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| 1 | 26 mA cm-2 JSC achieved in the integrated solar cells显示文摘Organometal halide perovskite has drawn much attention due to their high light-absorption coefficient,outstanding carrier mobility,and long-range charge-transport lengths.The most remarkable progress made by this type of perovskite materials is in the field of photovoltaics[1–4].The power conversion efficiency(PCE)of perovskite solar cells(PSCs)has exceeded 25%since they were first used as the active layer in solar cells in 2009[5]. | Qiaogan Liao Huiliang Sun Bolin Li Xugang Guo | 2019 | Science Bulletin2019，64，23： | 4 |
| 2 | Reducing energy loss via tuning energy levels of polymer acceptors for efficient all-polymer solar cells显示文摘The open-circuit voltage(Voc) of all-polymer solar cells(all-PSCs) is typically lower than 0.9 V even for the most efficient ones.Large energy loss is the main reason for limiting Voc and efficiency of all-PSCs. Herein, through materials design using electron deficient building blocks based on bithiophene imides, the lowest unoccupied molecular orbital(LUMO) energy levels of polymer acceptors can be effectively tuned, which resulted in a reduced energy loss induced by charge generation and recombination loss due to the suppressed charge-transfer(CT) state absorption. Despite a negligible driving force, all-PSC based on the polymer donor and acceptor combination with well-aligned energy levels exhibited efficient charge transfer and achieved an external quantum efficiency over 70% while maintaining a large Voc of 1.02 V, leading to a 9.21% efficiency. Through various spectroscopy approaches, this work sheds light on the mechanism of energy loss in all-PSCs, which paves an avenue to achieving efficient all-PSCs with large Voc and drives the further development of all-PSCs. | Huiliang Sun Bin Liu Jianwei Yu Xianshao Zou Guangye Zhang Yujie Zhang Wei Zhang Mengyao Su Qunping Fan Kun Yang Jianhua Chen He Yan Feng Gao Xugang Guo | 2020 | Science China Chemistry2020，63，12： | 2 |
| 3 | A Study on the Biocompatibility of MgO Coating Prepared by Anodic Oxidation Method on Magnesium Metal显示文摘Magnesium(Mg),is widely used for the bone repair in oral and orthopedic application due to excellent bioactivity,degradation and biocompatibility.However,the range of application is greatly limited because of the rapid degradation of Mg metal in the body.Surface modification is an effective method to enhance the corrosion resistance and reduce the degradation rate of Mg metal.In the present study,pure Mg metal(P-Mg)was subjected to alkali-heat treatment(AT-Mg)or anodic oxidation-heat treatment(AO-HT-Mg).Both AT-Mg and AO-HT-Mg had a layer of MgO on their surfaces after treatment.Then the effects of MgO coating on corrosion resistance,bioactivity,Mesenchymal Stem Cells’(MSCs)proliferation,adhesion and osteogenic differentiation,and the bone repair capability of Mg metal were investigated.We found both AT-Mg and AO-HT-Mg had stronger corrosion resistance than P-Mg.MSCs on both AT-Mg and AO-HT-Mg had higher expression of proteins and genes of ALP,OCN,Col-I and Runx2 than those on P-Mg.They also showed better bone repair property than P-Mg in vivo.In general,MgO layer formed by anodic oxidation-heat treatment had better resistance and biocompatibility than that produced by alkali-heat treatment.This study indicated the MgO coating not only improved the corrosion resistance of Mg metal,but also promoted the osteogenic differentiation of MSCs and bone regeneration. | Yangmei Chen Xugang Lu Fenghua Zhao Yi Hu Shibing Xiong Yuqiang Guo Ping Huang Bangcheng Yang | 2020 | Journal of Bionic Engineering2020，17，1： | 2 |
| 4 | Engineering of dendritic dopant-free hole transport molecules:enabling ultrahigh fill factor in perovskite solar cells with optimized dendron construction显示文摘Developing dopant-free hole-transporting materials(HTMs)for high-performance perovskite solar cells(PVSCs)has been a very active research topic in recent years since HTMs play a critical role in optimizing interfacial charge carrier kinetics and in turn determining device performance.Here,a novel dendritic engineering strategy is first utilized to design HTMs with a D-A type molecular framework,and diphenylamine and/or carbazole is selected as the building block for constructing dendrons.All HTMs show good thermal stability and excellent film morphology,and the key optoelectronic properties could be fine-tuned by varying the dendron structure.Among them,MPA-Cz-BTI and MCz-Cz-BTI exhibit an improved interfacial contact with the perovskite active layer,and non-radiative recombination loss and charge transport loss can be effectively suppressed.Consequently,high power conversion efficiencies(PCEs)of 20.8%and 21.35%are achieved for MPA-Cz-BTI and MCz-Cz-BTI based devices,respectively,accompanied by excellent long-term storage stability.More encouragingly,ultrahigh fill factors of 85.2%and 83.5%are recorded for both devices,which are among the highest values reported to date.This work demonstrates the great potential of dendritic materials as a new type of dopant-free HTMs for high-performance PVSCs with excellent FF. | Wei Chen Yang Wang Bin Liu Yajun Gao Ziang Wu Yongqiang Shi Yumin Tang Kun Yang Yujie Zhang Weipeng Sun Xiyuan Feng Frédéric Laquai Han Young Woo Aleksandra B.Djurisic Xugang Guo Zhubing He | 2021 | Science China Chemistry2021，64，1： | 2 |
| 5 | Determination of optimal dietary selenium levels by full expression of selenoproteins in various tissues of broilers from 1 to 21 d of age显示文摘The current NRC dietary selenium(Se)requirement(0.15 mg/kg)of broilers is primarily based on growth performance data reported in 1986.Our study aimed to determine optimal dietary Se levels of broilers fed a practical corn-soybean meal diet for the full expression of selenoproteins in various tissues.A total of 384 one-d-old male broilers(n=8 replicates/diet)were fed a basal corn-soybean meal diet or the basal diet supplemented with 0.1,0.2,0.3,0.4 or 0.5 mg Se/kg in the form of Na_(2)SeO_(3) for 21 d.Regression analysis was conducted to evaluate the optimal dietary Se levels using broken-line,quadratic or asymptotic models.The activity of glutathione peroxidase(GPX)in the plasma,liver,kidney and pancreas,iodothyronine deiodinase(DIO)in the plasma,liver and pancreas,and thioredoxin reductase(Txnrd)in the liver and pancreas,the mRNA levels of Gpx1,Gpx4,Dio1,selenoprotein(Seleno)h,Selenop and Selenou in the liver,Gpx4,Dio1,Txnrd1,Txnrd2,Selenoh,Selenop and Selenou in the kidney,and Gpx1,Gpx4,Selenoh and Selenou in the pancreas,and the protein levels of GPX4 in the liver and kidney of broilers were influenced(P<0.05)by added Se levels,and increased quadratically(P<0.05)with the increase of added Se levels.The estimates of optimal dietary Se levels were 0.07 to 0.36 mg/kg based on the fitted broken-line,quadratic or asymptotic models(P<0.001)of the aforementioned selenoprotein expression in the plasma,liver and kidney,and 0.09 to 0.46 mg/kg based on the fitted broken-line models(P<0.001)of the aforementioned selenoprotein expression in the pancreas.The results indicate that the optimal dietary Se levels would be 0.36 mg/kg to support the full expression of selenoproteins in the plasma,liver and kidney,and 0.46 mg/kg to support the full expression of selenoproteins in the pancreas of broilers fed a practical corn-soybean meal diet from 1 to 21 d of age. | Xiudong Liao Guoqing Liu Guangming Sun Xiaoming Sun Tao Liu Lin Lu Liyang Zhang Minhong Zhang Yanli Guo Xugang Luo | 2021 | Animal Nutrition2021，，4： | 2 |
| 6 | A Cost-Effective D-A-D Type Hole-Transport Material Enabling 20% Efficiency Inverted Perovskite Solar Celis显示文摘High-performance,cost-effective hole-transport materials(HTMs)are greatly desired for the commercialization of perovskite solar cells(PVSCs).Herein,two new HTMs,TPA-FO and TPA-PDO,are devised and synthesized,which have a donor-acceptor-donor(D-A-D)type molecule design featuring carbonyl group-functionalized arenes as the acceptor(A)units.The carbonyl group at the central core of HTMs can not only tune frontier molecular orbital(FMO)energy levels and surface wettability,but also can enable efficient surface passivation effects,resulting in reduced recombination loss.When employed as HTMs in inverted PVSCs without using dopant,TPA-FO with one carbonyl group yields a high power conversion efficiency(PCE)of 20.24%,which is among the highest values reported in the inverted PVSCs with dopant-free HTMs.More importantly,the facile one-step synthetic process enables a low cost of 30 USD g^(-1) for TPA-FO,much cheaper than the most studied HTMs used for high-efficiency dopant-free PVSCs.These results demonstrate the potential of D-A-D type molecules with carbonyl group-functionalized arene core in developing the low-cost dopant-free HTMs toward highly efficient PVSCs. | Jiachen Huang Jie Yang Huiliang Sun Kui Feng Qiaogan Liao Bolin Li He Yan Xugang Guo | 2021 | Chinese Journal of Chemistry2021，39，6： | 2 |
| 7 | Optimization of solvent swelling for efficient organic solar cells via sequential deposition显示文摘Compared to bulk heterojunction(BHJ)organic solar cells(OSCs)prepared by the blend casting in“one step process”,sequential deposition(SD)processed OSCs can realize an ideal profile of vertical component distribution due to the swelling of polymer films.Herein,we did trials on several kinds of second solvents for swelling the polymer layer,and investigated the packing structure and morphology of the swollen films and the performance of the resulting devices.We found that an optimized morphology can be achieved by solvent swelling while using orthodichlorobenzene(o-DCB)as the second layer processing-solvent,with polymer donor PffBT-3 as bottom layer,PC71BM as top layer and bicontinuous networks in the middle.Such solvent swelling process also makes the SD method exempt from thermal annealing treatment.The device based on SD yields a power conversion effi-ciency(PCE)up to 8.7%without any post-treatment,outperforming those from the devices based on SD using other solvents and that(7.06%)from BHJ device,respectively.We also extended the use of this approach to allpolymer blend system,and successfully improved the efficiency from 4.72%(chloroform)to 9.35%(o-DCB),which is among the highest PCEs in all-polymer-based OSCs fabricated with SD method.The results demonstrate that the swelling of the polymer by the second layer solvent is a necessity for SD,paving the way towards additivefree high-performance OSCs. | Qiaogan Liao Bangbang Li Huiliang Sun Chang Woo Koh Xianhe Zhang Bin Liu Han Young Woo Xugang Guo | 2021 | Materials Reports(Energy)2021，1，4： | 1 |
| 8 | Thieno3, 4-cpyrrole-4,6-dione-based donor-acceptor conjugated, po- lymers for solar cells 显示文摘 | Guo Xugang Xin Hao Felix Sunjoo Kim | 2011 | Macromolecules2011，44，： | 1 |
| 9 | Over 16% efficiency all-polymer solar cells by sequential deposition显示文摘All-polymer solar cells(all-PSCs) have received extensive attention due to their excellent mechanical robustness and performance stability. However, the power conversion efficiency(PCE) of all-PSCs still lags behind those of organic solar cells(OSCs)based on non-fullerene small molecule acceptors. Herein, we report highly efficient all-PSCs via sequential deposition(SD) with donor and acceptor layers coated sequentially to optimize the film microstructure. Compared with the bulk heterojunction(BHJ)all-PSCs, an optimized morphology with vertical component distribution was achieved for the SD-processed all-PSCs due to the synergistic effect of swelling of polymer films and using additive. Such strategy involves using chlorobenzene as the first layer processing-solvent for polymer donor, chloroform as the second processing-solvent for polymer acceptor with trace 1-chloronaphthalene, efficiently promoting exciton dissociation and charge extraction and reducing trap-assisted recombination.Consequently, over 16% all-PSCs fabricated via SD method was realized for the first time, which is much higher than that(15.2%) of its BHJ counterpart and also among the highest PCEs in all-PSCs. We have further demonstrated the generality of this approach in various all-polymer systems. This work indicates that the SD method can yield excellent all-PSCs and provides a facile approach to fabricating high-performance all-PSCs. | Bangbang Li Xuanyu Zhang Ziang Wu Jie Yang Bin Liu Qiaogan Liao Junwei Wang Kui Feng Rui Chen Han Young Woo Fei Ye Li Niu Xugang Guo Huiliang Sun | 2022 | Science China Chemistry2022，65，6： | 1 |
| 10 | Recent progress in low-cost noncovalently fused-ring electron acceptors for organic solar cells显示文摘The power conversion efficiencies(PCEs)of organic solar cells(OSCs)have improved considerably in recent years with the development of fused-ring electron acceptors(FREAs).Currently,FREAs-based OSCs have achieved high PCEs of over 19%in single-junction OSCs.Whereas the relatively high synthetic complexity and the low yield of FREAs typically result in high production costs,hindering the commercial application of OSCs.In contrast,noncovalently fused-ring electron acceptors(NFREAs)can compensate for the shortcomings of FREAs and facilitate large-scale industrial production by virtue of the simple structure,facile synthesis,high yield,low cost,and reasonable efficiency.At present,OSCs based on NFREAs have exceeded the PCEs of 15%and are expected to reach comparable efficiency as FREAs-based OSCs.Here,recent advances in NFREAs in this review provide insight into improving the performance of OSCs.In particular,this paper focuses on the effect of the chemical structures of NFREAs on the molecule conformation,aggregation,and packing mode.Various molecular design strategies,such as core,side-chain,and terminal group engineering,are presented.In addition,some novel polymer acceptors based on NFREAs for all-polymer OSCs are also introduced.In the end,the paper provides an outlook on developing efficient,stable,and low-cost NFREAs for achieving commercial applications. | Qingqing Bai Qiming Liang Henan Li Huiliang Sun Xugang Guo Li Niu | 2022 | Aggregate2022，3，6： | 1 |
| 11 | Conjugated polymers from naphthalene bisimide 显示文摘 | Guo Xugang Watson M D | 2008 | Org Lett2008，10，23： | 1 |
| 12 | Novel dental implant modifications with two-staged double benefits for preventing infection and promoting osseointegration in vivo and in vitro显示文摘Peri-implantitis are a major problem causing implant failure these days.Accordingly,anti-infection during the early stage and subsequent promotion of osseointegration are two main key factors to solve this issue.Micro-arc oxidation(MAO)treatment is a way to form an oxidation film on the surface of metallic materials.The method shows good osteogenic properties but weak antibacterial effect.Therefore,we developed combined strategies to combat severe peri-implantitis,which included the use of a novel compound,PD,comprising dendrimers poly(amidoamine)(PAMAM)loading dimethylaminododecyl methacrylate(DMADDM)as well as MAO treatment.Here,we explored the chemical properties of the novel compound PD,and proved that this compound was successfully synthesized,with the loading efficiency and encapsulation efficiency of 23.91%and 31.42%,respectively.We further report the two-stage double benefits capability of PD+MAO:(1)in the first stage,PD+MAO could decrease the adherence and development of biofilms by releasing DMADDM in the highly infected first stage after implant surgery both in vitro and in vivo;(2)in the second stage,PD+MAO indicated mighty anti-infection and osteoconductive characteristics in a rat model of peri-implantitis in vivo.This study first reports the two-staged,double benefits of PD+MAO,and demonstrates its potential in clinical applications for inhibiting peri-implantitis,especially in patients with severe infection risk. | Xiaoyu Huang Yang Ge Bina Yang Qi Han Wen Zhou Jingou Liang Mingyun Li Xian Peng Biao Ren Bangcheng Yang Michael D.Weir Qiang Guo Haohao Wang Xinxuan Zhou Xugang Lu Thomas W.Oates Hockin H.K.Xu Dongmei Deng Xuedong Zhou Lei Cheng | 2021 | Bioactive Materials2021，6，12： | 1 |
| 13 | Polymer acceptors for all-polymer solar cells显示文摘Bulk-heterojunction polymer solar cells(PSCs)as a clean and renewable energy resource have attracted great attention from both academia and industry[1−20].Recently non-fullerene PSCs based on polymer donors(PDs)and small molecule acceptors(SMAs)have achieved remarkable success with the power conversion efficiencies(PCEs)over 18%[21−26]. | Xiaofei Ji Zuo Xiao Huiliang Sun Xugang Guo Liming Ding | 2021 | Journal of Semiconductors2021，42，8： | 0 |
| 14 | Alkoxy-Functionalized Bithiophene/thiazoles: Versatile Building Blocks for High-Performance Organic and Polymeric Semiconductors显示文摘CONSPECTUS:Organic electronics has experienced substantial advances in the past decade,driven by the development of high-performance organic semiconductors(OSCs)in combination with device engineering.While the pursuit of new aromatic building blocks has been a central topic in OSC innovation,the installation of novel side chains is also of significance for accessing high-performance solution-processable OSCs due to their great impact on(macro)molecular conformation/configuration,energy levels,intra/intermolecular interaction,and packing motifs,as well as film morphology of the materials.Compared to tuning the length,branching point,anchoring position,and terminal group of alkyl side chains,alkoxy functionalization can afford multifaceted advantages by modulating the properties of bothπ-conjugated main chains and side chain substituents.For instance,the oxygen atom in alkoxy chains not only greatly decreases the steric hindrance between adjacent aromatic rings due to its reduced van der Waal radius(∼1.4Å)versus that of a CH_(2) moiety(∼2.0Å)but also induces intramolecular noncovalent interaction for improving backbone coplanarity and charge transport properties.The highly electron-donating alkoxy chains can also greatly facilitate the intramolecular charge transfer(ICT),and hence the resulting semiconductors can yield absorption beyond the infrared region,which is essential for full coverage of solar absorption in photovoltaic devices.Additionally,the high polarity of oligo(ethylene glycol)-type alkoxy side chains can improve the miscibility of the OSCs with molecular dopants and ions,thus enabling them as a key part of the OSCs for emerging applications such as organic thermoelectrics and organic electrochemical transistors.In this Account,we summarize our pioneering and systematic efforts on the rational design,synthesis,and applications of novel alkoxy-functionalized head-to-head(HH)-linked bithiophene/thiazole-based building blocks and related organic/polymeric semiconductors.First,starting with a brief retrospective to the long pursuit of regioregular polythiophenes to avoid HH linkages for accessing highly planar polymers with high mobility,we introduce the basic design guidelines for developing alkoxy-functionalized bithiophene/thiazole-based building blocks via various molecular engineering strategies,including noncovalent interaction incorporation,symmetry-breaking,fluorination,cyanation,esterification,etc.In this part,the merits of HH-linked alkoxy-functionalized bithiophene/thiazoles in constructing high-performance OSCs will be elaborated.Then the principles of designing organic and polymeric semiconductors based on these building blocks toward applications in different optoelectronic devices will be further discussed.Afterward,we present recent examples of alkoxy-functionalized bithiophene/thiazoles-based materials which have delivered state-of-the-art performance in various optoelectronic devices,showing how the judicious structure tailoring of these building blocks can optimize the materials properties and device performance.Finally,we offer our insights into the further development of alkoxy-functionalized bithiophene/thiazoles-based derivatives and semiconductors for high-performance optoelectronic devices. | Kun Yang Zhicai Chen Yimei Wang Xugang Guo | 2023 | Accounts of Materials Research2023，4，3： | 0 |
| 15 | Self-assembled donor-acceptor hole contacts for inverted perovskite solar cells with an efficiency approaching 22%: The impact of anchoring groups显示文摘Self-assembled molecules(SAMs) have shown great potential in replacing bulk charge selective contact layers in high-performance perovskite solar cells(PSCs) due to their low material consumption and simple processing. Herein, we design and synthesize a series of donor-acceptor(D-A) type SAMs(MPA-BTCA, MPA-BT-BA, and MPA-BT-RA, where MPA is 4-methoxy-N-(4-methoxyphenyl)-N-phenylaniline;BT is benzo[c][1,2,5]-thiadiazole;CA is 2-cyanoacrylic acid, BA is benzoic acid, RA is rhodanine-3-propionic acid) with distinct anchoring groups, which show dramatically different properties. MPA-BTCA with CA anchoring groups exhibited stronger dipole moments and formed a homogeneous monolayer on the indium tin oxide(ITO) surface by adopting an upstanding self-assembling mode. However, the MPA-BT-RA molecules tend to aggregate severely in solid state due to the sp~3 hybridization of the carbon atom on the RA group, which is not favorable for achieving a long-range ordered self-assembled layer.Consequently, benefiting from high dipole moment, as well as dense and uniform self-assembled film,the device based on MPA-BT-CA yielded a remarkable power conversion efficiency(PCE) of 21.81%.Encouragingly, an impressive PCE approaching 20% can still be obtained for the MPA-BT-CA-based PSCs as the device area is increased to 0.80 cm^(2). Our work sheds light on the design principles for developing hole selecting SAMs, which will pave a way for realizing highly efficient, flexible, and large-area PSCs. | Qiaogan Liao Yang Wang Zilong Zhang Kun Yang Yongqiang Shi Kui Feng Bolin Li Jiachen Huang Peng Gao Xugang Guo | 2022 | Journal of Energy Chemistry2022，31，5： | 0 |
| 16 | PY-IT,an Excellent Polymer Acceptor显示文摘All-polymer solar cells(all-PSCs)have attracted considerable attention due to their inherent advantages over other types of organic solar cells,including superior optical and thermal stability,as well as exceptional mechanical durability.Recently,all-PSCs have experienced remarkable advancements in device performance thanks to the invention of polymerized small-molecule acceptors(PSMAs)since 2017.Among these PSMAs,PY-IT has garnered immense interest from the scientific community due to its exceptional performance in all-PSCs.In this review,we presented the design principles of PY-IT and discussed the various strategies employed in device engineering for PY-IT-based all-PSCs.These strategies include additive and interface engineering,layer-by-layer processing methods,meniscus-assisted coating methods,and ternary strategy.Furthermore,this review highlighted several novel polymeric donor materials that are paired with PY-IT to achieve efficient all-PSCs.Lastly,we summarized the inspiring strategies for further advancing all-PSCs based on PY-IT.These strategies aim to enhance the overall performance and stability of all-PSCs by exploring new materials,optimizing device architectures,and improving fabrication techniques.By leveraging these approaches,we anticipate significant progress in the development of all-PSCs and their potential as a viable renewable energy source. | Qingqing Bai Qiming Liang Qian Liu Bin Liu Xugang Guo Li Niu Huiliang Sun | 2023 | Chinese Journal of Chemistry2023，41，24： | 0 |
| 17 | Revisiting the Bithiophene Imide-Based Polymer Donors: Molecular Aggregation and Orientation Control Enabling New Polymer Donors for High-Performance All-Polymer Solar Cells显示文摘Bithiophene imide (BTI)-based polymers have been promising photovoltaic materials due to their high mobility and tunable energy levels. However, BTI polymers have rarely been revisited since organic solar cells (OSCs) entered the era of non-fullerene electron acceptors (NFEA) likely owing to their incompatibility with NFEAs. Herein, fine-tuning the aggregation and orientation of BTI-based donor-π-acceptor (D-π-A) polymer donors was achieved by incorporating the linear n-octyl group into thiophene π-bridge. The resulting polymer donor G15 shows excellent compatibility with NFEA L15 (polymer acceptor). The G15-based all-polymer OSCs achieve high power conversion efficiency of 15.17%. This is significantly higher than that (< 5%) of its analogue with isomerized branched alkyl chains and also among the highest values for all-polymer OSCs. The results highlight that well-tailored BTI polymer donors are attractive photovoltaic materials for further exploration in non-fullerene organic solar cells. | Jie Yang Bin Liu Jin-Woo Lee Yimei Wang Huiliang Sun Zhicai Chen Qingqing Bai Bumjoon J.Kim Yan Jiang Li Niu Xugang Guo | 2022 | Chinese Journal of Chemistry2022，40，24： | 0 |
| 18 | Regioisomeric Polymer Semiconductors Based on Cyano-Functionalized Dialkoxybithiophenes:Structure-Property Relationship and Photovoltaic Performance显示文摘Cyano substitution is vital to the molecular design of polymer semiconductors toward highly efficient organic solar cells.However,how regioselectivity impacts relevant optoelectronic properties in cyano-substituted bithiophene systems remain poorly understood.Three regioisomeric cyano-functionalized dialkoxybithiophenes BT_(HH),BT_(HT),and BT_(TT) with headto-head,head-to-tail,and tail-to-tail linkage,respectively,were synthesized and characterized in this work.The resulting polymer semiconductors(PBDTBTs)based on these building blocks were prepared accordingly.The regiochemistry and property relationships of PBDTBTs were investigated in detail.The BTHH moiety has a higher torsional barrier than the analogs BT_(HT) and BT_(TT),and the regiochemistry of dialkoxybithiophenes leads to fine modulation in the optoelectronic properties of these polymers,such as optical absorption,band gap,and energy levels of frontier molecular orbitals.Organic field-effect transistors based on PBDTBT_(HH) had higher hole mobility(4.4×10^(-3) cm^(2)/(V·s))than those(ca.10^(-4) cm^(2)/(V·s))of the other two polymer analogs.Significantly different short-circuit current densities and fill factors were obtained in polymer solar cells using PBDTBTs as the electron donors.Such difference was probed in greater detail by performing space-charge-limited current mobility,thin-film morphology,and transient photocurrent/photovoltage characterizations.The findings highlight that the BTHH unit is a promising building block for the construction of polymer donors for highperformance organic photovoltaic cells. | Qingqing Bai Jun Huang Han Guo Suxiang Ma Jie Yang Bin Liu Kun Yang Huiliang Sun Han Young Woo Li Niu Xugang Guo | 2022 | Transactions of Tianjin University2022，28，5： | 0 |
| 19 | Advances in Green-Solvent-Processable All-Polymer Solar Cells显示文摘All-polymer solar cells(all-PSCs)have significantly improved long-term stability and mechanical stretchability.The power conversion efficiency(PCE)of all-PSCs has been rapidly improved from∼1%to now over∼17%,driven by rational molecular design,blend morphology optimization,and device engineering.However,most all-PSCs are generally processed with halogenated solvents,hazardous for human health and the global environment.Achieving high-performance all-PSCs with halogen-free solvent processing remains a challenge.This feature article presents recent advances in green-solvent-processable all-PSCs from the material design and morphological control perspective,and further reviews progress in using more environmentally friendly solvents(i.e.,water or alcohol)to achieve genuinely sustainable and environmentally friendly manufacturing all-PSCs.Finally,we provide an outlook on the challenges and opportunities for large-scale manufacturing of green-solvent-processable all-PSCs. | Qingqing Bai Huiliang Sun Xugang Guo Li Niu | 2022 | Chinese Journal of Polymer Science2022，40，8： | 0 |
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