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| 1 | 2D CoOOH Sheet-Encapsulated Ni2P into Tubular Arrays Realizing 1000 mA cm^-2-Level-Current-Density Hydrogen Evolution Over 100 h in Neutral Water显示文摘Water electrolysis at high current density(1000 mA cm-2 level)with excellent durability especially in neutral electrolyte is the pivotal issue for green hydrogen from experiment to industrialization.In addition to the high intrinsic activity determined by the electronic structure,electrocatalysts are also required to be capable of fast mass transfer(electrolyte recharge and bubble overflow)and high mechanical stability.Herein,the 2D CoOOH sheet-encapsulated Ni2P into tubular arrays electrocatalytic system was proposed and realized 1000 mA cm-2-levelcurrent-density hydrogen evolution over 100 h in neutral water.In designed catalysts,2D stack structure as an adaptive material can buffer the shock of electrolyte convection,hydrogen bubble rupture,and evolution through the release of stress,which insure the long cycle stability.Meanwhile,the rich porosity between stacked units contributed the good infiltration of electrolyte and slippage of hydrogen bubbles,guaranteeing electrolyte fast recharge and bubble evolution at the high-current catalysis.Beyond that,the electron structure modulation induced by interfacial charge transfer is also beneficial to enhance the intrinsic activity.Profoundly,the multiscale coordinated regulation will provide a guide to design high-efficiency industrial electrocatalysts. | Shucong Zhang Wenbin Wang Feilong Hu Yan Mi Shuzhe Wang Youwen Liu Xiaomeng Ai Jiakun Fang Huiqiao Li Tianyou Zhai | 2020 | Nano-Micro Letters2020,12,10: | 3 |
| 2 | Nanovilli electrode boosts hydrogen evolution:A surface with superaerophobicity and superhydrophilicity显示文摘Although tremendous efforts have been paid on electrocatalysts toward efficient electrochemical hydrogen generation,breakthrough is still highly needed in the design and synthesis of wonderful non-precious-metal electrocatalyst.Herein,a nanovilli Ni2P electrode,which with superaerophobic and superhydropholic can significantly facilitate the mass and electron transfer was constructed via a facial morphology control strategy.Meanwhile,the substitution of sluggish oxygen evolution with urea oxidation,lowering the two-electrode cell voltage to only 1.48 volts to achieve a current density of 10 mA·cm^(-2).Thus,the as-constructed electrode achieves the operation of hydrogen generation by an AA battery.This work sheds new light on the exploration of other high-efficient electrocatalysts for hydrogen generation by using intermittent clean energy. | Yijun Yin Yan Tan Qiuyuan Wei Shucong Zhang Siqi Wu Qin Huang Feilong Hu Yan Mi | 2021 | Nano Research2021,14,4: | 3 |
| 3 | In vitro apatite formation and its growth kinetics on hydroxyapatite/polyetheretherketone biocomposites显示文摘 | Shucong Yu Kithva Prakash Hariram Rajendra Kumar Philip Cheang Khor Khiam Aik | 2004 | Biomaterials2004,,15: | 1 |
| 4 | Semiparametric quantile-difference estimation for length-biased and right-censored data显示文摘Prevalent cohort studies frequently involve length-biased and right-censored data, a fact that has drawn considerable attention in survival analysis. In this article, we consider survival data arising from lengthbiased sampling, and propose a new semiparametric-model-based approach to estimate quantile differences of failure time. We establish the asymptotic properties of our new estimators theoretically under mild technical conditions, and propose a resampling method for estimating their asymptotic variance. We then conduct simulations to evaluate the empirical performance and efficiency of the proposed estimators, and demonstrate their application by a real data analysis. | Yutao Liu Shucong Zhang Yong Zhou | 2019 | Science China Mathematics2019,62,9: | 1 |
| 5 | Characteristics and Mechanism of Modified Triethanolamine as Cement Grinding Aids显示文摘Effects of modified triethanolamine as cement grinding aids on particles characteristics and mechanical property of cement were studied, and its reaction mechanism was analyzed by IR, Zeta potential, SEM, XRD and TG-DTA. The results show that the content of 3-32 μm particles for cement with 0.015% modified triethanolamine(M-TEA) is increased by 12.4%, and the compressive strengths of cement with 0.03% M-TEA are increased by 5.5 and 8.2 MPa at 3 and 28 days, respectively. And both the grinding and enhancement effects of M-TEA on cement are better than triethanolamine. The mechanism analysis shows that M-TEA not only has the amino and hydroxyl groups of TEA, but also has the ester, carbonyl, carboxyl groups which easily combine with metal ions of cement minerals, resulting in that M-TEA can promote surface adsorption and shield the unsaturated charges in the surface and crack section of particles, thus particles reunion is prevented and grinding efficiency is improved. Enhancement of M-TEA on cement mainly lies in that it can promote or induce hydration reaction of cement mineral with gypsum and water, which accelerates formation of hydration products, and then improves the structure and morphology of cement hydration products, thus the uniformity and compactness of product structure is increased. | 赵计辉 王栋民 WANG Xueguang LIAO Shucong | 2015 | Journal of Wuhan University of Technology(Materials Science)2015,30,1: | 0 |
| 6 | Controllable Ni/NiO interface engineering on N-doped carbon spheres for boosted alkaline water-to-hydrogen conversion by urea electrolysis显示文摘Interface engineering has gradually attracted substantial research interest in constructing active bifunctional catalysts toward urea electrolysis.The fundamental understanding of the crystallinity transition of the components on both sides of the interface is extremely significant for realizing controllable construction of catalysts through interface engineering,but it still remains a challenge.Herein,the Ni/NiO heterogenous nanoparticles are successfully fabricated on the porous N-doped carbon spheres by a facile hydrothermal and subsequent pyrolysis strategy.And for the first time we show the experimental observation that the Ni/NiO interface can be fine-tuned via simply tailoring the heating rate during pyrolysis process,in which the crystalline/amorphous or crystalline/crystalline Ni/NiO heterostructure is deliberately constructed on the porous N-doped carbon spheres(named as CA-Ni/NiO@NCS or CC-Ni/NiO@NCS,respectively).By taking advantage of the unique porous architecture and the synergistic effect between crystalline Ni and amorphous NiO,the well-designed CA-Ni/NiO@NCS displays more remarkable urea oxidation reaction(UOR)and hydrogen evolution reaction(HER)activity than its crystalline/crystalline counterpart of CC-Ni/NiO@NCS.Particularly,the whole assembled two-electrode electrolytic cell using the elaborate CANi/NiO@NCS both as the anode and cathode can realize the current density of 10 mA·cm^(−2)at a super low voltage of 1.475 V(264 mV less than that of pure water electrolysis),as well as remarkable prolonged stability over 63 h.Besides,the H_(2)evolution driven by an AA battery and a commercial solar cell is also studied to enlighten practical applications for the future. | Xiujuan Xu Xianbiao Hou Puyu Du Canhui Zhang Shucong Zhang Huanlei Wang Arafat Toghan Minghua Huang | 2022 | Nano Research2022,15,8: | 0 |
| 7 | Relative fitness of susceptible and Cry1A.105/Cry2Ab2-single-/dual-protein-resistant Helicoverpa zea (Boddie) (Lepidoptera: Noctuidae) on non-Bt diet and a diet containing a low concentration of two proteins显示文摘Helicoverpa zea(Boddie)is a destructive agricultural pest species that is targeted by both Bacillus thuringiensis(Bt)maize and cotton in the United States.Cry1A.105 and Cry2Ab2 are two Bt proteins expressed in a widely planted maize event MON 89034.In this study,two tests(Test-Ⅰ and Test-Ⅱ)were conducted to evaluate the relative fitness of Bt-susceptible and-resistant H.zea on non-Bt diet(Test-Ⅰ and Test-Ⅱ)and a diet containing a mix of Cry1A.105 and Cry2Ab2 at a low concentration(Test-Ⅱ only).Insect populations evaluated in Test-Ⅰ were two Bt-susceptible strains and three Bt-resistant strains(a single-protein Cry1A.105-,a single-protein Cry2Ab2-,and a dual-protein Cry1A.105/Cry2Ab2-resistant strains).Test-Ⅱ analyzed the same two susceptible strains,three backcrossed-and-reselected Cry1A.105/Cry2Ab2-single-/dual-protein-resistant strains,and three F1 heterozygous strains.Measurements of life table parameters showed that neither the single-nor dual-protein Cry1A.105/Cry2Ab2 resistance in H.zea was associated with fitness costs under the test conditions.The single Cry protein resistances at a concentration of a mix of Cry1A.105 and Cry2Ab2 that resulted in a zero net reproductive rate for the two susceptible strains were functionally incomplete recessive or codominant,and the dual-protein resistance was completely dominant.The lack of fitness costs could be a factor contributing to the rapid revolution of resistance to the Cry proteins in this species.Data generated from this study should aid our understanding of Cry protein resistance evolution and help in refining IRM programs for H.zea. | Shucong Lin Graham Head Paula Price Ying Niu Fangneng Huang | 2023 | Insect Science2023,30,2: | 0 |
| 8 | Clinical correlations with disease-associated auto-antibodies in a Chinese cohort with systemic sclerosis显示文摘To the Editor:Systemic sclerosis(SSc)is an autoimmune disease characterized by,progressive skin and visceral fibrosis,microvasculopathy,and autoimmunity.Circulating auto-antibodies(AAbs)are detectable in 90%to 95%of patients with SSc. | Sen Yang Minrui Liang Chen Chen Wenjing Ye Xiaoxia Zhu Yu Xue Ning Kong Yiyun Yu Dandan Xuan Shucong Zheng Xue Yang Zaihua Zhu Tianyi Zhao Weiguo Wan Hejan Zou | 2022 | Chinese Medical Journal2022,,15: | 0 |
| 9 | Wireless Self-Powered Vibration Sensor System for Intelligent Spindle Monitoring显示文摘In recent years,high-end equipment is widely used in industry and the accuracy requirements of the equipment have been risen year by year.During the machining process,the high-end equipment failure may have a great impact on the product quality.It is necessary to monitor the status of equipment and to predict fault diagnosis.At present,most of the condition monitoring devices for mechanical equipment have problems of large size,low precision and low energy utilization.A wireless self-powered intelligent spindle vibration acceleration sensor system based on piezoelectric energy harvesting is proposed.Based on rotor sensing technology,a sensor is made to mount on the tool holder and build the related circuit.Firstly,the energy management module collects the mechanical energy in the environment and converts the piezoelectric vibration energy into electric energy to provide 3.3 Vfor the subsequent circuit.The lithium battery supplies the system with additional power and monitors’the power of the energy storage circuit in real-time.Secondly,a three-axis acceleration sensor is used to collect,analyze and filter a series of signal processing operations of the vibration signal in the environment.The signal is sent to the upper computer by wireless transmission.The host computer outputs the corresponding X,Y,and Z channel waveforms and data under the condition of the spindle speed of 50∼2500 r/min with real-time monitoring.The KEIL5 platform is used to develop the system software.The small-size piezoelectric vibration sensor with high-speed,high-energy utilization,high accuracy,and easy installation is used for spindle monitoring.The experiment results show that the sensor system is available and practical. | Lei Yu Hongjun Wang Yubin Yue Shucong Liu Xiangxiang Mao Fengshou Gu | 2023 | Structural Durability & Health Monitoring2023,17,4: | 0 |
| 10 | Interface engineering of NiSe_(2) nanowrinkles/Ni_(5)P_(4)nanorods for boosting urea oxidation reaction at large current densities显示文摘Deliberate modulation of the electronic structure via interface engineering is one of promising perspectives to build advanced catalysts for urea oxidation reaction(UOR)at high current densities.However,it still remains some challenges originating from the intrinsically sluggish UOR dynamics and the high energy barrier for urea adsorption.In response,we report the coupled NiSe_(2)nanowrinkles with Ni_(5)P_(4)nanorods heterogeneous structure onto Ni foam(denoted as NiSe_(2)@Ni_(5)P_(4)/NF)through successive phosphorization and selenization strategy,in which the produced closely contacted interface could provide high-flux electron transfer pathways.Theoretical findings decipher that the fast charge transfer takes place at the interfacial region from Ni_(5)P_(4)to NiSe_(2),which is conducive to optimizing adsorption energy of urea molecules.As expected,the well-designed NiSe_(2)@Ni_(5)P_(4)/NF only requires the low potential of 1.402 V at the current density of 500 mA·cm^(-2).More importantly,a small Tafel slope of 27.6 mV·dec^(-1),a high turnover frequency(TOF)value of 1.037 s^(-1)as well as the prolonged stability of 950 h at the current density of 100 mA·cm^(-2)are also achieved.This study enriches the understanding on the electronic structure modulation via interface engineering and offers bright prospect to design advanced UOR catalysts. | Jinyang Li Xiujuan Xu Xianbiao Hou Shucong Zhang Ge Su Weiqian Tian Huanlei Wang Minghua Huang Arafat Toghan | 2023 | Nano Research2023,16,7: | 0 |