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| 1 | Aquathermolysis of conventional heavy oil with superheated steam显示文摘This paper presents a new aquathermolysis study of conventional heavy oil in superheated steam.A new high temperature autoclave was designed,where volume and pressure could be adjusted. Aquathermolysis was studied on two different conventional heavy oil samples under different reaction times and temperatures.Experimental results show that aquathermolysis does take place for conventional heavy oil.As reaction time increases,the oil viscosity reduces.However,the reaction will reach equilibrium after a certain period of time and won’t be sensitive to any further reaction time any more. Analysis shows that,while resin and asphaltenes decrease,saturated hydrocarbons and the H/C ratio increase after reaction.The main mechanism of aquathermolysis includes hydrogenization,desulfuration reaction of resin and asphaltenes,etc. | Song Guangshou Zhou Tiyao Cheng Linsong Wang Yunxian Tian Guoqing Pi Jian Zhang Zheng | 2009 | Petroleum Science2009,6,3: | 6 |
| 2 | Radioimmunoimaging of colorectal cancer using ^(99m)Tc-labeled monoclonal antibody显示文摘Radioimmunoimagingofcolorectalcancerusing99mTclabeledmonoclonalantibodyHUJinYue1,SUJiaanZhi2,PIZhiMing3,ZHUJianGao1,ZHO... | HU JinYue1, SU JianZhi2, PI ZhiMing3, ZHU JianGao1, ZHOU GuoHua1 and SUN QuBing1Keywords colorectal neoplasms/radioimmunoimaging antibody, monoclonal isotope labeling technium/diagnostic use | 1998 | World Journal of Gastroenterology1998,4,4: | 4 |
| 3 | Organic Carbon Isotope Geochemistry of the Neoproterozoic Doushantuo Formation,South China显示文摘The Neoproterozoic Doushantuo Formation on the Yangtze Platform,South China,documents a sedimentary succession with different sedimentary facies from carbonate platform to slope and to deep sea basin,and hosts one of the world-class phosphorite deposits.In these strata,exquisitely preserved fossils have been discovered:the Weng’an biota.This study presents carbon isotope geochemistry which is associated paired carbonate and organic matter from the Weng’an section of a carbonate platform(shelf of the Yangtze Platform,Guizhou Province)from the Songtao section and Nanming section of a transition belt(slope of the Yangtze Platform,Guizhou Province)and from the Yanwutan section(basin area of the Yangtze Platform,Hunan Province).Environmental variations and bio-events on the Yangtze Platform during the Late Neoproterozoic and their causal relationship are discussed.Negative carbon isotope values for carbonate and organic carbon(mean δ13Corg = ?35.0‰)from the uppermost Nantuo Formation are followed by an overall increase in δ13C up-section.Carbon isotope values vary between ?9.9‰ and 3.6‰ for carbonate and between ?35.6‰ and ?21.5‰ for organic carbon,respectively.Heavier δ13Ccarb values suggest an increase in organic carbon burial,possibly related to increasing productivity(such as the Weng’an biota).The δ13C values of the sediments from the Doushantuo Formation decreased from the platform via the slope to basin,reflecting a reduced environment with minor dissolved inorganic carbon possibly due to a lower primary productivity.It is deduced that the classical upwelling process,the stratification structure and the hydrothermal eruption are principally important mechanisms to interpret the carbon isotopic compositions of the sediments from the Doushantuo Formation. | GUO Qingjun LIU Congqiang Harald STRAUSS Tatiana GOLDBERG ZHU Maoyan PI Daohui WANG Jian | 2006 | Acta Geologica Sinica(English Edition)2006,80,5: | 3 |
| 4 | Phase Evolution of Aluminum-Chromium-Phosphate Binders during HeatTreatmen显示文摘 | Chao Zou Dai Hai Zhang YiLi Wen Jian Wang Kui Cheng Chen Lu Song Gao Ling Zhao Pi Yi Du Ge ShenJian Xun Wang Gao Rong Han | | 0,,: | 1 |
| 5 | Thermal stability of electroless-nickel/solder interface: Part B. Interfacial fatigue resistance显示文摘 | Pi Lin Liu Jian Ku Shang | 2000 | Metallurgical and Materials Transactions A2000,,11: | 1 |
| 6 | p38 and ERK, but not JNK, are involved in copper-induced apoptosis in cultured cerebellar granule neurons显示文摘 | Xiaohong Chen Xiujian Lan Suilin Mo Jian Qin Wenming Li Peiqing Liu Yifan Han Rongbiao Pi | 2009 | Biochemical and Biophysical Research Communications2009,,4: | 1 |
| 7 | Microwave pho tonics 显示文摘 | Jian pi ngYao | 2009 | Journal of Lightwave Technology2009,27,3: | 1 |
| 8 | A Built-in Test Scheme for Pipelined Multipliers and Dividers显示文摘An embedded test pattern generator scheme in large-operand multiplier and divider is presented by applying simple digital circuit. This scheme is based on the generation of cyclic code polynomials from a characterized polynomials generator G(X). Only full adders / subtractors and shift registers are used in the proposed multiplier and divider hardware. The input data of the multiplier/divider can be processed in parallel or in pipelined without considering carry/borrow delays during the operations. The speed of computation has therefore been greatly improved by approximately a factor of 2. Since most parts of the components can be both used in the multiplier and divider, just one full adder is applied in the multiplier to be replaced by a subtractor in the divider. The structure is therefore tremendously reduced. In addition, this hardware can be incorporated with a cyclic code generator t perform built-in self-test (BIST). | Hao-Yung Lo1, Tsin-Yuan Chang1, Hsiu-Feng Lin, Chichyang Chen, Jenshiuh Liu, Chia-Cheng Liu, Jian Houng Lee, Jung-Shiarn Shie, Shin Shing Chen, Pi Cheng Chang, Web Ming Cho, Jyh Ho Houng, Miin-Shyue Shiau, and Chih-Hung Yang Institute of Information Engi | 2000 | 湖南大学学报(自然科学版)2000,27,S2: | 0 |
| 9 | Feasibility and physics potential of detecting ^(8)B solar neutrinos at JUNO显示文摘The Jiangmen Underground Neutrino Observatory(JUNO)features a 20 kt multi-purpose underground liquid scintillator sphere as its main detector.Some of JUNO's features make it an excellent location for^8B solar neutrino measurements,such as its low-energy threshold,high energy resolution compared with water Cherenkov detectors,and much larger target mass compared with previous liquid scintillator detectors.In this paper,we present a comprehensive assessment of JUNO's potential for detecting^8B solar neutrinos via the neutrino-electron elastic scattering process.A reduced 2 MeV threshold for the recoil electron energy is found to be achievable,assuming that the intrinsic radioactive background^(238)U and^(232)Th in the liquid scintillator can be controlled to 10^(-17)g/g.With ten years of data acquisition,approximately 60,000 signal and 30,000 background events are expected.This large sample will enable an examination of the distortion of the recoil electron spectrum that is dominated by the neutrino flavor transformation in the dense solar matter,which will shed new light on the inconsistency between the measured electron spectra and the predictions of the standard three-flavor neutrino oscillation framework.IfDelta m^(2)_(21)=4.8times10^(-5);(7.5times10^(-5))eV^(2),JUNO can provide evidence of neutrino oscillation in the Earth at approximately the 3sigma(2sigma)level by measuring the non-zero signal rate variation with respect to the solar zenith angle.Moreover,JUNO can simultaneously measureDelta m^2_(21)using^8B solar neutrinos to a precision of 20% or better,depending on the central value,and to sub-percent precision using reactor antineutrinos.A comparison of these two measurements from the same detector will help understand the current mild inconsistency between the value of Delta m^2_(21)reported by solar neutrino experiments and the KamLAND experiment. | Angel Abusleme Thomas Adam Shakeel Ahmad Sebastiano Aiello Muhammad Akram Nawab Ali Fengpeng An Guangpeng An Qi An Giuseppe Andronico Nikolay Anfimov Vito Antonelli Tatiana Antoshkina Burin Asavapibhop João Pedro Athayde Marcondes de André Didier Auguste Andrej Babic Wander Baldini Andrea Barresi Eric Baussan Marco Bellato Antonio Bergnoli Enrico Bernieri David Biare Thilo Birkenfeld Sylvie Blin David Blum Simon Blyth Anastasia Bolshakova Mathieu Bongrand Clément Bordereau Dominique Breton Augusto Brigatti Riccardo Brugnera Riccardo Bruno Antonio Budano Max Buesken Mario Buscemi Jose Busto Ilya Butorov Anatael Cabrera Hao Cai Xiao Cai Yanke Cai Zhiyan Cai Antonio Cammi Agustin Campeny Chuanya Cao Guofu Cao Jun Cao Rossella Caruso Cédric Cerna Jinfan Chang Yun Chang Pingping Chen Po-An Chen Shaomin Chen Shenjian Chen Xurong Chen Yi-Wen Chen Yixue Chen Yu Chen Zhang Chen Jie Cheng Yaping Cheng Alexander Chepurnov Davide Chiesa Pietro Chimenti Artem Chukanov Anna Chuvashova Gérard Claverie Catia Clementi Barbara Clerbaux Selma Conforti Di Lorenzo Daniele Corti Salvatore Costa Flavio Dal Corso Christophe De La Taille Jiawei Deng Zhi Deng Ziyan Deng Wilfried Depnering Marco Diaz Xuefeng Ding Yayun Ding Bayu Dirgantara Sergey Dmitrievsky Tadeas Dohnal Georgy Donchenko Jianmeng Dong Damien Dornic Evgeny Doroshkevich Marcos Dracos Frédéric Druillole Shuxian Du Stefano Dusini Martin Dvorak Timo Enqvist Heike Enzmann Andrea Fabbri Lukas Fajt Donghua Fan Lei Fan Can Fang Jian Fang Marco Fargetta Anna Fatkina Dmitry Fedoseev Vladko Fekete Li-Cheng Feng Qichun Feng Richard Ford Andrey Formozov Amélie Fournier Haonan Gan Feng Gao Alberto Garfagnini Alexandre Göttel Christoph Genster Marco Giammarchi Agnese Giaz Nunzio Giudice Franco Giuliani Maxim Gonchar Guanghua Gong Hui Gong Oleg Gorchakov Yuri Gornushkin Marco Grassi Christian Grewing Maxim Gromov Vasily Gromov Minghao Gu Xiaofei Gu Yu Gu Mengyun Guan Nunzio Guardone Maria Gul Cong Guo Jingyuan Guo Wanlei Guo Xinheng Guo Yuhang Guo Paul Hackspacher Caren Hagner Ran Han Yang Han Miao He Wei He Tobias Heinz Patrick Hellmuth Yuekun Heng Rafael Herrera Daojin Hong YuenKeung Hor Shaojing Hou Yee Hsiung Bei-Zhen Hu Hang Hu Jianrun Hu Jun Hu Shouyang Hu Tao Hu Zhuojun Hu Chunhao Huang Guihong Huang Hanxiong Huang Qinhua Huang Wenhao Huang Xingtao Huang Yongbo Huang Jiaqi Hui Wenju Huo Cédric Huss Safeer Hussain Antonio Insolia Ara Ioannisian Daniel Ioannisyan Roberto Isocrate Kuo-Lun Jen Xiaolu Ji Xingzhao Ji Huihui Jia Junji Jia Siyu Jian Di Jiang Xiaoshan Jiang Ruyi Jin Xiaoping Jing Cécile Jollet Jari Joutsenvaara Sirichok Jungthawan Leonidas Kalousis Philipp Kampmann Li Kang Michael Karagounis Narine Kazarian Amir Khan Waseem Khan Khanchai Khosonthongkee Patrick Kinz Denis Korablev Konstantin Kouzakov Alexey Krasnoperov Svetlana Krokhaleva Zinovy Krumshteyn Andre Kruth Nikolay Kutovskiy Pasi Kuusiniemi Tobias Lachenmaier Cecilia Landini Sébastien Leblanc Frederic Lefevre Liping Lei Ruiting Lei Rupert Leitner Jason Leung Demin Li Fei Li Fule Li Haitao Li Huiling Li Jiaqi Li Jin Li Kaijie Li Mengzhao Li Nan Li Nan Li Qingjiang Li Ruhui Li Shanfeng Li Shuaijie Li Tao Li Weidong Li Weiguo Li Xiaomei Li Xiaonan Li Xinglong Li Yi Li Yufeng Li Zhibing Li Ziyuan Li Hao Liang Hao Liang Jingjing Liang Jiajun Liao Daniel Liebau Ayut Limphirat Sukit Limpijumnong Guey-Lin Lin Shengxin Lin Tao Lin Jiajie Ling Ivano Lippi Fang Liu Haidong Liu Hongbang Liu Hongjuan Liu Hongtao Liu Hu Liu Hui Liu Jianglai Liu Jinchang Liu Min Liu Qian Liu Qin Liu Runxuan Liu Shuangyu Liu Shubin Liu Shulin Liu Xiaowei Liu Yan Liu Alexey Lokhov Paolo Lombardi Claudio Lombardo Kai Loo Chuan Lu Haoqi Lu Jingbin Lu Junguang Lu Shuxiang Lu Xiaoxu Lu Bayarto Lubsandorzhiev Sultim Lubsandorzhiev Livia Ludhova Fengjiao Luo Guang Luo Pengwei Luo Shu Luo Wuming Luo Vladimir Lyashuk Qiumei Ma Si Ma Xiaoyan Ma Xubo Ma Jihane Maalmi Yury Malyshkin Fabio Mantovani Francesco Manzali Xin Mao Yajun Mao Stefano MMari Filippo Marini Sadia Marium Cristina Martellini Gisele Martin-Chassard Agnese Martini Davit Mayilyan Axel Müller Ints Mednieks Yue Meng Anselmo Meregaglia Emanuela Meroni David Meyhöfer Mauro Mezzetto Jonathan Miller Lino Miramonti Salvatore Monforte Paolo Montini Michele Montuschi Nikolay Morozov Pavithra Muralidharan Massimiliano Nastasi Dmitry VNaumov Elena Naumova Igor Nemchenok Alexey Nikolaev Feipeng Ning Zhe Ning Hiroshi Nunokawa Lothar Oberauer Juan Pedro Ochoa-Ricoux Alexander Olshevskiy Domizia Orestano Fausto Ortica Hsiao-Ru Pan Alessandro Paoloni Nina Parkalian Sergio Parmeggiano Teerapat Payupol Yatian Pei Nicomede Pelliccia Anguo Peng Haiping Peng Frédéric Perrot Pierre-Alexandre Petitjean Fabrizio Petrucci Luis Felipe Piñeres Rico Oliver Pilarczyk Artyom Popov Pascal Poussot Wathan Pratumwan Ezio Previtali Fazhi Qi Ming Qi Sen Qian Xiaohui Qian Hao Qiao Zhonghua Qin Shoukang Qiu Muhammad Rajput Gioacchino Ranucci Neill Raper Alessandra Re Henning Rebber Abdel Rebii Bin Ren Jie Ren Taras Rezinko Barbara Ricci Markus Robens Mathieu Roche Narongkiat Rodphai Aldo Romani Bedřich Roskovec Christian Roth Xiangdong Ruan Xichao Ruan Saroj Rujirawat Arseniy Rybnikov Andrey Sadovsky Paolo Saggese Giuseppe Salamanna Simone Sanfilippo Anut Sangka Nuanwan Sanguansak Utane Sawangwit Julia Sawatzki Fatma Sawy Michaela Schever Jacky Schuler Cédric Schwab Konstantin Schweizer Dmitry Selivanov Alexandr Selyunin Andrea Serafini Giulio Settanta Mariangela Settimo Muhammad Shahzad Vladislav Sharov Gang Shi Jingyan Shi Yongjiu Shi Vitaly Shutov Andrey Sidorenkov FedorŠimkovic Chiara Sirignano Jaruchit Siripak Monica Sisti Maciej Slupecki Mikhail Smirnov Oleg Smirnov Thiago Sogo-Bezerra Julanan Songwadhana Boonrucksar Soonthornthum Albert Sotnikov Ondrej Sramek Warintorn Sreethawong Achim Stahl Luca Stanco Konstantin Stankevich DušanŠtefánik Hans Steiger Jochen Steinmann Tobias Sterr Matthias Raphael Stock Virginia Strati Alexander Studenikin Gongxing Sun Shifeng Sun Xilei Sun Yongjie Sun Yongzhao Sun Narumon Suwonjandee Michal Szelezniak Jian Tang Qiang Tang Quan Tang Xiao Tang Alexander Tietzsch Igor Tkachev Tomas Tmej Konstantin Treskov Andrea Triossi Giancarlo Troni Wladyslaw Trzaska Cristina Tuve Stefan van Waasen Johannes van den Boom Guillaume Vanroyen Nikolaos Vassilopoulos Vadim Vedin Giuseppe Verde Maxim Vialkov Benoit Viaud Cristina Volpe Vit Vorobel Lucia Votano Pablo Walker Caishen Wang Chung-Hsiang Wang En Wang Guoli Wang Jian Wang Jun Wang Kunyu Wang Lu Wang Meifen Wang Meng Wang Ruiguang Wang Siguang Wang Wei Wang Wenshuai Wang Xi Wang Xiangyue Wang Yangfu Wang Yaoguang Wang Yi Wang Yifang Wang Yuanqing Wang Yuman Wang Zhe Wang Zheng Wang Zhimin Wang Zongyi Wang Apimook Watcharangkool Lianghong Wei Wei Wei Yadong Wei Liangjian Wen Christopher Wiebusch Steven Chan-Fai Wong Bjoern Wonsak Diru Wu Fangliang Wu Qun Wu Wenjie Wu Zhi Wu Michael Wurm Jacques Wurtz Christian Wysotzki Yufei Xi Dongmei Xia Yuguang Xie Zhangquan Xie Zhizhong Xing Benda Xu Donglian Xu Fanrong Xu Jilei Xu Jing Xu Meihang Xu Yin Xu Yu Xu Baojun Yan Xiongbo Yan Yupeng Yan Anbo Yang Changgen Yang Huan Yang Jie Yang Lei Yang Xiaoyu Yang Yifan Yang Haifeng Yao Zafar Yasin Jiaxuan Ye Mei Ye Ugur Yegin Frédéric Yermia Peihuai Yi Xiangwei Yin Zhengyun You Boxiang Yu Chiye Yu Chunxu Yu Hongzhao Yu Miao Yu Xianghui Yu Zeyuan Yu Chengzhuo Yuan Ying Yuan Zhenxiong Yuan Ziyi Yuan Baobiao Yue Noman Zafar Andre Zambanini Pan Zeng Shan Zeng Tingxuan Zeng Yuda Zeng Liang Zhan Feiyang Zhang Guoqing Zhang Haiqiong Zhang Honghao Zhang Jiawen Zhang Jie Zhang Jingbo Zhang Peng Zhang Qingmin Zhang Shiqi Zhang Tao Zhang Xiaomei Zhang Xuantong Zhang Yan Zhang Yinhong Zhang Yiyu Zhang Yongpeng Zhang Yuanyuan Zhang Yumei Zhang Zhenyu Zhang Zhijian Zhang Fengyi Zhao Jie Zhao Rong Zhao Shujun Zhao Tianchi Zhao Dongqin Zheng Hua Zheng Minshan Zheng Yangheng Zheng Weirong Zhong Jing Zhou Li Zhou Nan Zhou Shun Zhou Xiang Zhou Jiang Zhu Kejun Zhu Honglin Zhuang Liang Zong Jiaheng Zou | 2021 | Chinese Physics C2021,45,2: | 0 |
| 10 | Virulence of Salmonella enterica Serovar Enteritidis Isolate LN-248-0 and Immune Responses in BALB/c Mice显示文摘Salmonella enterica serovar Enteritidis(S.Enteritidis)is a major etiological agent of acute gastroenteritis in humans;the mode of infection being consumption of undercooked or improperly handled poultry meat or contaminated eggs or milk[1,2].Among more than 2,600 serotypes of Salmonella,S.Enteritidis frequently causes Salmonella infections in humans[3]. | LIU Yang LI You Zhi FENG Tao GONG Pi Qian JIN Ying Cai ZHU Hong Wei JIANG Lin Lin ZHANG Jian Long CHEN Guo Zhong YU Xin ZHANG Xing Xiao | 2020 | Biomedical and Environmental Sciences2020,33,8: | 0 |
| 11 | Early weaning leads to the remodeling of lipid profile in piglet jejunal crypt cells during post-weaning days显示文摘Reportedly,proteins involved in lipid metabolism change significantly in the jejunal crypt cells of earlyweaned piglets,but the exact lipid profile change remains uncertain.In the present study,32 piglets weaned at 21 d of age were randomly divided into 4 groups with 8 replicates.The jejunal crypt cells of a group of piglets on the post-weaning day(PWD)1,3,7,and 14 were isolated per time point.Crypt cell lipid profiles were analyzed using ultra-high-performance liquid chromatography coupled with hybrid quadrupole time-of-flight mass spectrometry.This study showed that piglets suffered the greatest weaning stress on PWD 3 in terms of the lowest relative weight of the small intestine,the highest relative weight of the spleen,and the highest levels of malondialdehyde,cholesterol,and low-density lipoprotein cholesterol.The lipid profile of jejunal crypt cells including carnitine,sulfatide,sphingomyelin,hexosylceramide,and ceramide greatly changed after weaning,especially between PWD3 and 14(P<0.05).The differential lipid species between these 2 d were mainly involved in the glycerophospholipid metabolism pathway.In addition,potential lipid biomarkers for weaning stress in crypt cells such as phosphatidylcholine(PC)(9:0/26:1),PC(17:0/18:2),carnitine(24:0),carnitine(22:0),sphingomyelin(d14:1/22:0),PC(P-18:0/18:4),phosphatidylethanolamine(P-16:0/20:4),phosphatidylinositol(15:1/24:4),and dihexosylceramide(d14:1/26:1)were identified.The changes in lipid profile might be related to the inflammation caused by early weaning.These findings might provide new therapeutical targets for intestinal dysfunctions caused by weaning stress. | Yirui Shao Xia Xiong Kexing Wang Pi Cheng Lijun Zou Jian Zhou Ming Qi Yulong Yin | 2022 | Animal Nutrition2022,,4: | 0 |
| 12 | Insights into ionic association boosting water oxidation activity and dynamic stability显示文摘There have been reports about Fe ions boosting oxygen evolution reaction(OER)activity of Ni-based catalysts in alkaline conditions,while the origin and reason for the enhancement remains elusive.Herein,we attempt to identify the activity improvement and discover that Ni sites act as a host to attract Fe(Ⅲ)to form Fe(Ni)(Ⅲ)binary centres,which serve as the dynamic sites to promote OER activity and stability by cyclical formation of intermediates(Fe(Ⅲ)→Fe(Ni)(Ⅲ)→Fe(Ni)-OH→Fe(Ni)-O→Fe(Ni)OOH→Fe(Ⅲ))at the electrode/electrolyte interface to emit O_(2).Additionally,some ions(Co(Ⅱ),Ni(Ⅱ),and Cr(Ⅲ))can also be the active sites to catalyze the OER process on a variety of electrodes.The Fe(Ⅲ)-catalyzed overall water-splitting electrolyzer comprising bare Ni foam as the anode and Pt/Ni-Mo as the cathode demonstrates robust stability for 1600 h at 1000 mA cm^(-2)@~1.75 V.The results provide insights into the ioncatalyzed effects boosting OER performance. | Zanling Huang Shuqi Zhu Yuan Duan Chaoran Pi Xuming Zhang Abebe Reda Woldu Jing-Xin Jian Paul K.Chu Qing-Xiao Tong Liangsheng Hu Xiangdong Yao | 2024 | Journal of Energy Chemistry2024,89,2: | 0 |
| 13 | Gas-phase photocatalytic oxidation of benzene over titanium dioxide loaded on Bi_(12)TiO_(20)显示文摘TiO2 was prepared by sol-gel method using tetrabutyl titanate as precursor. TiO2 was loaded on Bi12TiO20. The photocatalyst with different TiO2 loading was calcined at 723 K. The photocatalytic activity of decomposition gaseous benzene was investigated in a batch reactor. The prepared photocatalyst was characterized by UV-vis diffuse reflectance. The result showed that TiO2/Bi12TiO20 absorbed much more ultraviolet light than Ti02 in the ultraviolet light region and showed red shift. The results indicated that the prepared photocatalyst can greatly promote the photocatalytic activity. The 2.0% TiO2/Bi12TiO20 system exhibited the highest photocatalytic activity. | Tao Lin, Zhan Pi, Mao Chu Gong, Jun Bo Zhong, Jian Li Wang, Yao Qiang Chen College of Chemistry, Sichuan University, Chengdu 610064, China | 2007 | Chinese Chemical Letters2007,18,2: | 0 |
| 14 | Copper-catalyzed asymmetric propargylic substitution of anthrones and propargylic esters显示文摘Anthrones are key structural motifs in many natural products, bioactive compounds and pharmaceutical chemicals. Earth-abundant-metal-catalyzed asymmetric functionalization of anthrones has not proved to be viable. Herein, we disclosed a highly enantioselective propargylic substitution of anthrones with propargylic esters using copper salts with chiral N, N, P-ligand. This strategy is amenable to a broad range of substrates, uses readily available starting materials, provides excellent yields with remarkable enantioselectivity under mild conditions, and enables attractive products diversification routes. | Zhiheng Li Danran Li Huaming Xiang Jian Huang Yinuo Zheng Cuiju Zhu Xiuling Cui Chao Pi Hao Xu | 2022 | Chinese Chemical Letters2022,33,2: | 0 |
| 15 | Fabrication of micro pin fins on inclined V-shaped microchannel walls via laser micromilling显示文摘A laser-micromilling process was developed for fabricating micro pin fins on inclined V-shaped microchannel walls for enhanced microchannel heat sinks.A pulsed nanosecond fiber laser was utilized.The feasibility and mechanism of the formation of micro pin fins on inclined microchannel walls were investigated for a wide range of processing parameters.The effects of the laser output power,scanning speed,and line spacing on the surface morphologies and geometric sizes of the micro-pin fins were comprehensively examined,together with the material removal mechanisms.Micro pin fins with acute cone tips were readily formed on the V-shaped microchannel walls via the piling of recast layers and the downflow of re-solidified materials in the laser-ablation process.The pin-fin height exhibited an increasing trend when the scanning speed increased from 100mm/s to 300 mm/s,and it decreased continuously when the line spacing increased from 5μm to 20μm.The optimal processing parameters for preparing micro pin fins on V-shaped microchannels were found to be a laser output power of 21 W,scanning speed of 100-300 mm/s,and line spacing of 2-5μm.Moreover,the V-shaped microchannels with micro pin fins induced a 7%-538%boiling heat-transfer enhancement over their counterpart without micro pin fins. | Da-Xiang Deng Jian Zheng Xiao-Long Chen Guang Pi Yong-Heng Liu | 2022 | Advances in Manufacturing2022,10,2: | 0 |