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| 1 | CO2电还原用氮掺杂碳基过渡金属单原子催化剂显示文摘温和条件下将CO2电催化还原(CO2RR)为高能量密度燃料和高附加值碳产品是降低大气中CO2浓度、储存间歇性可再生能源、实现碳中和的重要途径之一。设计和开发对电催化CO2RR兼具高活性、高选择性、高稳定性、且对析氢反应(HER)具有显著抑制作用的高性能廉价催化剂是CO2RR研究的关键。单原子催化剂(SACs)由于其独特的电子结构和几何结构对许多重要化学反应(如CO氧化反应、加氢反应、析氧反应、氧还原反应、析氢反应等)显示出优异的催化活性而广受关注。近年来,N掺杂多孔碳载体过渡金属单原子催化材料(M-N-C)显示出对电化学二氧化碳还原的广阔前景、并有望成为在水相电解质中还原CO2的贵金属(Au,Ag)催化剂的替代品。本文从单原子催化材料M-N-C的制备、影响电催化性能的因素及MNx活性基团三个方向介绍了单原子催化剂M-N-C电催化CO2RR的研究现状和进展。最后,就目前该方向研究中尚待解决的问题进行了总结、并对下一步的研究进行了展望。 | 朱红林 李文英 黎挺挺 Michael Baitinger Juri Grin 郑岳青 | 2019 | 化学进展2019，31，7： | 8 |
| 2 | Monitoring dioxins and PCBs in eggs as sensitive indicators for environmental pollution and global contaminated sites and recommendations for reducing and controlling releases and exposure显示文摘This review compiles information on PCDD/F-and PCB-contaminated eggs from 20 years of global egg monitoring around emission sources in four continents conducted by the International Pollutants Elimination Network(IPEN)and Arnika as well as a compilation of data from scientific literature.IPEN monitored 127 pooled egg samples including samples from 113 chicken flocks at potential PCDD/F-and PCB-contaminated sites around priority sources listed in the Stockholm Convention(e.g.waste incinerators,metal industries,cement plants,and open burning).99(88%)of pooled egg samples were above the EU maximum limits for PCDD/Fs(2.5 pg PCDD/F-TEQ/g fat)or the sum of PCDD/Fs and dioxinlike PCBs(5 pg PCDD/F-PCB-TEQ/g fat).Children consuming such eggs exceed the tolerable weekly intake(TWI).This demonstrates that close to 90%of these areas were not safe for the production of free-range eggs.Sixteen out of the 113 egg samples(14%)were contaminated above 50 pg TEQ/g fat and exceeded the EU maximum limit more than 10 times.From the 26 pooled egg samples around incinerators 24(92%)exceeded the limit with a mean of 43.1 pg TEQ/g fat(2.6e234 pg TEQ/g).All 21 egg samples around metal industries(4.4e112.6 pg TEQ/g fat)were above limits with mean concentration of 26.0 pg TEQ/g fat.Also all 7 egg samples measured at e-waste recycling sites were above limits(mean 308 pg TEQ/g fat).In 58(51%)pooled egg samples the PCB-TEQ was above 5 pg TEQ/g fat exceeding the EU maximum limit with dioxin-like PCBs alone.This highlights the role of commercial PCBs for global contamination with dioxin-like compounds.It was discovered that around metal industries,shredder plants,open burning sites of e-waste and dump sites,a high share of contamination was caused by dl-PCBs.This clearly shows severe PCB release from the end-of-life management of PCB-containing equipment in developing countries.Also highly contaminated eggs were found at many sites where plastic was incinerated.The highest contaminated egg sample ever measured came from an e-waste site in Ghana and had 856 pg TEQ/g fat plus 300 pg TEQ from brominated dioxins(PBDD/Fs).Other extreme PCDD/F contaminations of eggs were found at a chlor-alkali site(514 pg TEQ/g fat),Agent Orange contaminated areas in Vietnam(490,249 and 246 pg TEQ/g fat)and e-waste sites(568 and 520 pg TEQ/g fat).Where DR CALUX®bioassay revealed higher TEQ compared to measured PCDD/F-PCB-TEQ in IPEN studies,polybrominated PBDD/F were also measured and detected up to 300 pg TEQ/g fat at e-waste sites.One positive outcome from the IPEN studies is that all 10 pooled supermarket eggs in developing countries were below regulatory limit.Policy recommendations are made including:a systematic assessment of areas around PCDD/Fs and PCBs sources;measures for reduction of exposures of populations;urgent control of emission sources including PCB equipment,the open burning of plastic,and the use of plastic as fuel in boilers/incinerators in developing countries without air pollution control.Furthermore,soil limits need to be re-assessed and lowered for free-range poultry. | Jindrich Petrlik Lee Bell Joe DiGangi Serge Molly Allo'o Allo'o Gilbert Kuepouo Griffins Ochieng Ochola Valeriya Grechko Nikola Jelinek Jitka Strakova Martin Skalsky Yuyun Ismawati Drwiega Jonathan N.Hogarh Eric Akortia Sam Adu-Kumi Akarapon Teebthaisong Maria Carcamo Bjorn Beeler Peter Behnisch Claudia Baitinger Christine Herold Roland Weber | 2022 | Emerging Contaminants2022，8，1： | 2 |
| 3 | The clinical performance of porcelain-fused-to-metal precious alloy singlecrowns: chipping, recurrent caries,periodontitis, and loss of retention显示文摘 | Behr M Zeman F Baitinger T | 2014 | Prosthodont2014，27，2： | 1 |
| 4 | A new structural model of glasslike carbon 显示文摘 | Pesin L A Baitinger E M | 2002 | Carbon2002，40，3： | 1 |
| 5 | Salmeterol response is not affected by 2-adrenergic receptor genotype in subjects with persistent asthma 显示文摘 | Bleeckcr ER Yancey SW Baitinger LA | 2006 | J Allergy Clin Immunol2006，118，4： | 1 |
| 6 | Impact of repeated intravenous bone marrow mesenchymal stem cells infusion on myocardial collagen network remodeling in a rat model of doxorubicin-induced dilated cardiomyopathy显示文摘 | Qin Yu Qianxiao Li Rongmei Na Xiaofei Li Baiting Liu Lili Meng Hanyu Liutong Weiyi Fang Ning Zhu Xiaoqun Zheng | 2014 | Molecular and Cellular Biochemistry (-)2014，，1： | 1 |
| 7 | Salmeterol response isnot affected byβ2-adrenergic receptor genotype in subjects with per-sistent asthma显示文摘 | Bleecker E Yancey SW Baitinger LA | 2006 | J Allergy Clin Immunol2006，118，4： | 1 |
| 8 | A new structural model of glasslike carbon 显示文摘 | Pesin L A Baitinger E M | 2002 | Carbon2002，40，3： | 1 |
| 9 | Thermoelectric properties of Eu(Zn1-xCd02Sb2 显示文摘 | ZHANG H BAITINGER M TANG M B | 2010 | Dalton Transactions2010，39，： | 1 |
| 10 | A new structural model of glasslike carbon显示文摘 | Baitinger EM | 2002 | Carbon2002，40，3： | 1 |
| 11 | A new structural model of glass-like carbon显示文摘 | PesinLA Baitinger EM | 2002 | Carbon2002，40，3： | 1 |
| 12 | A new structural model of glasslike carbon显示文摘 | Pesin L A Baitinger E M | 2002 | Carbon2002，40，3： | 1 |
| 13 | A new structural model of glasslike carbon 显示文摘 | Pesin L A Baitinger E M | 2002 | Carbon2002，40，3： | 1 |
| 14 | Crystal structure of the defect clathrate Cs8Sn44□2显示文摘 | von Schnering H.G Kroner R Baitinger M Peters K Nesper R Grin Y.Z | | 0，，： | 1 |
| 15 | In vivo requirement for RecJ,Exo Ⅶ,Exo I,and Exo X in methyl-directed mismatch repair显示文摘 | Burdett V Baitinger C Viswanathan M | 2001 | Proc Natl Acad Sci USA2001，9802，： | 1 |
| 16 | Salmeterol response is not affected by beta2-adrenergic receptor genotype in subjeetswith persistent asthma显示文摘 | Bleeeker ER Yaneey SW Baitinger LA | 2006 | J Allcrgy Clin Immunol2006，118，4： | 1 |
| 17 | A new structural model of glass - like carbon 显示文摘 | L A PESIN E M BAITINGER | 2002 | Carbon2002，40，： | 1 |
| 18 | Fire retardance treatment of fabric for the 80 s:smolder resistant cotton treated with boric acid显示文摘 | BAITINGER W F | 1982 | Textile Research Journal1982，，1： | 1 |
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