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您的检索式：作者名="P.Gregory Van Patten"
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| 1 | Cation engineering on lead iodide perovskites for stable and high-performance photovoltaic applications显示文摘Perovskite solar cells(PSCs) based on methylammonium lead iodide(CH_3NH_3PbI_3) have shown unprecedentedly outstanding performance in the recent years. Nevertheless, due to the weak interaction between polar CH_3NH_3^+(MA^+) and inorganic PbI_3-sublattices, CH_3NH_3PbI_3 dramatically suffers from poor moisture stability, thermal decomposition and device hysteresis. As such, strong electrostatic interactions between cations and anionic frameworks are desired for synergistic improvements of the abovementioned issues. While replacements of I-with Br-and/or Cl-evidently widen optical bandgaps of perovskite materials, compositional modifications can solely be applied on cation components in order to preserve the broad absorption of solar spectrum. Herein, we review the current successful practices in achieving efficient, stable and minimally hysteretic PSCs with lead iodide perovskite systems that employ photoactive cesium lead iodide(CsPbI_3), formamidinium lead iodide(HC(NH_2)_2 PbI_3, or FAPbI_3),MA_(1-x-y-z_FA_xCs_yRb_zPbI_3 mixed-cation settings as well as two-dimensional butylammonium(C_4H_9NH_3^+,or BA^+)/MA^+, polymeric ammonium(PEI+)/MA+co-cation layered structures. Fundamental aspects behind the stabilization of perovskite phases α-CsPbI_3, α-FAPbI_3, mixed-cation MA_(1-x-y-z)FA_xCs_yRb_zPbI_3 and crystallographic alignment of(BA)_2(MA)_3 Pb_4I_(13) for effective light absorption and charge transport will be discussed. This review will contribute to the continuous development of photovoltaic technology based on PSCs. | Jue Gong Peijun Guo Savannah E.Benjamin P.Gregory Van Patten Richard D.Schaller Tao Xu | 2018 | Journal of Energy Chemistry2018，27，4： | 3 |
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