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1篇 您的检索式:作者名="HE Binling"
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1SYNTHESIS OF NEW POLY (p-PHENYLENEVINYLENE) DERIVATIVES WITH IMPROVED SOLUBILITY显示文摘PPV-based copolymers with cyano group in the main chain have been synthesized by Wittig-type polycondensation of alkoxy-substituted dialdehydes and 4,4’-bis(cyanomethyl)-substituted diphenyl ether: [―C6H4―O―C6H4―C(CN)(CH―C6H2(OR)2―C(C(CN)―]n (POPPV). The copolymers are highly soluble in common solvents and their super highly transparent homogeneous thin films can be formed by spin coating directly without heat treatment. The chemical structures are determined by NMR and IR spectroscopys and evaluated using photoluminescence, gel-permeation chromatography (GPC) and DSC (or TGA) methods. The incorporation of ether group into the PPV backbone has an interruption of the main-chain conjugation, that results in the blue-shift of electroluminescence spectra and enhancement the solubility.ZHANG Fuqiang YIN Shougen LIU Xiaohang HUANG Wenqiang HE Binling 2000Chinese Journal of Reactive Polymers2000,9,2:0
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