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您的检索式：作者名="Sabrieon Sanders"
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| 1 | Assessing the effects of surface-bound humic acid on the phototoxicity of anatase and rutile TiO_2 nanoparticles in vitro显示文摘In this study,the cytotoxicity of two different crystal phases of TiO_2 nanoparticles,with surface modification by humic acid(HA),to Escherichia coli,was assessed.The physicochemical properties of TiO_2 nanoparticles were thoroughly characterized.Three different initial concentrations,namely 50,100,and 200 ppm,of HA were used for synthesis of HA coated TiO_2 nanoparticles(denoted as A/RHA50,A/RHA100,and A/RHA200,respectively).Results indicate that rutile(LC50(concentration that causes 50%mortality compared the control group)=6.5)was more toxic than anatase(LC_50=278.8)under simulated sunlight(SSL)irradiation,possibly due to an extremely narrow band gap.It is noted that HA coating increased the toxicity of anatase,but decreased that of rutile.Additionally,AHA50 and RHA50had the biggest differences compared to uncoated anatase and rutile with LC_50of 201.9 and21.6,respectively.We then investigated the formation of reactive oxygen species(ROS)by TiO_2 nanoparticles in terms of hydroxyl radicals(OH)and superoxide anions(O_2^-).Data suggested that O_2^- was the main ROS that accounted for the higher toxicity of rutile upon SSL irradiation.We also observed that HA coating decreased the generation of OH and O_2^- on rutile,but increased O_2^- formation on anatase.Results from TEM analysis also indicated that HA coated rutile tended to be attached to the surface of E.coli more than anatase. | Xiaojia He Sabrieon Sanders Winfred G.Aker Yunfeng Lin Jessica Douglas Huey-min Hwang | 2016 | Journal of Environmental Sciences2016，28，4： | 6 |
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