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3篇 您的检索式:作者名="Radovan DIMITRIJEVIC"
    题名 作者 年代 出处 被引量
1Crystal Structure and Chemical Composition of Ludwigite from Vranovac Ore Deposit (Boranja Mountain,Serbia)显示文摘The crystal structure of ludwigite from Vranovac ore deposit (Boranja Mt., Serbia) was refined using the X-ray powder diffraction (XRPD) Rietveld method in the space group Pbam to a final RB=7.45% and RF=5.26%. It has the unit cell dimensions of: a=9.2515(2) ; b=12.3109(2) ; c=3.03712(7) ; and V=345.91(1) 3. The calculated distances and angles are mostly in good agreement with the Mg2+-Fe2+ substitutions across the M(1) and M(3) sites, as well as with the Fe3+-Al3+ replacement in the M(4) site. However, the mean observed M(2)-O distance is considerably shorter than prescribed, due to a slight increase of the Fe3+ content in the M(2) site. Such replacement was compensated by slight increase of the Fe2+ content in the M(4) site, resulting in the (Mg1.48Fe2+0.46Fe3+0.05Mn0.02)2.01(Fe3+0.94Fe2+0.04Al0.02)1.00B1.00O5 composition. The formation temperature was estimated to be about 500-600°C. The influences of the various chemical compositions to the crystallographic parameters, M-O distances, M(3) and M(4) sites shift, distortion parameters and estimated valences, were also studied and compared with other reference samples.Pavle TANCIC Radovan DIMITRIJEVIC Maja POZNANOVIC Aleksandar PACEVSKI Slobodanka SUDAR 2012Acta Geologica Sinica(English Edition)2012,86,6:1
2FTIR Spectroscopy of Framework Aluminosilicate Structures:Carnegieite and Pure Sodium Nepheline显示文摘Smilja Markovic Vera Dondur Radovan Dimitrijevic 2003Journal of Molecular Structure2003,654,:1
3Macroscopically-Zoned Grandite from the Garnetite Skarn of Meka Presedla(Kopaonik Mountain,Serbia)显示文摘The macroscopically-zoned grandite from the garnetite skarn of Meka Presedla(Kopaonik Mountain,Serbia) was studied with optical microscopy,electron microprobe analysis(EMPA),Fourier transform infra-red(FT-IR),and Raman methods.The EMPA results indicate that the main core-rim compositional variations(Ca2.93-2.97Mn0.05-0.06Mg0.00-0.01Al1.14-1.26Fe3+0.72-0.83Ti0.00-0.02Si2.97-3.02O12) slightly differ along the zones,showing evidence for a quasi-cyclic alternation of the oscillatory zoning nature.Among this,considerable variation is observed only by the Al-Fe3+ substitutions in the octahedral site.The EMPA also indicate that the grandite zones compositionally vary,mostly within ±1 and ±2 mol% of the homogeneity level range,that is,Grs64±1Adr36±1Sps2(A),Grs62±1Adr38±1Sps2(B),Grs59±2Adr40±2Sps2(C),Grs58±2Adr41±2Sps2(D),and Grs58±1Adr41±1Sps2(E).Therefore,the investigated garnet can be considered as relatively highly homogeneous.The majority of compositions lie within the narrow miscibility region of 0.58±2Pavle TANCIC Predrag VULIC Reinhard KAINDL Bernhard SARTORY Radovan DIMITRIJEVIC 2012Acta Geologica Sinica(English Edition)2012,86,2:1
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