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| 1 | Promoted effect of zinc–nickel bimetallic oxides supported on HZSM-5 catalysts in aromatization of methanol显示文摘Zn/ZSM-5(NZ2) and Zn/Ni/ZSM-5(NZ3) as the catalysts for methanol to aromatics(MTA) were synthesized by a simple ultrasonic impregnation. The textural and acid properties of all catalysts were characterized using XRD, HRTEM, NH_3-TPD, Py-IR, XPS, XRF and TG techniques. The XRD and HRTEM results showed that the basic zeolite structures were not affected much with the incorporation of Zn and Ni species. However, great changes have taken place in acid properties. The Py-IR and XPS results indicated that the Zn-Lewis acid sites(ZnOH^+ species), which have stronger interaction with the zeolite framework compared with ZnO species, were generated at the expense of B acid sites with the incorporation of zinc species. Moreover, the product analysis results showed that the incorporation of zinc species promoted the primary aromatization by enhancing the dehydroaromatization and suppressing the cracking and subsequent H-transfer reaction. Furthermore, the addition of Ni species well inhibited the loss of zinc species by converting partial ZnO species to ZnOH^+ species, and thus improved the aromatization activity and catalyst stability. The catalytic performance results showed that the NZ3 possess higher conversion of methanol in a longer time and lower average rate of coke formation compared with NZ2. In addition,the NZ3 also exhibited the highest yield of BTX as the reaction proceeds. | Yanming Jia Junwen Wang Kan Zhang Wei Feng Shibin Liu Chuanmin Ding Ping Liu | 2017 | Journal of Energy Chemistry2017，26，3： | 7 |
| 2 | Self-sacrificial templating synthesis of flower-like nickel phyllosilicates and its application as high-performance reinforcements in epoxy nanocomposites显示文摘The nanocomposites of flower-like nickel phyllosilicate particles incorporated into epoxy resin were fabricated via an in-situ mixing process.The flower-like nickel phyllosilicate particles were firstly synthesized using a mild self-sacrificial templating method,and the morphology and lamellar structure were examined carefully.Several properties of mechanical,thermal and tribological responses of epoxy nanocomposites were performed.It was demonstrated that adequate flower-like nickel phyllosilicate particles dispersed well in the matrix,and the nanocomposites displayed enhanced tensile strength and elastic modulus but decreased elongation at break as expected.In addition,friction coefficient and wear rate were increased first and then decreased along with the particle content,and showed the lowest values at a mass fraction of 5%.Nevertheless,the incorporated flower-like nickel phyllosilicate particles resulted in the continuously increasing thermal stability of epoxy resin(EP)nanocomposites.This study revealed the giant potential of flower-like particles in preparing high-quality EP nanocomposites. | Jinian Yang Xuesong Feng Shibin Nie Yuxuan Xu Zhenyu Li | 2022 | Frontiers of Chemical Science and Engineering2022，16，4： | 2 |
| 3 | Flexible optoelectronic devices based on metal halide perovskites显示文摘The unique physical and chemical properties of metal halide perovskites predestine the devices to achieve high performance in optoelectronic field.Among the numerous high qualities of perovskites,their different low-temperature synthesis methods and preparation processes make them impressive and popular materials for flexible optoelectronic devices.Mainstream perovskite devices,for instance,solar cells,photodetectors and light-emitting diodes,have been fabricated on flexible substrates and show outstanding flexibility as well as high performance.For soft wearable electronic systems,mechanical flexibility is the premier condition.Compared to common devices based on rigid substrates,flexible perovskite devices are more practical and see widespread applications in energy,detection,display,and other fields.This review summarizes the recent progress of flexible perovskite solar cells,photodetectors and light-emitting diodes.The design and fabrication of different high-performance flexible perovskite devices are introduced.Various low-dimensional perovskite materials and configurations for flexible perovskite devices are presented.In addition,the limitations and challenges for further application are also briefly discussed. | Hao Chen Hao Wang Jiang Wu Feng Wang Ting Zhang Yafei Wang Detao Liu Shibin Li Richard V.Penty Ian H.White | 2020 | Nano Research2020，13，8： | 2 |
| 4 | Mechanical and antibacterial properties of tannic acid-encapsulated carboxymethyl chitosan/polyvinyl alcohol hydrogels显示文摘The objective of this study was to develop an effective,potential wound dressing,which was constructed with a composite hydrogel of poly(vinyl alcohol)(PVA),carboxymethyl chitosan(CMC)and tannic acid(TA)by cryogenic treatment and freeze-drying method.The as-prepared TA-crosslinked PVA/CMC hydrogels exhibited interconnected pore structure with the mean pore size of roughly 3.7��m.We found that the compressive strength and stiffness of composite hydrogel increased when the TA component was introduced.However,the PVA/CMC-TA hydrogel possessed obviously lower swell property than that of the TA-free PVA/CMC hydrogel.We also found that the TA addition significantly improved the antibacterial capacity of the as-prepared hydrogel.Moreover,the inhibition zone test showed that the antibacterial activity of PVA/CMC-TA against S.aureus bacteria was greater than that against E.coli.The biological results indicated that the PVA/CMC-TA hydrogel exhibited good cytocompatibility to natural human dermal fibroblasts.In summary,our PVA/CMC-TA composite hydrogel exhibited promising mechanical and antibacterial properties,which showed great potential application as wound healing materials. | Xiaofan Feng Xiuling Hou Congjing Cui Shibin Sun Sahiya Sadik Shaohua Wu Fang Zhou | 2021 | Engineered Regeneration2021，2，1： | 2 |
| 5 | Enhancement of oxygen reduction activity and stability via introducing acid-resistant refractory Mo and regulating the near-surface Pt content显示文摘Although Pt Ni catalyst possesses good oxygen reduction activity, its poor stability is the main obstacle for the commercialization of proton exchange membrane fuel cells(PEMFCs). In this work, we introduce the acid-resistant refractory Mo to enhance the structure stability and modify the electronic structure of Pt in the prepared PtNi catalyst, improving the catalytic activity for oxygen reduction reaction(ORR). In addition, near-surface Pt content in the nanoparticle is also optimized to balance the ORR activity and stability. The electrochemical results show that the alloy formed by Mo and Pt Ni is obviously more stable than the PtNi alloy alone, because the acid-resistant Mo and its oxides effectively prevent the dissolution of Pt. Especially, the Pt3 Ni3 MoN/C exhibits the optimal ORR catalytic performance in O2-saturated 0.1 mol L^(-1) HClO4 aqueous solutions, with mass activity(MA) of 900 m A mg^(-1) Pt at 0.90 V vs. RHE, which is 3.75 times enhancement compared with the commercial Pt/C(240 mA mg^(-1) Pt). After 30 k accelerated durability tests, its MA(690 m A mg^(-1) Pt) is still 2.88 times higher than the pristine Pt/C. This study thus provides a valuable method to design stable ORR catalysts with high efficiency and has great significance for the commercialization of PEMFCs. | Shouquan Feng Jiajia Lu Lin Luo Guangfu Qian Jinli Chen Hanna SAbbo Salam JJTitinchi Shibin Yin | 2020 | Journal of Energy Chemistry2020，29，12： | 2 |
| 6 | Fabricating Cationic Lignin Hydrogels for Dye Adsorption显示文摘Due to the low content of adsorption-active groups in lignin,its application in the field of adsorption is limited.Herein,we first prepared cationic kraft lignin acrylate,from which a cationic lignin(CKLA)hydrogel was further prepared by cationic kraft lignin acrylate,acrylamide,and N,N’-methylenebisacrylamide.The morphology,compression properties and swelling properties of CKLA hydrogels were investigated.The prepared CKLA hydrogel was applied as an adsorbent for Congo red.The effect of CKLA hydrogel dosages,initial concentration of Congo red,and pH on adsorption efficiency was investigated.The maximum Congo red removal efficiency was obtained at the initial concentration of Congo red of 50 mg/L,pH 7,and 5 mg dosage of CKLA hydrogel with 20%cationic lignin content.After five cycles of adsorption,the adsorption efficiency of the hydrogel for Congo red still reached more than 80%.The CKLA hydrogel showed pseudo-second-order adsorption kinetics for Congo red adsorption.These results demonstrate the potential of the CKLA hydrogel as an adsorbent for water treatment. | Chao Wang Xuezhen Feng Wanbing Li Shibin Shang Haibo Zhang | 2023 | Journal of Renewable Materials2023，11，4： | 1 |
| 7 | Investigation on flame retardancy and thermal degradation of flame retardant poly(butylene suceinate)/bam- boo fiber biocomposites显示文摘 | Nie Shibin Liu Xueli Dai Guanglong Yuan Shujie Cai Feng Li Benxia Hu Yuan | 2012 | Journal of Applied Polymer Sci enee2012，125，： | 1 |
| 8 | Tea Polyphenols Reducing Lipopolysaccharide-induced Inflammatory Responses in RAW264.7 Macrophages via NF-κB Pathway显示文摘The anti-inflammatory activity of tea polyphenols(TPs)in RAW264.7 macrophages stimulated by lipopolysaccharide(LPS)was investigated in this paper.RAW264.7 macrophages were treated with different concentrations of TP(0,12.5,25,50,100,and 200μg/mL)and then stimulated by LPS.Another blank control group was set up.The expression of pro-inflammatory cytokines associated with the nuclear factor-kappa B(NF-κB)signaling pathway was investigated before and after TP treatment.Pretreatment of RAW264.7 cells with TP decreased the expression of tumor necrosis factor-α(TNF-α),interleukin-6(IL-6)and interleukin 1 beta(IL-1β)pro-inflammatory cytokines.In addition,TP inhibited the phosphorylation of p65 and IκB by blocking the phosphorylation and the degradation of NF-κB inhibitor protein.In conclusion,TP exerts anti-inflammatory effects by regulating the release of inflammatory mediators via the NF-κB signaling pathway. | SU Siyi LI Xiaoyu GUO Xu ZHOU Ruiming LI Manman MING Pengfei HUANG Yingying Sajid Ur RAHMAN DING Hongyan FENG Shibin LI Jinchun WANG Xichun LI Yu WU linjie | 2019 | Chemical Research in Chinese Universities2019，35，6： | 1 |
| 9 | Mechanism-based strain gradient Drucker–Prager elastoplasticity for pressure-sensitive materials显示文摘 | Lu Feng Yilan Kang Guang Zhang Shibin Wang | 2010 | International Journal of Solids and Structures2010，，20： | 1 |
| 10 | A fault prediction method for catenary of high-speed rails based on meteorological conditions显示文摘Fault frequency of catenary is related to meteo-rological conditions. In this work, based on the historical data, catenary fault frequency and weather-related fault rate are introduced to analyse the correlation between catenary faults and meteorological conditions, and further the effect of meteorological conditions on catenary oper-ation. Moreover, machine learning is used for catenary fault prediction. As with the single decision tree, only a small number of training samples can be classified cor-rectly by each weak classifier, the AdaBoost algorithm is adopted to adjust the weights of misclassified samples and weak classifiers, and train multiple weak classifiers. Finally, the weak classifiers are combined to construct a strong classifier, with which the final prediction result is obtained. In order to validate the prediction method, an example is provided based on the historical data from a railway bureau of China. The result shows that the mapping relation between meteorological conditions and catenary faults can be established accurately by AdaBoost algorithm. The AdaBoost algorithm can accurately predict a catenary fault if the meteorological conditions are provided. | Sheng Lin Qinyang Yu Zhen Wang Ding Feng Shibin Gao | 2019 | Journal of Modern Transportation2019，27，3： | 0 |
| 11 | The Structural and Chemical Reactivity of Lattice Oxygens on β-PbO_(2 ) EOP Electrocatalysts显示文摘The oxygen evolution reaction(OER)and electrochemical ozone production(EOP)attracted considerable attention due to their wide applications in electrocatalysis,but the detailed reaction mechanism of product formation as well as the voltage effect on O_(2)/O_(3)formation still remains unclear.In this work,density functional theory calculations were used to systematically investigate the possible reaction mechanisms of OER and EOP on the PbO_(2)(110)surface,with the possible reaction network involving surface lattice oxygen atoms(LOM)proposed.The results show that the LOM-2 reaction pathway involving two surface lattice oxygen atoms(Olatt)and one oxygen atom from H_(2)O was the most thermodynamically reactive.Different potential determining step(PDS)was obtained depending on the multiple reaction pathway,and the results show that the facile diffusion of Olattwould proceed the LOM pathway and promote the formation of surface oxygen vacancies(O_(vac1)/O_(vac2)).Furthermore,O_(vac1)/O_(vac2)formation on the surface would trigger further reactions of H_(2)O adsorption and splitting,which refilled the oxygen vacancy and ensured the considerable stability of the PbO_(2)(110)surface.Multiple H_(2)O dissociation pathways were proposed on PbO_(2)(110)with oxygen vacancy sites:the acid-base interaction mechanism and the vacancy fulfilling mechanism. | Wenwen Li Ge Feng Jia Liu Xing Zhong Zihao Yao Shengwei Deng Shibin Wang Jianguo Wang | 2022 | Chinese Journal of Structural Chemistry2022，41，12： | 0 |
| 12 | Boosting efficiency and stability of 2D alternating cation perovskite solar cells via rational surface-modification: Marked passivation efficacy of anion显示文摘Two-dimensional(2D) alternating cation(ACI) perovskite surface defects,especially dominant iodine vacancies(V_Ⅰ) and undercoordinated Pb^(2+),limit the performance of perovskite solar cells(PVSCs).To address the issue,1-butyl-3-methylimidazolium trifluoro-methane-sulfonate(BMIMOTF) and its iodide counterpart(BMIMI) are utilized to modify the perovskite surface respectively.We find that BMIMI can change the perovskite surface,whereas BMIMOTF shows a nondestructive and more effective defect passivation,giving significantly reduced defect density and suppressed charge-carrier nonradiative recombination.This mainly attributes to the marked passivation efficacy of OTF-anion on V_Ⅰ and undercoordinated Pb^(2+),rather than BMIMI^(+) cation.Benefiting from the rational surface-modification of BMMIMOTF,the films exhibit an optimized energy level alignment,enhanced hydrophobicity and suppressed ion migration.Consequently,the BMIMOTF-modified devices achieve an impressive efficiency of 21.38% with a record open-circuit voltage of 1.195 V,which is among the best efficiencies reported for 2D PVSCs,and display greatly enhanced humidity and thermal stability. | Hualin Zheng Xuefeng Peng Tingxi Chen Ting Zhang Shihao Yuan Lei Wang Feng Qian Jiang Huang Xiaodong Liu Zhi David Chen Yanning Zhang Shibin Li | 2023 | Journal of Energy Chemistry2023，，9： | 0 |
| 13 | Erratum to:Self-sacrificial templating synthesis of flower-like nickel phyllosilicates and its application as high-performance reinforcements in epoxy nanocomposites显示文摘Fig.3(a)on page 488 and Fig.7(a,a′)on page 493:It has come to our attention that the SEM pictures of Fig.3(a)and Fig.7(a,a′)for the fractured and worn surfaces of pure EP,respectively,are misused,because they have been reported in our previous work and were chosen accidentally to denote as the same control sample prepared using the exactly same procedure.The corrected Fig.3(a)and Fig.7(a,a′)are shown below.The data analysis,descriptions and conclusions are not affected by these unintentional errors. | Jinian Yang Xuesong Feng Shibin Nie Yuxuan Xu Zhenyu Li | 2022 | Frontiers of Chemical Science and Engineering2022，16，10： | 0 |
| 14 | Thermal effects on prediction accuracy of dense granite mechanical behaviors using modified maximum tangential stress criterion显示文摘Thermally-induced changes in the fracture properties of geological reservoir rocks can influence their stability,transport characteristics,and performance related to various deep subsurface energy projects.The modified maximum tangential stress(MMTS)criterion is a classical theory for predicting the fracture instability of rocks.However,there is a lack of research on the accuracy of MMTS theory when rocks are subjected to different temperatures.In this study,mechanical theoretical analysis and failure and fracture mechanics experiments of granite under the influence of temperatures ranging from 20℃to 600℃are carried out.The results showed that the theoretical estimated value of MMTS differs significantly from the experimental data at 20℃-600℃.The Keff/KIC ratio is less than the experimental test value due to the critical crack growth radius(rc)estimated by the conventional method being larger than the critical crack growth radius(rce)derived from the experimental data.Varied temperatures affect the fracture process zone size of fine-grained,compact granite,and the MMTS theoretical estimation results.Therefore,it is essential to modify the critical crack growth radius for MMTS theory to accurately predict the fracture characteristics of thermally damaged rocks.In addition,the variation of the rock’s me-chanical properties with temperature and its causes are obtained.Between 20℃and 600℃,the mode-Ⅰ,mode-Ⅱ,and mixed-mode(a-30℃and 45℃)fracture toughness and Brazilian splitting strength of the granite decrease by 80%and 73%,respectively.When the rock is heated above 400℃,its deterioration is mainly caused by a widening of its original cracks. | Gan Feng Chun Zhu Xiaochuan Wang Shibin Tang | 2023 | Journal of Rock Mechanics and Geotechnical Engineering2023，15，7： | 0 |
| 15 | Facile synthesis of polyaniline nanorods to simultaneously enhance the mechanical properties and wear resistance of epoxy composites显示文摘To enhance the mechanical properties and wear resistance of epoxy resin,polyaniline nanorods were first synthesized using a facile route,and then introduced into the epoxy matrix to yield composites via solution mixing.Several measurements were conducted to investigate the phase structures and compositions of polyaniline nanorods,and their positive influences on the mechanical and tribological properties of epoxy resin were also characterized.The results confirmed that the as-synthesized polyaniline exhibited representative rod-like morphologies and dispersed well in the epoxy matrix,leading to significant enhancements in the tensile strength and elastic modulus of epoxy composites.The highest values of 110.33 MPa and 2.04 GPa were obtained by adding 5%-7%polyaniline nanorods,which were 43%and 62%higher than the pure sample,respectively.The wear rate was increased first and then decreased along with polyaniline nanorods,presenting the lowest value of 2.12×10^(−5) mm^(3)·Nm^(−1) by adding 5%filler,which was markedly reduced by ca.70%compared to the control sample.Finally,the possible wear mechanism was proposed and discussed in detail.This study tried to broaden the applications of polyaniline nanorods in the field of tribology. | Liu Jiang Jinian Yang Jie Dong Shibin Nie Yuxuan Xu Xuesong Feng | 2023 | Frontiers of Chemical Science and Engineering2023，17，9： | 0 |
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