as high-performance electrode materials in supercapacitor显示文摘多轰炸的 CoFe 2 O 4 有层(1-4 ) 的一个悦耳的数字的空 microspheres 成功地作为一个模板用 cyclodextrin 经由一个灵巧的一步舞方法被综合,由锻烧列在后面。包括壳数字和壳孔,结构的特征被调整合成参数与优秀能力和耐久性生产空范围控制。这是为制作金属氧化物或二金属的金属氧化物的直接、一般的策略有壳的一个悦耳的数字的空 microspheres。 | Zhuo Wang Wei Jia Menglei Jiang Chen Chen Yadong Li | 2016 | Nano Research2016，9，7： | 14 |
| 20 | A general synthetic strategy to monolayer graphene显示文摘 | Youqi Zhu Tai Cao Chuanbao Cao Xilan Ma Xingyan Xu Yadong Li | 2018 | Nano Research2018，11，6： | 14 |
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