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1篇 您的检索式:作者名="Yuemeng Fei"
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1Surface passivation and hole extraction:Bifunctional interfacial engineering toward high-performance all-inorganic CsPbIBr2 perovskite solar cells with efficiency exceeding 12%显示文摘All-inorganic CsPbIBr2perovskite solar cells(PSCs)have attracted considerable research attention in recent years due to their excellent thermal stability.However,their power conversion efficiencies(PCEs)are relatively low and still far below the theoretical limit.Here,we report the use of an organic dye molecule(namely VG1-C8)as a bifunctional interlayer between perovskite and the hole-transport layer in CsPbIBr2PSCs.Combined experimental and theoretical calculation results disclose that the multiple Lewis base sites in VG1-C8 can effectively passivate the trap states on the perovskite films.Meanwhile,theπ-conjugated dye molecule significantly accelerates the hole extraction from the perovskite absorber as evidenced by the photoluminescence analysis.Consequently,the VG1-C8 treatment simultaneously boosts the photovoltage and photocurrent density values from 1.26 V and 10.80 mA cm^(-2) to 1.31 V and 12.44 m A cm^(-2),respectively.This leads to a significant enhancement of PCE from 9.20%to12.10%under one sun irradiation(AM 1.5G).To our knowledge,this is the record efficiency reported so far for CsPbIBr_(2) PSCs.Thus,the present work demonstrates an effective interfacial passivation strategy for the development of highly efficient PSCs.Qi Liu Junming Qiu Xianchang Yan Yuemeng Fei Yue Qiang Qingyan Chang Yi Wei Xiaoliang Zhang Wenming Tian Shengye Jin Ze Yu Licheng Sun 2022Journal of Energy Chemistry2022,31,11:0
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