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1篇 您的检索式:作者名="Tulloch Gavin"
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1Improved crystallinity and self-healing effects in perovskite solar cells via functional incorporation of polyvinylpyrrolidone显示文摘Air moisture is the key issue for perovskites which invades the films and accelerates the damage of devices. Here, polyvinylpyrrolidone(PVP) is introduced to the methylammonium lead iodide(MAPbI_(3)) perovskite precursor to control crystal growth and endow the devices with self-healing ability in a moisture environment. The strong C=O...ΗAΝ hydrogen bonding interactions between PVP and MAPbI_(3) was confirmed by nuclear magnetic resonance measurements. By introducing hydrogen bonding in the MAPbI_(3)-based PSCs, we form a compact perovskite film of excellent electronic quality with a power conversion efficiency(PCE) of up to 20.32%. Furthermore, the O...ΗAΝ hydrogen bonding interactions at the grain boundaries suppress the decomposition of methylammonium cations and improve the recyclable dissolution–recrystallization of perovskite. As a result, the MAPbI_(3)-PVP based cells exhibited striking moisture stability and self-healing behavior, with negligible decay in efficiency after 500 h of operation in high humidity(65% ± 5% relative humidity) and rapid recovering ability after their removal from the humid environment.Yunjuan Niu Dingchao He Zhengguo Zhang Jun Zhu Tulloch Gavin Polycarpos Falaras Linhua Hu 2022Journal of Energy Chemistry2022,31,5:1
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