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| 1 | Evaluation of the microstructure,thermal and mechanical properties of Cu/SiC nanocomposites fabricated by mechanical alloying显示文摘Nano-sized silicon carbide(SiC:0wt%,1wt%,2wt%,4wt%,and 8wt%)reinforced copper(Cu)matrix nanocomposites were manufactured,pressed,and sintered at 775 and 875℃in an argon atmosphere.X-ray diffraction(XRD)and scanning electron microscopy were performed to characterize the microstructural evolution.The density,thermal expansion,mechanical,and electrical properties were studied.XRD analyses showed that with increasing SiC content,the microstrain and dislocation density increased,while the crystal size decreased.The coefficient of thermal expansion(CTE)of the nanocomposites was less than that of the Cu matrix.The improvement in the CTE with increasing sintering temperature may be because of densification of the microstructure.Moreover,the mechanical properties of these nanocomposites showed noticeable enhancements with the addition of SiC and sintering temperatures,where the microhardness and apparent strengthening efficiency of nanocomposites containing 8wt%SiC and sintered at 875℃were 958.7 MPa and 1.07 vol%^(−1),respectively.The electrical conductivity of the sample slightly decreased with additional SiC and increased with sintering temperature.The prepared Cu/SiC nanocomposites possessed good electrical conductivity,high thermal stability,and excellent mechanical properties. | Essam B.Moustafa Mohammed A.Taha | 2021 | International Journal of Minerals,Metallurgy and Materials2021,28,3: | 4 |
| 2 | Zeolitic imidazolate framework-67 derived Al-Co-S hierarchical sheets bridged by nitrogen-doped graphene:Incorporation of PANI derived carbon nanorods for solid-state asymmetric supercapacitors显示文摘Metal sulfides have been widely enticed as battery-type electrodes in supercapacitor devices because of their maximal theoretical capacitance.Nevertheless,their lower conductivity and ion transport kinetics can largely restrict their rate performance,hence the practical usage in fields of demanding high power devices.Therefore,the design of new electrodes with higher energy and power densities remains a highly challenging task.To the best of our knowledge,a novel hierarchical composite of Al-CoS_(2) on nitrogendoped graphene(NG)is prepared based on a zeolite imidazole framework using a simple and scalable hydrothermal process.In this hybrid,ultrathin Al-CoS_(2) nanosheet arrays are vertically orientated on the NG framework to limit self-aggregation,hence increasing the electrical property and cycle stability of composite.It is investigated that the Al/Co feeding ratio plays a crucial role in controlling the obtained hierarchical structure of Al-Co-S sheets and their electrode performance.Also,Al^(3+) can influence remarkably the morphology and electrochemical property of the resultant graphene composite.An effective synergism is noticed between the redox Al-CoS_(2) and NG resulting in fast electron transfer and chargingdischarging processes.Surprisingly,when the as-developed composite is utilized as a positive electrode at an applied current density of 1 A/g,a specific capacitance of 1915.8 F/g is attained with ultra-long cycle stability(96%,10,000 cycles)and an excellent retention rate(~89%).As a consequence,when a solid-state asymmetric supercapacitor(ASC)device is made by combining an Al-CoS_(2) @NG hybrid with a negative electrode made of polyaniline(PANI)derived carbon nanorods(PCNRs),it demonstrates remarkable specific capacitance(188 F/g),energy density(66.9 Wh/kg),and cyclic stability of 92%after 10,000 cycles.This may open the pathway for the application of the next-generation supercapacitors in the future. | Emad S.Goda Bidhan Pandit Sang Eun Hong Bal Sydulu Singu Seong K.Kim Essam B.Moustafa Kuk Ro Yoon | 2022 | Journal of Energy Chemistry2022,31,11: | 0 |
| 3 | Numerical and experimental analyses of rock failure mechanisms due to microwave treatment显示文摘Despite the extensive studies conducted on the effectiveness of microwave treatment as a novel rock preconditioning method,there is yet to find reliable data on the rock failure mechanisms due to microwave heating.In addition,there is no significant discussion on the energy efficiency of the method as one of the important factors among the mining and geotechnical engineers in the industry.This study presents a novel experimental method to evaluate two main rock failure mechanisms due to microwave treatment without applying any mechanical forces,i.e.distributed and concentrated heating.The result shows that the existence of a small and concentrated fraction of a strong microwave absorbing mineral will change the failure mechanism from the distributed heating to the concentrated heating,which can increase the weakening over microwave efficiency(WOME)by more than 10 folds.This observation is further investigated using the developed coupled numerical model.It is shown that at the same input energy,the existence of microwave absorbing minerals can cause major heat concentration inside the rock and increase the maximum temperature by up to three times. | Haitham M.Ahmed Adel Ahmadihosseini Ferri Hassani Mohammed A.Hefni HussinA.M.Ahmed Hussein A.Saleem Essam B.Moustafa Agus P.Sasmito | 2023 | Journal of Rock Mechanics and Geotechnical Engineering2023,15,10: | 0 |