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2篇 您的检索式:作者名="Thomas Ederth"
    题名 作者 年代 出处 被引量
1A neutron reflectivity study of drainage and stratification of AOT foam films 显示文摘EDERTH T THOMAS R K 2003Langmuir2003,19,19:1
2Towards electrochemical hydrogen storage in liquid organic hydrogen carriers via proton-coupled electron transfers显示文摘Green hydrogen is identified as one of the prime clean energy carriers due to its high energy density and a zero emission of CO_(2).A possible solution for the transport of H_(2)in a safe and low-cost way is in the form of liquid organic hydrogen carriers(LOHCs).As an alternative to loading LOHC with H_(2)via a two-step procedure involving preliminary electrolytic production of H_(2)and subsequent chemical hydrogenation of the LOHC,we explore here the possibility of electrochemical hydrogen storage(EHS)via conversion of proton of a proton donor into a hydrogen atom involved in covalent bonds with the LOHC(R)via a protoncoupled electron transfer(PCET)reaction:2nH^(+)+2ne^(-)+Rox■n H_(2)^(0)Rred.We chose 9-fluorenone/fluorenol(Fnone/Fnol)conversion as such a model PCET reaction.The electrochemical activation of Fnone via two sequential electron transfers was monitored with in-situ and operando spectroscopies in absence and in presence of different alcohols as proton donors of different reactivity,which enabled us to both quantify and get the mechanistic insight on PCET.The possibility of hydrogen extraction from the loaded carrier molecule was illustrated by chemical activation.Hamid Ghorbani Shiraz Mikhail Vagin Tero-Petri Ruoko Viktor Gueskine Krzysztof Karon Mieczystaw tapkowski Tobias Abrahamsson Thomas Ederth Magnus Berggren Xavier Crispin 2022Journal of Energy Chemistry2022,31,10:0
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