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| 1 | Applications of Metal–Organic Frameworks and Their Derivatives in Electrochemical CO_(2)Reduction显示文摘Electrochemically reducing CO_(2)to more reduced chemical species is a promising way that not only enables the conversion of intermittent energy resources to stable fuels,but also helps to build a closed-loop anthropogenic carbon cycle.Among various electrocatalysts for electrochemical CO_(2)reduction,multifunctional metal–organic frameworks(MOFs)have been employed as highly efficient and selective heterogeneous electrocatalysts due to their ultrahigh porosity and topologically diverse structures.Up to now,great progress has been achieved in the design and synthesis of highly active and selective MOF-related catalysts for electrochemical CO_(2)reduction reaction(CO_(2)RR),and their corresponding reaction mechanisms have been thoroughly studied.In this review,we summarize the recent progress of applying MOFs and their derivatives in CO_(2)RR,with a focus on the design strategies for electrocatalysts and electrolyzers.We first discussed the reaction mechanisms for different CO_(2)RR products and introduced the commonly applied electrolyzer configurations in the current CO_(2)RR system.Then,an overview of several categories of products(CO,HCOOH,CH_(4),CH_(3)OH,and multi-carbon chemicals)generated from MOFs or their derivatives via CO_(2)RR was discussed.Finally,we offer some insights and perspectives for the future development of MOFs and their derivatives in electrochemical CO_(2)reduction.We aim to provide new insights into this field and further guide future research for large-scale applications. | Chengbo Li Yuan Ji Youpeng Wang Chunxiao Liu Zhaoyang Chen Jialin Tang Yawei Hong Xu Li Tingting Zheng Qiu Jiang Chuan Xia | 2023 | Nano-Micro Letters2023，15，8： | 2 |
| 2 | Concept of the Solar Ring mission: Preliminary design and mission profile显示文摘The Solar Ring mission, a concept to monitor the Sun and inner heliosphere from multiple perspectives, has been funded for prephase study by the Strategic Priority Program of Chinese Academy of Sciences in space sciences. The Solar Ring is comprised of 6 spacecraft, grouped in three pairs, moving around the Sun in an elliptical orbit in the ecliptic plane. The mission costs,including launch fee, deep-space maneuvers, and deployment time of the ring, are highly relevant to the working orbit, deepspace transfer, and phase angle within a group. The preliminary mission profile is analyzed and designed in this paper. The launch way, two spacecraft with one rocket, is adopted. The deployment time, phasing maneuvers, and C_(3) of launch energy are evaluated for the elliptical orbits with the perihelion between 0.7 and 0.9 AU using the rockets of Long March(LM) 3A and 3B.Numerical simulations show two candidate trajectories: fast deployment within 4 years by LM-3B, medium deployment more than 6 years by cheaper rocket of LM-3A. In order to obtain both fast deployment and low launch cost, another orbit profile is proposed by shortening the phase angle within a group. The suggested working orbits and the corresponding costs of launch,deployment time, and phasing maneuvers will strongly support the science objectives. | WANG YaMin CHEN Xin WANG PengCheng QIU ChengBo WANG YuMing ZHANG YongHe | 2021 | Science China(Technological Sciences)2021，64，1： | 1 |
| 3 | Highly efficient red phosphorescent light-emitting diodes based on ruthenium(II)-complex-doped semiconductive polymers 显示文摘 | Xia Hong Zhang Chengbo Qiu Song | 2004 | Applied Physics Letters2004，84，2： | 1 |
| 4 | Highly efficient red phosphorescent light-emitting diodes based on ruthenium (Ⅱ)-complex-doped semiconductive polymers显示文摘 | Xia Hong Zhang Chengbo Qiu Song | 2004 | Applied Physics Letters2004，84，2： | 1 |
| 5 | Electrochemical CO_(2) reduction:Progress and opportunity with alloying copper显示文摘Electroreduction of carbon dioxide(CO_(2)) into value-added chemicals offers an entrancing approach to main-taining the global carbon cycle and eliminating environmental threats.A key obstacle to achieving long-term and large-scale implementation of electrochemical CO_(2) reduction technology is the lack of active and selective cat-alysts.Copper(Cu)is one of the few candidates that can facilitate C–C coupling to obtain high-energy oxygenates and hydrocarbons beyond carbon monoxide(CO),but it suffers from poor selectivity for products of interest and high overpotentials.Alloying is an effective way to break the linear scaling relations and uniquely manipulate the reactivity and selectivity,which is hard to achieve by using monometallic compositions alone.By alloying Cu with other metals,one could change the catalytic properties of the catalyst by tuning the local electronic structure and modulating the adsorption strength of the reaction intermediates,thus improving the catalytic activity and selectivity.In this review,we focus on the recently developed Cu-based alloy catalysts(including conventional alloys,high-entropy alloys and single-atom alloys)that have been applied in electrocatalytic CO_(2) reduction(ECR).Theoretical calculations and experimental advances in understanding the key rate-limiting and selectivity-determining steps in those alloys are summarized,with a particular focus on identifying binding energy de-scriptors and the dynamic product formation mechanisms.In addition,we outline the opportunities and chal-lenges in the fundamental understanding of ECR by recommending advanced in-situ characterization techniques and standardized electrochemical methods and offer atomic-level design principles for steering the reaction pathways to the desired products. | Mao Ding Zhaoyang Chen Chunxiao Liu Youpeng Wang Chengbo Li Xu Li Tingting Zheng Qiu Jiang Chuan Xia | 2023 | Materials Reports(Energy)2023，3，1： | 0 |
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