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| 1 | Active catalytic species generated in situ in zirconia incorporated hydrogen storage material magnesium hydride显示文摘This study explores how zirconia additive interacts with MgH_(2)to improve its hydrogen storage performance.Initially it is confirmed that the zirconia added MgH_(2)powder releases hydrogen at a temperature of about 50℃below that of the additive free MgH_(2).Subsequent tests by X ray diffraction(XRD)and infrared(IR)spectroscopy techniques reveal that the ZrO_(2) mixed MgH_(2)powder contains ZrHx(21.5)and MgO secondary phases.This observation is supported by the negative Gibbs free energy values obtained for the formation of ZrH_(2)/MgO from ZrO_(2)/MgH_(2)powder samples.An X ray photoelectron spectroscopy(XPS)study reveals that apart from Zr^(4+)cations,Zr^(2+) and zero valent Zr exist in the powder.Atomic force microscopy(AFM)study reveals that the average grain size is 20 nm and the elemental line scan profiles further proves the existence of oxygen deficient Zr bearing phase(s).This study strengthens the belief that functional metal oxide additives in fact chemically interact with MgH_(2)to make active in-situ catalysts in the MgH_(2)system. | D.Pukazhselvan K.S.Sandhya Devaraj Ramasamy Aliaksandr Shaula Igor Bdikin Duncan Paul Fagg | 2022 | Journal of Magnesium and Alloys2022,10,3: | 3 |
| 2 | Large-area high-throughput synthesis of monolayer graphene sheet by Hot Filament Ther- mal Chemical Vapor Deposition显示文摘 | Ranjit Hawaldar Igor Bdikin | 2012 | Scientific reports2012,682,2: | 1 |
| 3 | Effect of Zr/Ti ratio on the microstructure andferroelectric properties of lead zirconate titanate thin films显示文摘 | KHAENAMKAEW P MUENSIT S BDIKIN I K | 2007 | Materials Chemistry and Physics2007,102,23: | 1 |
| 4 | Crystal structure and multiferroic properties of Gd-substituted BiFeO3 显示文摘 | Khomchenko V Kiselev D Bdikin I | 2008 | Appl Phys Lett2008,93,26: | 1 |
| 5 | High-pressure phase transition of hexagonal alkali pnictides 显示文摘 | LEONOVA M E BDIKIN I K KULINICH S A | 2003 | InorgMater2003,39,3: | 1 |
| 6 | Effect of ZrATiratio on the microstructure and ferroelectric properties of lead zirconatetitanate thin films 显示文摘 | KHAENAMKAEW P MUENSIT S BDIKIN I K | 2007 | Mater Chem Phys2007,102,23: | 1 |
| 7 | Structural,Morphological and Piezoresponse Studies of Pr and Sc Co-substituted BiFeO3 Ceramics显示文摘 | Coondoo I Panwar N Bdikin I | 2012 | Jourmd of Physics DtApplied Physics2012,45,05: | 1 |
| 8 | Influence of Mg doping on dielectric and optical properties of ZnO nano-plates prepared by wet chemical method显示文摘 | Zamiri R Singh B Bdikin I | 2014 | Solid State Communications2014,195,: | 1 |
| 9 | Ferroelectric and ferromagnetic properties of Gd-doped BiFeO 3 –BaTiO 3 solid solution显示文摘 | Radheshyam Rai Igor Bdikin Manuel Almeida Valente Andrei L. Kholkin | 2009 | Materials Chemistry and Physics2009,,3: | 1 |
| 10 | Magnetic properties of randomly oriented BaM,SrM,Co2Y,Co2Z and Co2W hexagonal ferrite fibres显示文摘 | PULLAR R C BDIKIN I K BHATTACHARYA A K | 2012 | Journal of the European Ceramic Society2012,32,: | 1 |
| 11 | Effect of Zr/Ti ratio on the microstructure and ferroelectric properties of lead zirconate titanate thin films显示文摘 | KHAENAMKAEW P MUENSIT S BDIKIN I K | 2007 | Materials Chemistry and Physics2007,102,23: | 1 |
| 12 | Nanoscale characterization of polycrystalline ferroelectric materials for piezoelectric applications显示文摘 | A. L. Kholkin I. K. Bdikin D. A. Kiselev V. V. Shvartsman S.-H. Kim | 2007 | Journal of Electroceramics2007,,1: | 1 |
| 13 | Effect of Zr/Ti ratio on the miemstrueture and ferreeleetrie properties of lead zireonate titanate thin f'dms显示文摘 | Khaenamkaew P Muensit S Bdikin I K | 2007 | Materials Chemistry and Physics2007,102,23: | 1 |
| 14 | Magnetic and properties of randomly oriented BaM,SrM,Co2Y-Co2Z and Co2W hexagonal ferrite fibres 显示文摘 | PULLAR R C BDIKIN I K BHATTACHARYA A K | 2012 | Journal of the European Ceramic Society2012,32,4: | 1 |
| 15 | Effect of Gd substitution on the crystal structure and multiferroic properties of BiFeO 3显示文摘 | V.A. Khomchenko V.V. Shvartsman P. Borisov W. Kleemann D.A. Kiselev I.K. Bdikin J.M. Vieira A.L. Kholkin | 2009 | Acta Materialia2009,,: | 1 |
| 16 | Strong piezoelec- tricity in bioinspired peptide nanotubes 显示文摘 | Kholkin A Amdursky N Bdikin I | 2010 | ACS Nano2010,4,2: | 1 |
| 17 | Comprehensive investigation of structural,dielectric and local piezoelectric properties of KNN ceramics显示文摘In this research paper,we utilized the traditional high-temperature solid-state reaction method to fabricate the K_(0.495)Na_(0.520)NbO_(3),K_(0.480)Na_(0.535)NbO_(3)and K_(0.475)Na_(0.540)NbO_(3)(abbreviated as KNN-1,KNN-2,and KNN-3,respectively)lead-free ion deficient ceramics for understanding the influence of ionic deficiency on the crystalline structure and dielectric/piezoelectric properties of the samples.X-ray diffraction patterns of these samples exhibited a perovskite tetragonal phase.Dielectric anomalies around 287℃and 471℃were identified as ferroelectric to ferroelectric and ferroelectric to paraelectric-transition temperatures for KNN-2 at 1 kHz.It was found that the composition KNN-2 exhibit relatively high Curie temperature i.e.,471℃.The conductivity plots confirm that the activation energies are frequency-dependent.The impedance behavior in our ceramic samples can be analyzed with the bulk/grain effect.The slope of Z′with temperature shows negative temperature coefficient of resistance(NTCR)type behavior in proposed KNN ceramics material. | Poonam Kumari Madan Lal Sunil Kumar Radheshyam Rai Anupinder Singh D.V.Karpinsky Igor Bdikin | 2019 | Journal of Advanced Dielectrics2019,9,2: | 0 |
| 18 | FERROELECTRIC AND MAGNETIC PROPERTIES OF PEROVSKITE STRUCTURED Bi_(1-x-y)Gd_(x)Ba_(y)Fe_(1-y)Ti_(y)O_(3)MAGNETOELECTRIC CERAMICS显示文摘Ternary solid solutions of BiFeO_(3),GdFeO_(3)and BaTiO_(3)have been prepared by solid-state reaction method.Dielectric properties of these ceramics have been characterized in the tem-perature range between room temperature and 673 K and magnetic properties between 5 K and 300K.For the understanding of the multiferroic property,the relation between the crystal structures,magnetic transition and ferroelectric transitions with increasing temperature have been analyzed.All ceramic samples show single perovskite phase.When Ba content exceeds 0.2 wt%,the sintering ability is weakened and the phase structure of Bi_(1-x-y)Gd_(x)Ba_(y)Fe_(1-y)Ti_(y)O_(3)(with x=0.2 and y=0.1,0.2,0.3,0.4,0.5)solid solution changes from rhombohedral to tetragonal phase.The maximum ferroelectric transition temperature(T_(c))of this system was in the range 154-165℃with the dielectric constant peak of 6000 for y=0.5 at 100 kHz.Well-saturated piezoresponse hysteresis loops were observed for all compositions indicating room temperature ferroelectricity.With increasing Ba content(up to 0.3 wt%)the remanent magnetization M,increased and the coercive magnetic field decreased. | RADHESHYAM RAI IGOR BDIKIN M.A.VALENTE ANDREI L.KHOLKIN | 2011 | Journal of Advanced Dielectrics2011,1,2: | 0 |