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1Applied catalysis for sustainable development of chemical industry in China显示文摘Progressing green chemical technologies is signiicant to the sustainable development of chemical industry in China, as the energy and environment problems increasingly became great challenges to the whole society. he scientiic connotation of sustainable energy chemical engineering can be generalized as green carbon/hydrogen science which means optimization of carbon/hydrogen atom economics based on high eicient catalysis and low-carbon emission. his review illustrated recent advances in developing sustainable technologies for applied catalysis in chemical industry of China, including the ields of high eicient conversion of heavy oil, green petrochemical catalytic technologies, clean utilization of coal and natural gas, promoting sustainable resources and clean energy, etc. Moreover, from the view of industrial point, some important common scientiic problems were discussed and summarized, such as the relation between molecular difusion and catalyzing eiciency, homogeneous catalysis in heterogeneous catalysts,in situ or operando characterization of industrial catalysis, etc., aiming to supplying a forward roadmap to academia and/or industry.Zaiku Xie Zhicheng Liu Yangdong Wang Zhonghao Jin 2015National Science Review2015,2,2:10
2Design and application of microgrid operation control system based on IEC 61850显示文摘We consider the microgrid operation control technology including design of microgrid operation control system,MG control device and control strategy.We pay much attention on microgrid operation control device which is core control device.In order to solve the contradiction of quick speed about microgrid operation mode shift and slow speed about the management system,threelayers control architecture based on IEC61850 is designed and adaptive control strategy is used on MG operation control system.The system has been applied in a distributed generation/energy storage power station.The actual operation shows that the system can be effectively and flexibly connected to distribution network.Wen LU Yangdong ZHAO Weixing LI Hongwei DU 2014Journal of Modern Power Systems and Clean Energy2014,2,3:8
3The essential mass transfer step in hierarchical/nano zeolite: surface diffusion显示文摘An important topic in zeolite catalyst design is how to improve utilization efficiency o f active sites in micropores by upgrading the effective diffusivity o f reactants/products in zeolite crystal particles[l].Nano-and hierarchical structures have drawn lots of attention in zeolitic catalysis fields in recent years;because these two methods can obviously improve the catalysis efficiency by shortening the configuration diffusion length[2].However,new problems were raised in the construction process of hierarchical or nano-zeolites.For instance,it was found that the hierarchical structure can change the intrinsic properties of surface acid sites in zeolite[3].Fan et al.reported that when the length scale o f the zeolite approaches several nanometers;the difFusional time constants[4,5]and the apparent configuration diffusion lengths will be significantly increased than expected[6].Therefore,enhanced mass transport in hierarchical zeolite will be overpredicted if not considering the extent of sorbate-sorbent interaction.Jian Zhou Wei Fan Yangdong Wang Zaiku Xie 2020National Science Review2020,7,11:7
4Insight into the topology effect on the diffusion of ethene and propene in zeolites: A molecular dynamics simulation study显示文摘Selectivity control is a difficult scientific and industrial challenge in methanol-to-olefins(MTO)conversion.It has been experimentally established that the topology of zeolite catalysts influenced the distribution of products.Besides the topology effect on reaction kinetics,the topology influences the diffusion of reactants and products in catalysts as well.In this work,by using COMPASS force-field molecular dynamics method,we investigated the intracrystalline diffusion of ethene and propene in four different zeolites,CHA,MFI,BEA and FAU,at different temperatures.The self-diffusion coefficients and diffusion activation barriers were calculated.A strong restriction on the diffusion of propene in CHA was observed because the self-diffusion coefficient ratio of ethene to propene is larger than 18 and the diffusion activation barrier of propene is more than 20 kJ/mol in CHA.This ratio decreases with the increase of temperature in the four investigated zeolites.The shape selectivity on products from diffusion perspective can provide some implications on the understanding of the selectivity difference between HSAPO-34 and HZSM-5 catalysts for the MTO conversion.Chuanming Wang Bowei Li Yangdong Wang Zaiku Xie 2013Journal of Energy Chemistry2013,22,6:6
5A fingerprint feature extraction algorithm based on curvature of Bezier curve显示文摘Fingerprint feature extraction is a key step of fingerprint identification. A novel feature extraction algorithm is proposed in this paper, which describes fingerprint feature with the bending information of fingerprint ridges. Ridges in the specific region of fingerprint images are traced firstly in the algorithm, and then these ridges are fit with Bezier curve. Finally, the point that has the maximal curvature on Bezier curve is defined as a feature point. Experimental results demonstrate that this kind of feature points characterize the bending trend of fingerprint ridges effectively, and they are robust to noise, in addition, the extraction precision of this algorithm is also better than the conventional approaches.Yuan Huaqiang Ye Yangdong Deng Jianguang Chai Xiaoguang Li Yong 2007Progress in Natural Science:Materials International2007,17,11:5
6Sand-fixing characteristics of Carex brunnescens and its application with straw checkerboard technique in restoration of degraded alpine meadows显示文摘Carex brunnescens(Pers.), a typical clonal species, is considered to be the only herb found to date that can develop on sand dunes in Maqu alpine region of northwestern China. However, the characteristics that C. brunnescens resists to harsh alpine environment have not been documented. In this study, we conducted a field investigation to determine the morphological, reproductive, and sand-fixing characteristics of C. brunnescens. Concomitantly, we transplanted the belowground rhizomes of C. brunnescens to sand dunes and compared the abilities to restore degraded alpine meadows among sand dunes that had no further treatment(SD+N), sand dunes that had straw checkerboard technique but no transplanted rhizomes of C. brunnescens(SD+SCT), and sand dunes that had both SCT and transplanted rhizomes of C. brunnescens(SD+SCT+P). We found that belowground vertical rhizomes and horizontal rhizomes(including branching rhizomes and main rhizomes) of C. brunnescens were highly developed and that population reproduction was dominated by horizontal rhizomes. C. brunnescens exhibited a significant sand-fixation effect under following conditions: population density was 145–156 ramets/m^2, vegetation cover was 31.2%–39.3%, total length of belowground rhizomes was 11,223 cm/m^2, total length of belowground first-order roots was 9161–10,524 cm/m^2, fresh weight of aboveground part was 198.5–212.6 g/m^2, and fresh weight of belowground part was 578.8–612.4 g/m^2. It should be particularly noted that SD+SCT+P treatment(sand dunes that had both straw checkerboard technique and transplanted rhizomes of C. brunnescens) was the best and SD+N(sand dunes that had no further treatment) was the worst in terms of following biotic indicators: total number of reproductive ramets, total number of belowground rhizomes, and fresh weight of aboveground and belowground parts of C. brunnescens, contents of soil organic carbon, available nitrogen, microbial biomass carbon, and microbial biomass nitrogen. It implies that applying SCT in sand dunes and transplanting belowground rhizomes to sand dunes with SCT could improve both soil fertility and growth of C. brunnescens. These results suggest that the SCT-promoted high reproductive abilities of belowground rhizomes of C. brunnescens can successfully facilitate the establishment of ramets and can thus be an effective strategy to restore degraded vegetation in Maqu alpine region of northwestern China.KANG Jianjun ZHAO Ming TAN Yanrong ZHU li BING Danhui ZHANG Yangdong TONG Shengli 2017Journal of Arid Land2017,9,5:4
7Application of the Clustering Method in Molecular Dynamics Simulation of the Diffusion Coefficient显示文摘Using molecular dynamics (MD) simulation, the diffusion of oxygen, methane, ammonia and carbon dioxide in water was simulated in the canonical NVT ensemble, and the diffusion coefficient was analyzed by the clustering method. By comparing to the conventional method (using the Einstein model) and the differentiation-interval variation method, we found that the results ob- tained by the clustering method used in this study are more close to the experimental values. This method proved to be more reason- able than the other two methods.LIU Qingzhi HU Yangdong 2008Journal of Ocean University of China2008,7,1:4
8Palm oil protectsα-linolenic acid from rumen biohydrogenation and muscle oxidation in cashmere goat kids显示文摘Background:In ruminants,dietary C18:3n-3 can be lost through biohydrogenation in the rumen;and C18:3n-3 that by-passes the rumen still can be lost through oxidation in muscle,theoretically reducing the deposition of C18:3n-3,the substrate for synthesis of poly-unsaturated fatty acids(n-3 LCPUFA)in muscle.In vitro studies have shown that rumen hydrogenation of C18:3n-3 is reduced by supplementation with palm oil(rich in cis-9 C18:1).In addition,in hepatocytes,studies with neonatal rats have shown that cis-9 C18:1 inhibits the oxidation of C18:3n-3.It therefore seems likely that palm oil could reduce both rumen biohydrogenation of C18:3n-3 and muscle oxidation of C18:3n-3.The present experiment tested whether the addition of palm oil to a linseed oil supplement for goat kids would prevent the losses of C18:3n-3 and thus improve the FA composition in two muscles,Longissimus dorsi and Biceps femoris.To investigate the processes involved,we studied the rumen bacterial communities and measured the mRNA expression of genes related to lipid metabolism in Longissimus dorsi.Sixty 4-month-old castrated male Albas white cashmere kids were randomly allocated among three dietary treatments.All three diets contained the same ingredients in the same proportions,but differed in their fat additives:palm oil(PMO),linseed oil(LSO)or mixed oil(MIX;2 parts linseed oil plus 1 part palm oil on a weight basis).Results:Compared with the LSO diet,the MIX diet decreased the relative abuandance of Pseudobutyrivibrio,a bacterial species that is positively related to the proportional loss rate of dietary C18:3n-3 and that has been reported to generate the ATP required for biohydrogenation(reflecting a decrease in the abundance of rumen bacteria that hydrogenate C18:3n-3 in MIX kids).In muscle,the MIX diet increased concentrations of C18:3n-3,C20:5n-3,C22:6n-3,and n-3 LCPUFA,and thus decreased the n-6/n-3 ratio;decreased the mRNA expression of CPT1β(a gene associated with fatty acid oxidation)and increased the mRNA expression of FADS1 and FADS2(genes associated with n-3 LCPUFA synthesis),compared with the LSO diet.Interestingly,compared to Longissimus dorsi,Biceps femoris had greater concentrations of PUFA,greater ratios of unsaturated fatty acids/saturated fatty acids(U/S),and poly-unsaturated fatty acids/saturated fatty acids(P/S),but a lesser concentration of saturated fatty acids(SFA).Conclusions:In cashmere goat kids,a combination of linseed and palm oils in the diet increases the muscle concentration of n-3 LCPUFA,apparently by decreasing the relative abundance of rumen bacteria that are positively related to the proportional loss rate of dietary C18:3n-3,by inhibiting mRNA expression of genes related to C18:3n-3 oxidation in muscle,and by up-regulating mRNA expression of genes related to n-3 LCPUFA synthesis in muscle,especially in Longissimus dorsi.Xue Wang Graeme B.Martin Qi Wen Shulin Liu Yinhao Li Binlin Shi Xiaoyu Guo Yanli Zhao Yangdong Guo Sumei Yan 2021Journal of Animal Science and Biotechnology2021,12,2:3
9A Hierarchical Ensemble Learning Framework for Energy-Efficient Automatic Train Driving显示文摘Railway transportation plays an important role in modern society. As China's massive railway transportation network continues to grow in total mileage and operation density, the energy consumption of trains becomes a serious concern. For any given route, the geographic characteristics are known a priori, but the parameters(e.g., loading and marshaling) of trains vary from one trip to another. An extensive analysis of the train operation data suggests that the control gear operation of trains is the most important factor that affects the energy consumption. Such an observation determines that the problem of energy-efficient train driving has to be addressed by considering both the geographic information and the trip parameters. However, the problem is difficult to solve due to its high dimension, nonlinearity, complex constraints, and time-varying characteristics. Faced with these difficulties, we propose an energy-efficient train control framework based on a hierarchical ensemble learning approach. Through hierarchical refinement, we learn prediction models of speed and gear. The learned models can be used to derive optimized driving operations under real-time requirements. This study uses random forest and bagging – REPTree as classification algorithm and regression algorithm, respectively. We conduct an extensive study on the potential of bagging, decision trees, random forest, and feature selection to design an effective hierarchical ensemble learning framework. The proposed framework was testified through simulation. The average energy consumption of the proposed method is over 7% lower than that of human drivers.Guohua Xi Xibin Zhao Yan Liu Jin Huang Yangdong Deng 2019Tsinghua Science and Technology2019,24,2:3
10Understanding Zeolites Catalyzed Methanol-to-Olefins Conversion from Theoretical Calculations显示文摘Chuanming Wang Yangdong Wang Zaiku Xie 2018Chinese Journal of Chemistry2018,36,5:3
11Shape selective catalysis in methylation of toluene: Development, challenges and perspectives显示文摘Jian Zhou Zhicheng Liu Yangdong Wang Dejin Kong Zaiku Xie 2018Frontiers of Chemical Science and Engineering2018,12,1:3
12The green hydrolysis technology of hemicellulose in corncob by the repeated use of hydrolysate显示文摘To achieve green hydrolysis technology of hemicellulose through repeated using hydrolysate,the hydrolysis of hemicellulose in corncob was studied.The influence of repeated use of corncob hydrolysate on concentrations of D-xylose and L-arabinose was investigated.The loss rates of D-xylose in the prepared D-xylose solutions both with and without corncob,and repeated using corncob hydrolysate under identical acidity condition were discussed.The result shows that D-xylose concentration and L-arabinose concentration are all gradually increasing with the growing time of repeated use of corncob hydrolysate.After the fifth repetition,the concentrations of D-xylose and L-arabinose are 196.7 g·L^(-1)and 22.0 g·L^(-1),respectively.Substance inhibiting the degradation of D-xylose is generated during repeated use of corncob hydrolysate,and the production is further proved by the change of D-xylose concentration and the loss rate of D-xylose over heating time.Lei Guo Yangdong Hu Lianying Wu Chen Liang Weitao Zhang 2018Chinese Journal of Chemical Engineering2018,26,1:2
13Towards a green bulk-scale biobutanol from bioethanol upgrading显示文摘Biobutanol is attracting increasingly interest as a source of renewable energy and biofuels because of its many advantages over bioethanol that include higher energy density, fuel efficiency, and reduced engine damages. Currently, there is a growing interest in producing biobutanol from bioethanol, in view of the tremendous potential benefits of this transformation for the bulk production of biobutanol in a target specific manner. This perspective paper describes recent progress for the ethanol to butanol process. The different catalysts, including homogeneous and heterogeneous catalytic systems, for ethanol to butanol are outlined and compared, and the key issues and requirements for future developments are highlighted.A major challenge for further development and application of ethanol to butanol process is to find an optimal balance between different catalytic functions and to suppress the formation of side products that has plagued most catalytic bioethanol upgrading systems.Qi Zhang Jing Dong Yongmei Liu Yangdong Wang Yong Cao 2016Journal of Energy Chemistry2016,25,6:2
14A new model in correlating and calculating the solid–liquid equilibrium of salt–water systems显示文摘In this work, a new activity coefficient model was deduced for the correlation of solid–liquid equilibrium(SLE) in electrolyte solutions. The new excess Gibbs energy equation for SLE contains two parts: the single electrolyte item and the mixed electrolyte item. Then a new hypothesis for the reference state of activity coefficients was proposed in the work. Literature data for single electrolyte solution and mixed electrolyte solution systems,with temperature spanning from 273.15 to 373.15 K, were successfully correlated using the developed model.Xianzhen Xu Yangdong Hu Lianying Wu Xia Chen 2016Chinese Journal of Chemical Engineering2016,24,8:2
15Effect of support nature on WO3/SiO2 structure and butane-1 metathesis显示文摘Wang Yangdong Chen Qingling Yang Weimin 2003Applied Catalysis A:Gereral2003,250,:1
16Using change-point analysis and weighted averaging approaches to explore the relationships between common benthic diatoms and in- stream environmental variables in mid-Atlantic highlands streams, USA显示文摘Christine L W Yangdong Pan 2008Hydrobiologia2008,614,:1
17Attack structural vulnerability of power grids- a hybrid approach based on complex networks显示文摘Guo Chena Zhao Yangdong Hill D J 2010Physica A2010,389,3:1
18A self-adaptive RBF neural network classifier for transformer fault analysis显示文摘Ke Meng Zhao Yangdong Dian Huiwang 2010IEEE Transactions on Power Systems2010,25,3:1
19Isolation and Identification of Squash Leaf Curl China Virus in Zucchini显示文摘[Objectives]In 2019,virus diseases occurred widely on zucchini planted in Shandong Province.The disease symptom was different from previous reports.This study aimed to identify the pathogen causing the zucchini virus disease.[Methods]Ten diseased zucchini leaves were collected in the field and used as materials for PCR and sequencing.[Results]PCR detection and sequencing showed that the nucleotide sequence of the amplified fragment had the highest identity with the squash isolate of squash leaf curl China virus(SLCCNV)(MW389919.1)in Guangdong Province.Primers were further designed for amplifying the full-length SLCCNV.The full-length DNA-A was 2730 bp(OM692270.1),and the full-length DNA-B was 2711 bp(OM692269.1).Through sequence alignment,it was found that the DNA-A sequence shared identity of 89.65%-99.42%with registered SLCCNV,and the identity with the SLCCNV-GDHY pumpkin isolate(MW389919.1)in Guangdong was the highest,at 99.42%.The DNA-B sequence was identical with registered SLCCNV in the range of 81.82%-97.29%,and the identity with the SLCCNV-GDHY pumpkin isolate(MW389918.1)in Guangdong,was the highest,at 97.29%.Therefore,it was speculated that SLCCNV is the pathogen of zucchini virus disease.Since the virus was first found on zucchini in Shandong,it was named SLCCNV-SD.[Conclusions]This study provides materials for the research on the spread of SLCCNV in China and the analysis of population genetic characteristics,as well as a reference for the prevention and control of the virus in zucchini.Huixian SHI Yimin GU Xingsheng LI Xiping SUN Yangdong GUO Xiaowei YUAN 2022Agricultural Biotechnology2022,11,5:1
20Experimental measurement and thermodynamic modeling of binary and ternary solid–liquid phase equilibrium for the systems formed by L-arabinose,D-xylose and water显示文摘Solid–liquid phase equilibrium data for binary(L-arabinose–water) and(D-xylose–water) systems at temperatures from(269.85–298.05) K and ternary(L-arabinose–D-xylose–water) system at temperatures of 273.85 K,278.85 K and 284.45 K were measured at atmospheric pressure.The ternary phase diagrams of the systems were constructed on the base of the measured solubility.Two pure solid phases were formed at given temperatures,including pure L-arabinose and pure D-xylose,which were con firmed and determined by the method of Schreinemakers' wet residue.At the same temperature,the crystallization region of L-arabinose was larger than D-xylose's.The acquired solubility data were then correlated using the NRTL model,Wilson model and Xu model.The calculated solubility with the three models agreed well with the experimental values.Lei Guo Lianying Wu Weitao Zhang Chen Liang Yangdong Hu 2017Chinese Journal of Chemical Engineering2017,25,10:1
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