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| 1 | High performance octahedral PtNi/C catalysts investigated from rotating disk electrode to membrane electrode assembly显示文摘Octahedral PtNi/C catalysts have demonstrated superior catalytic performance in oxyge n reduction reacti on (ORR) over commercial Pt/C with rotating disk electrode (RDE). However, it is not trivial to translate such promising results to real-world membrane-electrode assembly (MEA). In this work, we have synthesized octahedral PtNi/C catalysts using poly(diallyldimethylammonium chloride)(PDDA) as a capping age nt and in vestigated their performance from RDE to MEA. In RDE, mass activity and specific activity of the optimized octahedral PtNi/C catalyst for oxygen reduction reaction (ORR) are nearly 19 and 28 times high of the state-of-the-art commercial Pt/C, respectively. At MEA level, the octahedral PtNi/C catalyst exhibits excelle nt power generation performa nee and durability paired with commercial Pt/C ano de. Its cell voltage at 1,000mA·cm^-2 reaches 0.712 V, and maximum power density is 881.6 mW·cm^-2 and its performance attenuation is also less, around 11.8% and 7% under galvanostatic condition of 1,000 mA·cm^-2 for 100 h. Such results are investiaged by thermodynamic analysis and fundametal performance modeling, which indicate the single cell performance can be further improved by reducing the size of PtNi/C catalyst agglomerates. Such encouraging results have demonstrated the feasibility to convey the superior performance of octahedral PtNi/C from RDE to MEA. | Bing Li Jue Wang Xin Gao Congwei Qin Daijun Yang Hong Lv Qiangfeng Xiao Cunman Zhang | 2019 | Nano Research2019，12，2： | 3 |
| 2 | The Controllable Design of Catalyst Inks to Enhance PEMFC Performance:A Review显示文摘Typical catalyst inks in proton exchange membrane fuel cells(PEMFCs)are composed of a catalyst,its support,an ionomer and a solvent and are used with solution processing approaches to manufacture conventional catalyst layers(CLs).Because of this,catalyst ink formulation and deposition processes are closely related to CL structure and performance.However,catalyst inks with ideal rheology and optimized electrochemical performances remain lacking in the large-scale application of PEMFCs.To address this,this review will summarize current progress in the formulation,characterization,modeling and deposition of catalyst inks.In addition,this review will highlight recent advancements in catalyst ink materials and discuss corresponding complex interactions.This review will also present various catalyst ink dispersion methods with insights into their stability and introduce the application of small-angle scattering and cryogenic transmission electron microscopy(cryo-TEM)technologies in the characterization of catalyst ink microstructures.Finally,recent studies in the kinetic modeling and deposition of catalyst inks will be analyzed. | Yuqing Guo Fengwen Pan Wenmiao Chen Zhiqiang Ding Daijun Yang Bing Li Pingwen Ming Cunman Zhang | 2021 | Electrochemical Energy Reviews2021，4，1： | 2 |
| 3 | Structural charaeterization of iridoid glucosides by ultra-performance liquid chromatography/electrospray ionization quadrupole time-of flight randem mass spectrometry显示文摘 | Li CunMan Zhang XiuLi Xue XingYa | 2008 | Rapid Commun Mass Spectrom2008，22，12： | 1 |
| 4 | Structural Characterization of Iridoid Glucosides by Ultra-performance Liquid Chromatography/electrospray Ionization Quadrupole Time of Flight Tandem Mass Spectrometry显示文摘 | LI Cunman ZHANG Xiuli XUE Xingya | 2008 | Rapid Commun Mass Spectrom2008，22，12： | 1 |
| 5 | Analysis of Iridoid Glucosides in Hedyotis Diffusa by High-performance Liquid Chromatography/electrospray Ionization Tandem Mass Spectrometry显示文摘 | LI Cunman XUE Xingya ZHOU Dayong | 2008 | Journal of Pharmaceutical and Biomedical Analysis2008，48，： | 1 |
| 6 | Analysis of iridoid glucosides in Hedyotis diffusa by high-perform- ance liquidchromatography/electrospray ionization tan- dem mass spectrometry显示文摘 | Cunman Li Xingya Xue Dayong Zhou | 2008 | J Pharmaceut Biomed Anal2008，48，： | 1 |
| 7 | Accelerated Test of Silicone Rubbers Exposing to PEMFC environment显示文摘The durability of sealing material is one of the major challenges to the overall lifetime of proton exchange membrane fuel cell(PEMFC).In order to study the failure mode and aging mechanism of fuel cell seals,this paper focuses on the most widely used commercial silicone rubber,and an ex-situ accelerated aging method was employed by simulating the circumstance of PEMFC,including higher temperature and clamping force,lower p H value and F-with higher concentration.The main factors that affect the performance of the seal were obtained through the test of their morphologies and mechanical properties.The failure mode of the aging mechanism of the rubbers were analyzed through scanning electron microscopy(SEM),energy dispersive spectrometer(EDS),attenuated-total-reflection infrared spectroscopy(ATR-IR),mass loss,compression set(CS),etc.It was found that temperature played an important role in the deterioration of seal performance,and the change of the parameters of the compression set with time conformed the dynamic empirical formula,which provides the experimental basis for the lifetime prediction of the seals. | Daijun Yang Jingwen Ma Qing Zhang Bing Li Pingwen Ming Cunman Zhang | 2020 | Progress in Natural Science:Materials International2020，30，6： | 0 |
| 8 | Development of advanced anion exchange membrane from the view of the performance of water electrolysis cell显示文摘Green hydrogen produced by water electrolysis combined with renewable energy is a promising alternative to fossil fuels due to its high energy density with zero-carbon emissions.Among water electrolysis technologies,the anion exchange membrane(AEM) water electrolysis has gained intensive attention and is considered as the next-generation emerging technology due to its potential advantages,such as the use of low-cost non-noble metal catalysts,the relatively mature stack assembly process,etc.However,the AEM water electrolyzer is still in the early development stage of the kW-level stack,which is mainly attributed to severe performance decay caused by the core component,i.e.,AEM.Here,the review comprehensively presents the recent progress of advanced AEM from the view of the performance of water electrolysis cells.Herein,fundamental principles and critical components of AEM water electrolyzers are introduced,and work conditions of AEM water electrolyzers and AEM performance improvement strategies are discussed.The challenges and perspectives are also analyzed. | Chao Liu Zhen Geng Xukang Wang Wendong Liu Yuwei Wang Qihan Xia Wenbo Li Liming Jin Cunman Zhang | 2024 | Journal of Energy Chemistry2024，90，3： | 0 |
| 9 | Pt‑Based Intermetallic Compound Catalysts for the Oxygen Reduction Reaction:Structural Control at the Atomic Scale to Achieve a Win–Win Situation Between Catalytic Activity and Stability显示文摘The development of ordered Pt-based intermetallic compounds is an effective way to optimize the electronic characteristics of Pt and its disordered alloys,inhibit the loss of transition metal elements,and prepare fuel cell catalysts with high activity and long-term durability for the oxygen reduction reaction(ORR).This paper reviews the structure–activity characteristics,research advances,problems,and improvements in Pt-based intermetallic compound fuel cell catalysts for the ORR.First,the structural characteristics and performance advantages of Pt-based intermetallic compounds are analyzed and explained.Second,starting with 3d transition metals such as Fe,Co,and Ni,whose research achievements are common,the preparation process and properties of Pt-based intermetallic compound catalysts for the ORR are introduced in detail according to element types.Third,in view of preparation problems,improvements in the preparation processes of Pt-based intermetallic compounds are also summarized in regard to four aspects:coating to control the crystal size,doping to promote ordering transformation,constructing a“Pt skin”to improve performance,and anchoring and confinement to enhance the interaction between the crystal and support.Finally,by analyzing the research status of Pt-based intermetallic compound catalysts for the ORR,prospective research directions are suggested. | Jue Wang Fengwen Pan Wenmiao Chen Bing Li Daijun Yang Pingwen Ming Xuezhe Wei Cunman Zhang | 2023 | Electrochemical Energy Reviews2023，6，1： | 0 |
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