| 19 | The Novel Benzo-15-Crown-5 with Palladium(II) Complex: [Na(B15CS)]_2,[Pd(SCN)_4]显示文摘A novel Pd(II) Benzo-15-crown-5 complex [Na(B15CS)]2[Pd(SCN)4] has been isolated and characterized by IR and X-ray diffraction analysis. The crystal structure belongs to monoclinic, space group P21,/n with cell dimensions, a = l.0164(6), b = l.3743(3), c = l.4987(7) nm, β = 95.248(6) °, V = 2.0847 'nm3, Z = 2, F(000) = 944, R = 0.053, Rw = 0.072. The compound consists of two [Na(B15CS)]+ complex canons and a [Pd(SCN)4]2- complex anion. Each sodium ion is coordinated by five crown ether oxygen atoms and one N atom from the SCN group of [Pd(SCN)4]2- to form stable neutral complex. | Lan Ying ZHU Jian Min DOU Ying LIU De Zhi SUN Pei Ju ZHENG Chen Xia DU Yu ZHU Department of Biology and Chemistry, Liaocheng Teacher’s University, Liaocheng 252000 Research Center of Analysis and Measurement, Fudan University, Shanghai 200433 Key | 2000 | Chinese Chemical Letters2000，11，9： | 1 |
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