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您的检索式：作者名="Jianghai Deng"
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| 1 | Controlled synthesis of single cobalt atom catalysts via a facile one-pot pyrolysis for efficient oxygen reduction and hydrogen evolution reactions显示文摘Metal-nitrogen doped carbon catalysts(M-N/C) with abundantly accessible M-Nxsites, particularly single metal atom M-N/C(SAM-N/C), have been developed as a substitute for expensive Pt-based catalysts.These catalysts are used to increase the efficiency of otherwise sluggish oxygen reduction reactions(ORR) and hydrogen evolution reactions(HER). However, although the agglomerated metal nanoparticles are usually easy to form, they are very difficult to remove due to the protective surface-coating carbon layers, a factor that significantly hampers SAM-N/C fabrication. Herein, we report a one-step pyrolysis approach to successfully fabricate single cobalt atom Co-N/C(SACo-N/C) by using a Co2+-SCN-coordination compound as the metal precursor. Thanks to the decomposition of Co2+-SCN-compound at lower temperature than that of carbon layer deposition, Co-rich particles grow up to larger ones before carbon layers formation. Even though encapsulated by the carbon layers, it is difficult for the large Co-rich particle to be completely sealed. And thus, it makes the Co atoms possible to escape from incomplete carbon layer, to coordinate with nitrogen atoms, and to form SACo-N/C catalysts. This SACo-N/C exhibits excellent performances for both ORR(half-wave potential of 0.878 V) and HER(overpotential at 10 mA/cm2 of178 m V), and is thus a potential replacement for Pt-based catalysts. When SACo-N/C is integrated into a Zn-O2 battery, battery with high open-circuit voltage(1.536 V) has high peak power density(266 mW/cm2)and large gravimetric energy density(755 mA h/gZn) at current densities of 100 mA/cm2. Thus, we believe that this strategy may offer a new direction for the effective generation of SAM-N/C catalysts. | Yao Wang Linhui Chen Zhanxin Mao Lishan Peng Rui Xiang Xianyi Tang Jianghai Deng Zidong Wei Qiang Liao | 2019 | Science Bulletin2019，64，15： | 10 |
| 2 | Hierarchically porous nitrogen-doped carbon as cathode for lithium–sulfur batteries显示文摘Porous nitrogen-doped carbon is an especially promising material energy storage due to its excellent conductivity, stable physicochemical properties, easy processability, controllable porosity and low price.Herein, we reported a novel well-designed hierarchically porous nitrogen-doped carbon(HPNC) via a combination of salt template(ZnCl_2) and hard template(SiO_2) as sulfur host for lithium–sulfur batteries. The low-melting ZnCl_2 is boiled off and leaves behind micropores and small size mesopores during pyrolysis process, while the silica spheres are removed by acid leaching to generate interconnected 3D network of macropores. The HPNC-S electrode exhibits an initial specific capacity of 1355 mAh g^(–1) at 0.1 C(1 C = 1675 m Ah g^(–1)), a high-rate capability of 623 m Ah g^(–1) at 2 C, and a small decay of 0.13% per cycle over 300 cycles at 0.2 C. This excellent rate capability and remarkable long-term cyclability of the HPNC-S electrode are attributed to its hierarchical porous structures for confining the soluble lithium polysulfide as well as the nitrogen doping for high absorbability of lithium polysulfide. | Rui Wu Siguo Chen Jianghai Deng Xun Huang Yujie Song Ruiyi Gan Xiaoju Wan Zidong Wei | 2018 | Journal of Energy Chemistry2018，27，6： | 8 |
| 3 | Influence of cooling rate after homogenization on the flow behavior of aluminum alloy 7050 under hot compression显示文摘 | Shengdan Liu Jianghai You Xinming Zhang Yunlai Deng Yubao Yuan | 2009 | Materials Science & Engineering A2009，，4： | 2 |
| 4 | Simultaneous analysis of fourteen tertiary amine stimulants in human urine for doping control purposes by liquid chromatography - tandem mass spectrometry and gas chromatographymass spectrometry 显示文摘 | Jianghai Lu San Wang Ying Dong Xiaobing Wang Shuming Yang Jianli Zhang Jing Deng Yang Qin Youxuan Xu Moutian Wu Gangfeng Ouyang | 2010 | Analytica Chimica Acta2010，657，1： | 1 |
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