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| 1 | Flavonoid content and radical scavenging activity in fruits of Chinese dwarf cherry(Cerasus humilis) genotypes显示文摘The Chinese dwarf cherry(Cerasus humilis(Bge.) Sok.) is a small shrub with edible fruits. It is native to northern and western China. This species was included as a medicinal plant in the ‘‘Chinese Pharmacopeia'' and has emerged as an economically important crop for fresh fruit consumption, processing into juice and wine and nutraceutical products as well. To gain a better understanding of flavonoid biosynthesis and help develop value added products and better cultivars with greater health benefits, we analyzed total flavonoid content(TFC), composition, and radical scavenging activities in fruit extracts of 16 Chinese dwarf cherry genotypes. Fruit peel TFC ranged from 33.5 to72.8 mg/g REáFW(RE: rutin equivalent, FW: fresh weight)while fruit flesh TFC ranged from 4.3 to 16.9 mg/g REáFW.An HPLC analysis revealed that fruit extracts contained 14 flavonoids with considerable variation in their profiles across genotypes. The most abundant flavonoids in most genotypes were proanthocyanidin B1(PA-B1), proanthocyanidin B2(PA-B2), phloretin 20-O-glucoside(PG), and phloretin 20,40-O-diglucoside(PDG). Principal component analysis showed that PG, PA-B1, and PA-B2 had large,positive factor loading values in the first principal component for each genotype. Increased scavenging activity of2,2-diphenyl-1-picrylhydrazyl(DPPH) radicals was apparent in genotypes ‘Nongda 4', ‘Nongda 3', ‘Nongda 6',‘Wenfenli', and '10-32', suggesting promising applications in the production of nutraceutical products. In summary, our results will aid in breeding, fruit processing, and developing medicinal uses of the Chinese dwarf cherry. | Pengfei Wang Xiaopeng Mu Junjie Du Yu Gary Gao Donghai Bai Luting Jia Jiancheng Zhang Haiyan Ren Xiaofang Xue | 2018 | Journal of Forestry Research2018，29，1： | 8 |
| 2 | Dark matter direct search sensitivity of the PandaX-4T experiment显示文摘The Panda X-4T experiment, a 4-ton scale dark matter direct detection experiment, is being planned at the China Jinping Underground Laboratory. In this paper we present a simulation study of the expected background in this experiment. In a 2.8-ton fiducial mass and the signal region between 1-10 keV electron equivalent energy, the total electron recoil background is found to be 4.9 × 10^(-5) kg^(-1) d^(-1) keV^(-1). The nuclear recoil background in the same region is 2.8 × 10^(-7) kg^(-1) d^(-1) keV^(-1). With an exposure of 5.6 ton-years, the sensitivity of Panda X-4 T could reach a minimum spin-independent dark matter-nucleon cross section of 6 × 10^(-48) cm^2 at a dark matter mass of 40 Ge V/c^2. | HongGuang Zhang Abdusalam Abdukerim Wei Chen Xun Chen YunHua Chen XiangYi Cui BinBin Dong DeQing Fang ChangBo Fu Karl Giboni Franco Giuliani LinHui Gu XuYuan Guo ZhiFan Guo Ke Han ChangDa He ShengMing He Di Huang XingTao Huang Zhou Huang Peng Ji XiangDong Ji YongLin Ju ShaoLi Li Yao Li Heng Lin HuaXuan Liu JiangLai Liu YuGang Ma YaJun Mao KaiXiang Ni JinHua Ning XiangXiang Ren Fang Shi AnDi Tan AnQing Wang Cheng Wang HongWei Wang Meng Wang QiuHong Wang SiGuang Wang XiuLi Wang XuMing Wang Zhou Wang MengMeng Wu ShiYong Wu JingKai Xia MengJiao Xiao PengWei Xie BinBin Yan JiJun Yang Yong Yang ChunXu Yu JuMin Yuan JianFeng Yue Dan Zhang Tao Zhang Li Zhao QiBin Zheng JiFang Zhou Ning Zhou XiaoPeng Zhou | 2019 | Science China(Physics,Mechanics & Astronomy)2019，62，3： | 6 |
| 3 | Effects of carbon diffusing field in alloy solvent on the growth of tower-shape diamond single crystal显示文摘High-quality type-Ib tower-shape diamond single crystals were synthesized in cubic anvil high pressure apparatus (SPD-6×1200) at 5.4 GPa and 1250-1450°C. The (100) face of seed crystal was used as the growth face, and FeNiMnCo alloy was used as the solvent/catalyst. Two kinds of carbon diffusing fields (type-B and type-G) were simulated by finite element method (FEM). Using the two kinds of carbon diffusing fields, many diamond single crystals were synthesized. The effects of carbon diffusing fields on the crystal quality and β value (the ratio of height to diameter of diamond crystal) were studied. The results show that using type-B diffusing field, considerable inclusions appeared in tower-shape diamond crystals with high β values; however, using type- G diffusing field, inclusions were reduced markedly in high β values tower-shape diamond crystals, and the crystal, up to 0.6 carat in weight and 5.3 mm in size, was synthesized. Experimental phenomena were explained well with the help of the FEM. | XIAO HongYu MA HongAn TIAN Yu LI Rui LI ShangSheng MA LiQiu LI Yong JIA XiaoPeng | 2010 | Chinese Science Bulletin2010，55，1： | 5 |
| 4 | Dependence of nitrogen concentration in type Ib diamonds on synthesis temperature显示文摘Type Ib diamonds were grown by the temperature gradient method (TGM) at 5.5 GPa and 1500-1560 K in a china-type cubic anvil high pressure apparatus using Ni70Mn25Co5 alloy as solvent/catalyst. The concentration of nitrogen (CN) in type Ib diamonds synthesized at different synthesis temperatures was measured by a Fourier transform infrared (FTIR) spectrometer. The dependence of CN in diamond on synthesis temperature was studied. For the type Ib diamonds synthesized using Ni70Mn25Co5 as catalyst, its CN decreases along with the increase of synthesis temperature. | TIAN Yu JIA XiaoPeng ZANG ChuanYi LI ShangSheng XIAO HongYu ZHANG YaFei HUANG GuoFeng LI Rui HAN QiGang MA LiQiu LI Yong CHEN XiaoZhou ZHANG Chong MA HongAn | 2009 | Chinese Science Bulletin2009，54，9： | 5 |
| 5 | Short-term effects of nitrogen deposition on soil respiration components in two alpine coniferous forests, southeastern Tibetan Plateau显示文摘Nitrogen (N) deposition to alpine forest ecosystems is increasing gradually, yet previous studies have seldom reported the effects of N inputs on soil CO2 flux in these ecosystems. Evaluating the effects of soil respiration on N addition is of great significance for understanding soil carbon (C) budgets along N gradients in forest ecosystems. In this study, four levels of N (0, 50, 100, 150 kg N ha^-1 a^-1) were added to soil in a Picea baifouriana and an Abies georgei natural forest on the Tibetan Plateau to investigate the effect of the N inputs on soil respiration. N addition stimulated total soil respiration (Rt) and its components including heterotrophic respiration (Rh) and autotrophic respiration (Ra);however, the promoted effects declined with an increase in N application in two coniferous forests. Soil respiration rate was a little greater in the spruce forest (1.05 μmol CO2 m^-2 s^-1) than that in the fir forest (0.97 μmol CO2 m^-2 s^-1). A repeated measures ANOVA indicated that N fertilization had significant effects on Rt and its components in the spruce forest and Rt in the fir forest, but had no obvious effect on Rh or Ra in the fir forest. Rt and its components had significant exponential relationships with soil temperature in both forests. N addition also increased temperature sensitivity (Q10) of Rt and its components in the two coniferous forests, but the promotion declined as N in put increased. Important, soil moisture had great effects on Rt and its components in the spruce forest (P<0.05), but no obvious impacts were observed in the fir forest (P>0.05). Following N fertilization, Ra was significantly and positively related to fine root biomass, while Rh was related to soil enzymatic activities in both forests. The mechanisms underlying the effect of simulated N deposition on soil respiration and its components in this study may help in forecasting C cycling in alpine forests under future levels of reactive N deposition. | Jian Wang Genxu Wang Yu Fu Xiaopeng Chen Xiaoyan Song | 2019 | Journal of Forestry Research2019，30，3： | 5 |
| 6 | Corrigendum to'Preparation of high-purity straight silicon nanowires by molten salt electrolysis'[Journal of Energy Chemistry 40(2020)171-179]显示文摘 | Jie Zhang Sheng Fang Xiaopeng Qi Zhanglong Yu Zhaohui Wu Juanyu Yang Shigang Lu | 2020 | Journal of Energy Chemistry2020，29，1： | 5 |
| 7 | Accelerometer-based Gait Authentication via Neural Network显示文摘 | SUN Hu YUAN Tao LI Xiaopeng HU Yu | 2012 | Chinese Journal of Electronics2012，21，3： | 4 |
| 8 | The rational design of multiple molecular module-based assemblies for simultaneously improving rice yield and grain quality显示文摘Rice is one of the most important staple food for over half of the world's population,and a substantial increase in productivity and quality of rice grain will be required to feed a growing human population.Grain size and shape are the two important components contributing to grain yield and quality,because they impact both yield potential and end-use quality.Over the past 50 years。 | Kun Wu Xiaopeng Xu Nan Zhong Haixiang Huang Jianping Yu Yafeng Ye Yuejin Wu Xiangdong Fu | 2018 | Journal of Genetics and Genomics2018，45，6： | 4 |
| 9 | Antibacterial activities against Porphyromonas gingivalis and biological characteristics of copper-bearing PEO coatings on magnesium显示文摘Unlike other parts of the body, jaw defection often involves dental and periodontal tissues, which colonized a great many oral anaerobic bacteria. As a remarkable degradable material, magnesium has become an excellent candidate for orthopedic appliances recently. But the high degradation rate is still a big problem. Making a biodegradable coating with good biocompatibility to slow down the degeneration rate of magnesium is one of the best methods. However, protective coatings will impair the antibacterial effects of magnesium which is caused by the rise of p H value throughout its degradation. To solve this problem, a series of composite coatings with different amounts of Cu O particles(3, 5 and 7 wt.%) were fabricated on pure magnesium through plasma electrolytic oxidation(PEO) to investigate in vitro biocompatibility and the antibacterial abilities against Porphyromonas gingivalis(P. gingivalis). Surface characterization and degradation behavior of the copper-bearing PEO coatings were also systematically studied. Furthermore,the most optimum coating was also systematically studied by X-ray photoelectron spectroscopy(XPS)and electrochemical corrosion test. Results of the present research revealed that adding proper amount of Cu O into PEO coatings could greatly improve the antibacterial abilities of the PEO coatings. The antibacterial activities of copper-bearing PEO coatings were excellent and revealed concentration-dependent and time-dependent. Biocompatibility of copper-bearing PEO coatings showed that proper amount of Cu could promote cell proliferation. Compared with other PEO coatings in this study, PEO-7 Cu showed some inhibition effects on cell proliferation and adhesion for long-term use. Electrochemical corrosion tests and immersion tests showed that PEO-5 Cu and PEO-7 Cu copper-bearing PEO coatings would provide satisfying corrosion resistance effects, while PEO-3 Cu was poorer than PEO coatings without Cu. However, compared with uncoated pure magnesium, the corrosion resistance of the PEO coating was much better. Based on the results of antibacterial ability, biocompatibility, and corrosion resistance of the above copper-bearing PEO coatings, PEO-5 Cu in this research was recommended to be used in patients with jaw defects. | Dan Zhang Qi Han Kun Yu Xiaopeng Lu Ying Liu Ze Lu Qiang Wang | 2021 | Journal of Materials Science & Technology2021，，2： | 4 |
| 10 | Progress of Jinping Underground laboratory for Nuclear Astrophysics(JUNA)显示文摘Jinping Underground laboratory for Nuclear Astrophysics(JUNA) will take the advantage of the ultra-low background of CJPL lab and high current accelerator based on an ECR source and a highly sensitive detector to directly study for the first time a number of crucial reactions occurring at their relevant stellar energies during the evolution of hydrostatic stars. In its first phase, JUNA aims at the direct measurements of^(25)Mg(p,γ)^(26)Al,^(19)F(p,α)^(16)O,^(13)C(α,n)^(16)O and ^(12)C(α,γ)^(16)O reactions. The experimental setup,which includes an accelerator system with high stability and high intensity, a detector system, and a shielding material with low background, will be established during the above research. The current progress of JUNA will be given. | WeiPing Liu ZhiHong Li JiangJun He XiaoDong Tang Gang Lian Zhu An JianJun Chang Han Chen QingHao Chen XiongJun Chen ZhiJun Chen BaoQun Cui XianChao Du ChangBo Fu Lin Gan Bing Guo GuoZhu He Alexander Heger SuQing Hou HanXiong Huang Ning Huang BaoLu Jia LiYang Jiang Shigeru Kubono JianMin Li KuoAng Li Tao Li YunJu Li Maria Lugaro XiaoBing Luo HongYi Ma ShaoBo Ma DongMing Mei YongZhong Qian JiuChang Qin Jie Ren YangPing Shen Jun Su LiangTing Sun WanPeng Tan Isao Tanihata Shuo Wang Peng Wang YouBao Wang Qi Wu ShiWei Xu ShengQuan Yan LiTao Yang Yao Yang XiangQing Yu Qian Yue Sheng Zeng HuanYu Zhang Hui Zhang LiYong Zhang NingTao Zhang QiWei Zhang Tao Zhang XiaoPeng Zhang XueZhen Zhang ZiMing Zhang Wei Zhao Zuo Zhao Chao Zhou | 2016 | Science China(Physics,Mechanics & Astronomy)2016，59，4： | 3 |
| 11 | A CRISPR/Cas12a-empowered surface plasmon resonance platform for rapid and specific diagnosis of the Omicron variant of SARS-CoV-2显示文摘The outbreak of the COVID-19 pandemic was partially due to the challenge of identifying asymptomatic and presymptomatic carriers of the virus,and thus highlights a strong motivation for diagnostics with high sensitivity that can be rapidly deployed.On the other hand,several concerning SARS-CoV-2 variants,including Omicron,are required to be identified as soon as the samples are identified as‘positive’.Unfortunately,a traditional PCR test does not allow their specific identification.Herein,for the first time,we have developed MOPCS(Methodologies of Photonic CRISPR Sensing),which combines an optical sensing technology-surface plasmon resonance(SPR)with the‘gene scissors’clustered regularly interspaced short palindromic repeat(CRISPR)technique to achieve both high sensitivity and specificity when it comes to measurement of viral variants.MOPCS is a low-cost,CRISPR/Cas12a-systemempowered SPR gene-detecting platform that can analyze viral RNA,without the need for amplification,within 38 min from sample input to results output,and achieve a limit of detection of 15 fM.MOPCS achieves a highly sensitive analysis of SARS-CoV-2,and mutations appear in variants B.1.617.2(Delta),B.1.1.529(Omicron)and BA.1(a subtype of Omicron).This platform was also used to analyze some recently collected patient samples from a local outbreak in China,identified by the Centers for Disease Control and Prevention.This innovative CRISPR-empowered SPR platform will further contribute to the fast,sensitive and accurate detection of target nucleic acid sequences with single-base mutations. | Zhi Chen Jingfeng Li Tianzhong Li Taojian Fan Changle Meng Chaozhou Li Jianlong Kang Luxiao Chai Yabin Hao Yuxuan Tang Omar AAl-Hartomy Swelm Wageh Abdullah GAl-Sehemi Zhiguang Luo Jiangtian Yu Yonghong Shao Defa Li Shuai Feng William J.Liu Yaqing He Xiaopeng Ma Zhongjian Xie Han Zhang | 2022 | National Science Review2022，9，8： | 3 |
| 12 | Recent Advances in Wide Bandgap Polymer Donors and Their Applications in Organic Solar Cells显示文摘Organic solar cells(OSCs)have attracted wide research interests in the past decades.In recent years,our group mainly focused on the new photovoltaic materials design and device engineering technologies for highly efficient OSCs.This account mainly summarizes our recent studies on the structural design of wide bandgap(WBG)polymers and their morphology control as well as applications in OSCs.Additionally,we introduce our work on binary and ternary blend devices and tandem solar cells containing these materials. | Xiaopeng Xu Liyang Yu Qiang Peng | 2021 | Chinese Journal of Chemistry2021，39，2： | 3 |
| 13 | Injectable kartogenin and apocynin loaded micelle enhances the alleviation of intervertebral disc degeneration by adipose-derived stem cell显示文摘Cell transplantation has been proved the promising therapeutic effects on intervertebral disc degeneration(IVDD).However,the increased levels of reactive oxygen species(ROS)in the degenerated region will impede the efficiency of human adipose-derived stem cells(human ADSCs)transplantation therapy.It inhibits human ADSCs proliferation,and increases human ADSCs apoptosis.Herein,we firstly devised a novel amphiphilic copolymer PEG-PAPO,which could self-assemble into a nanosized micelle and load lipophilic kartogenin(KGN),as a single complex(PAKM).It was an injectable esterase-responsive micelle,and showed controlled release ability of KGN and apocynin(APO).Oxidative stimulation promoted the esterase activity in human ADSCs,which accelerate degradation of esterase-responsive micelle.Compared its monomer,the PAKM micelle possessed better bioactivities,which were attributed to their synergistic effect.It enhanced the viability,autophagic activation(P62,LC3 II),ECM-related transcription factor(SOX9),and ECM(Collagen II,Aggrecan)maintenance in human ADSCs.Furthermore,it is demonstrated that the injection of PAKM with human ADSCs yielded higher disc height and water content in rats.Therefore,PAKM micelles perform promoting cell survival and differentiation effects,and may be a potential therapeutic agent for IVDD. | Chao Yu Dongdong Li Chenggui Wang Kaishun Xia Jingkai Wang Xiaopeng Zhou Liwei Ying Jiawei Shu Xianpeng Huang Haibin Xu Bin Han Qixin Chen Fangcai Li Jianbin Tang Chengzhen Liang Nigel Slater | 2021 | Bioactive Materials2021，6，10： | 3 |
| 14 | The crystal structure of Ac-AChBP in complex with α-conotoxin LvlA reveals the mechanism of its selectivity towards different nAChR subtypes显示文摘3* nAChRs,被认为为象疼痛那样的问题正在答应药目标,嗜好,心血管的功能,认知混乱等等,在整个中央、外部的神经系统被发现。-conotoxin (-CTx) LvIA 作为迄今为止知道的 32 nAChRs 的最选择的禁止者被识别了,并且它能把 32 nAChR 子类型与 6/323 和 34 种 nAChR 子类型区分开来。然而,它向 32 的选择的机制, 6/323,和 34 nAChRs 留下逃犯。这里,我们在 3.4 的一个决定与 Aplysia californica 醋胆素绑定蛋白质(Ac-AChBP ) 在建筑群报导 LvIA 的合作水晶结构 ? 。基于这建筑群的结构,和基于另外的 nAChR 子类型和有约束力的亲密关系试金当模特儿的相同,我们断定 LvIA 的 Asp-11 在选择起一个重要作用向 32 的 LvIA 和由做盐的 3/623 nAChRs 与老鼠的 Lys-155 衔接 3 子单元。在被老鼠的 Met-36, Thr-59,和 Phe-119 形成的一个恐水病的衣袋以内的 Asn-9 谎言在 32 nAChR 模型的 2 子单元,向 32 nAChR 子类型为它的更多的有势力选择揭示原因。这些结果提供能被用来设计 ligands 的分子的卓见有选择地指向 32 nAChRs,与为新治疗学的 -CTxs 的设计的重要含意。 | Manyu Xu Xiaopeng Zhu Jinfang Yu Jinpeng Yu Sulan Luo Xinquan Wang | 2017 | Protein & Cell2017，8，9： | 3 |
| 15 | H7N9 virus infection triggers lethal cytokine storm by activating gasdermin E-mediated pyroptosis of lung alveolar epithelial cells显示文摘The H7N9 influenza virus emerged in China in 2013,causing more than 1560 human infections,39% of which were fatal.A ‘cytokine storm’ in the lungs of H7N9 patients has been linked to a poor prognosis and death;however,the underlying mechanism that triggers the cytokine storm is unknown.Here,we found that efficient replication of the H7N9 virus in mouse lungs activates gasdermin E(GSDME)-mediated pyroptosis in alveolar epithelial cells,and that the released cytosolic contents then trigger a cytokine storm.Knockout of Gsdme switched the manner of death of A549 and human primary alveolar epithelial cells from pyroptosis to apoptosis upon H7N9 virus infection,and Gsdme knockout mice survived H7N9 virus lethal infection.Our findings reveal that GSDME activation is a key and unique mechanism for the pulmonary cytokine storm and lethal outcome of H7N9 virus infection and thus opens a new door for the development of antivirals against the H7N9 virus. | Xiaopeng Wan Jiqing Li Yupeng Wang Xiaofei Yu Xijun He Jianzhong Shi Guohua Deng Xianying Zeng Guobin Tian Yanbing Li Yongping Jiang Yuntao Guan Chengjun Li Feng Shao Hualan Chen | 2022 | National Science Review2022，9，1： | 3 |
| 16 | Synthesis of HTPB based PU-PS IPN Membrane for Pervaporation Recovery of Butanol显示文摘Hydroxyl terminated polybutadiene(HTPB) based polyurethane(PU)-polystyrene(PS) interpenetrating polymer network(IPN) was prepared and characterized by FTIR, TGA, WCA, swelling experiments, and SEM. The IPN was used for pervaporation(PV) recovery of butanol. Both the permeation flux and separation factor increased with feed temperature, and both water and butanol fluxes increased with feed concentration while no obvious effect of concentration on separation factor was found. Through the formation of IPN structure, the total flux of HTPB based PU increased greatly with the decrease of separation factor. At the feed temperature of 60 °C, the IPN membrane obtained a total flux of 613.3 g/m^2 h with a separation factor of 6.15. | 张凯 LI Li YU Wei HU Mingjie ZHOU Yongyan FAN Xiaopeng 廖俊 黄驰 | 2017 | Journal of Wuhan University of Technology(Materials Science)2017，32，6： | 2 |
| 17 | CRISPR-Cas12a-Empowered Electrochemical Biosensor for Rapid and Ultrasensitive Detection of SARS-CoV-2 Delta Variant显示文摘Coronavirus disease 2019(COVID-19)is a highly contagious disease caused by severe acute respiratory syndrome coronavirus 2(SARS-CoV-2).The gold standard method for the diagnosis of SARS-CoV-2 depends on quantitative reverse transcription-polymerase chain reaction till now,which is time-consuming and requires expensive instrumentation,and the confirmation of variants relies on further sequencing techniques.Herein,we first proposed a robust technique-methodology of electrochemical CRISPR sensing with the advantages of rapid,highly sensitivity and specificity for the detection of SARS-CoV-2 variant.To enhance the sensing capability,gold electrodes are uniformly decorated with electro-deposited gold nanoparticles.Using DNA template identical to SARS-CoV-2 Delta spike gene sequence as model,our biosensor exhibits excellent analytical detection limit(50 fM)and high linearity(R2=0.987)over six orders of magnitude dynamic range from 100 fM to 10 nM without any nucleic-acid-amplification assays.The detection can be completed within 1 h with high stability and specificity which benefits from the CRISPR-Cas system.Furthermore,based on the wireless micro-electrochemical platform,the proposed biosensor reveals promising application ability in point-of-care testing. | Chenshuo Wu Zhi Chen Chaozhou Li Yabin Hao Yuxuan Tang Yuxuan Yuan Luxiao Chai Taojian Fan Jiangtian Yu Xiaopeng Ma Omar AAl-Hartomy SWageh Abdullah GAl-Sehemi Zhiguang Luo Yaqing He Jingfeng Li Zhongjian Xie Han Zhang | 2022 | Nano-Micro Letters2022，14，10： | 2 |
| 18 | Study on high efficient electric discharge milling of silicon carbide ceramic with high resistivity显示文摘A new method which employs a group pulse power supply for electric discharge milling of the silicon carbide ceramic with the resistivity of 500 Ω·cm is presented. Due to the good machining stability and high pulse utilization, the material removal rate (MRR) can reach 72.9 mm3/min. The effects of high-frequency pulse duration, high-frequency pulse interval, peak voltage, peak current, polarity, rotate speed and group frequency on the process performance have been investigated. Also the EDMed surface microstructure is examined with a scanning electron microscope (SEM), an X-ray diffraction (XRD), an energy dispersive spectrometer (EDS) and a micro hardness tester. The results show that the conditions of smaller high-frequency pulse duration and pulse interval, higher peak voltage and peak current, and positive tool polarity are suitable for machining the SiC ceramic. The optimal rotate speed is 1090 r/min and the preferable group frequency is 730 Hz. In addition, there is a small quantity of iron on machined surface when machining with steel electrode. The average grain size of the EDMed surface is smaller than that of the unprocessed, and the micro hardness of machined surface is superior to that of the unprocessed. | JI RenJie LIU YongHong YU LiLi LI XiaoPeng DONG Xin | 2008 | Chinese Science Bulletin2008，53，20： | 2 |
| 19 | Flexible Vertex Engineers the Controlled Assembly of Distorted Supramolecular Tetrahedral and Octahedral Cages显示文摘Designing and building unique cage asemblies atrat increasing interet from supramolecular chemists but remain synthetically challenging.Herein,we propose the use of a flexible vertex with adjustable angles to selectively form highly distorted tetrahedral and octahedral cages,for the first time,in which the flexible ve rtex forms from the synergistic eft of coordination and covalent interactions.The inherent interligand angle of the vertex can be modulated by guest anions present,which allows for the fine-tuning of diferent cage geometries.Furthermore,the reversible structural transformation between tetrahedral and octahedral cages was achieved by anion exchange monitored by mass spectrometric technique,the smaller anions favoring tetrahedral cages,while the larger anions supporting octahedral cages.Additionally,the KBr-based cage thin films exhibited prominent enhancement of their third-order NLO responses in two or three orders of magnitude compared to those obtained for their corresponding solutions.This work not only provides a new methodology to build irregular polyhedral structures in a controlled and tunable way but also provides access to new kinds of promising functional optical materials. | Shu-Jin Bao Ze-Ming Xu Tian-Chen Yu Ying-Lin Song Heng Wang Zheng Niu Xiaopeng Li Brendan F.Abrahams Pierre Braunstein Jian-Ping Lang | 2022 | Research2022，，2： | 2 |
| 20 | Transsphenoidal microsurgical treatment of infradiaphragmatic craniopharyngioma显示文摘Objective Typically,the transcranial approach has been used for the treatment of craniopharyngiomas with suprasellar extension,whereas the transsphenoidal approach has been used mostly for infradiaphragmatic craniopharyngioma.Total resection of craniopharyngioma can reduce the recurrence rate,especially in young children,but it may lead to severe complications.Therefore,any benefit of the degree of resection must be weighed against the risk of complications by the surgeons.The purpose of this study was to explore the therapeutic outcome after transsphenoidal microsurgical treatment of infradiaphragmatic craniopharyngioma and share our experiences.Methods Between January 2003 and June 2013,30 patients with infradiaphragmatic craniopharyngioma underwent transsphenoidal microsurgical resection in our hospital.The neurological,visual,and endocrine functions,and extent of resection were analyzed retrospectively.Recurrence or growth of residual tumor tissue during follow-up was assessed using magnetic resonance imaging(MRI).Results Total resection was achieved in 25 patients(83.3%),subtotal resection was achieved in 4 patients(13.3%),and partial resection was achieved in 1 patient(3.4%).There were no perioperative deaths.Cerebrospinal fluid(CSF) leakage occurred in 6 patients,and among them,2 required surgical repair of the sella.New-onset postoperative diabetes insipidus(DI) developed in 8 patients.Vision and visual fields were improved at different levels in 13 out of 16 patients who had sight impediments before treatment.Tumor recurrence and regrowth was observed in 2 patients;1 patient underwent transsphenoidal reoperation,the condition of the other patient who had undergone several craniotomies grew worse over the 6-month follow-up period.Conclusion Transsphenoidal surgery is an ideal choice in treating infradiaphragmatic craniopharyngioma.The transsphenoidal approach,which preserves pituitary function and avoids damage to the hypothalamic structures and optic nerve,is associated with fewer complications than the transcranial approach and a low mortality rate. | Ting Lei Baofeng Wang Juan Chen Yu Xu Kai Shu Wei Sun Shaozheng Liu Xiaopeng Li | 2016 | Oncology and Translational Medicine2016，2，5： | 2 |
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