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| 1 | Multilayer 3D Chirality and Its Synthetic Assembly显示文摘3D chirality of sandwich type of organic molecules has been discovered.Te key element of this chirality is characterized by three layers of structures that are arranged nearly in parallel fashion with one on top and one down from the center plane.Individual enantiomers of these molecules have been fully characterized by spectroscopies with their enantiomeric purity measured by chiral HPLC.Te absolute confguration was unambiguously assigned by X-ray difraction analysis.Tis is the frst multilayer 3D chirality reported and is anticipated to lead to a new research area of asymmetric synthesis and catalysis and to have a broad impact on chemical,medicinal,and material sciences in future. | Guanzhao Wu Yangxue Liu Zhen Yang Nandakumar Katakam Hossein Rouh Sultan Ahmed Daniel Unruh Kazimierz Surowiec Guigen Li | 2019 | Research2019，，1： | 3 |
| 2 | Multi-layer 3D chirality:new synthesis,AIE and computational studies显示文摘New synthesis of multi-layer 3 D chiral molecules has been developed under novel conditions to give better outcomes.The aggregation-induced emission(AIE),UV irradiation/excitation,charge transfer(CT)and local excited(LE)ππ*transitions have been investigated on a representative individual enantiomer of pseudo C_2 asymmetry which was made possibly by differentiating moieties on phosphorous on N-phosphonyl ring of chiral sandwich framework.Meanwhile,a new tandem C–N/C–C coupling reaction was unexpectedly rendered providing a novel access to special benzo[a]carbazoles. | Yangxue Liu Guanzhao Wu Zhen Yang Hossein Rouh Nandakumar Katakam Sultan Ahmed Daniel Unruh Zhonghua Cui Hans Lischka Guigen Li | 2020 | Science China Chemistry2020，63，5： | 1 |
| 3 | Enantioselective assembly of multi-layer 3D chirality显示文摘The first enantioselective assembly of sandwich-shaped organo molecules has been achieved by conducting dual asymmetric Suzuki-Miyaura couplings and nine other reactions.This work also presents the first fully C-C anchored multi-layer 3D chirality with optically pure enantiomers.As confirmed by X-ray diffraction analysis that this chiral framework is featured by a unique C2-symmetry in which a nearly parallel fashion consisting of three layers:top,middle and bottom aromatic rings.Unlike the documented planar or axial chirality,the present chirality shows its top and bottom layers restrict each other from free rotation,i.e.,this multi-layer 3D chirality would not exist if either top or bottom layer is removed.Nearly all multi-layered compounds showed strong luminescence of different colors under UV irradiation,and several randomly selected samples displayed aggregation-induced emission(AIE)properties.This work is believed to have broad impacts on chemical,medicinal and material sciences including optoelectronic materials in future. | Guanzhao Wu Yangxue Liu Zhen Yang Tao Jiang Nandakumar Katakam Hossein Rouh Liulei Ma Yao Tang Sultan Ahmed Anis URahman Hongen Huang Daniel Unruh Guigen Li | 2020 | National Science Review2020，7，3： | 1 |
| 4 | The failure of the Tacoma Bridge: A physical model 显示文摘 | Green Daniel Unruh William G | 2006 | American Journal of Physics2006，74，8： | 1 |
| 5 | Multilayer 3D Chiral Folding Polymers and Their Asymmetric Catalytic Assembly显示文摘A novel class of polymers and oligomers of chiral folding chirality has been designed and synthesized,showing structurally compacted triple.column/multiple layer frameworks.Both uniformed and diferentiated aromatic chromophoric units were successfully constructed between naphthy!piers of this framework.Screening monomers,catalysts,and catalytic systems led 1o the success of asymmetric catalytic Suzuki-Miyaura polycouplings Enantio-and diastereochemistry were unambiguously determined by X-ray structural analysis and concurrently by comparison with a similar asymmetric induction by the same catalyst in the asymmetric synthesis of a chiral three layered product.The resuling chiral polymers exhibit intense fluorescence activity in a solid form and solution under speci fic wavelength irradiation. | Yao Tang Shengzhou Jin Sai Zhang Guan-Zhao Wu Jia-Yin Wang Ting Xu Yu Wang Daniel Unruh Kazimierz Surowiec Yanzhang Ma Shiren Wang Courtney Katz Hongjun Liang Yunze Li Wellong Cong Guigen Li | 2022 | Research2022，，2： | 0 |
| 6 | Triple-Columned and Multiple-Layered 3D Polymers:Design,Synthesis,Aggregation-Induced Emission(AIE),and Computational Study显示文摘Conjugated polymers and oligomers have great potentials in various fields,especially in materials and biological sciences because of their intriguing electronic and optoelectronic properties.In recent years,the through-space conjugation system has emerged as a new assembled pattern of multidimensional polymers.Here,a novel series of structurally condensed multicolumn/multilayer 3D polymers and oligomers have been designed and synthesized through one-pot Suzuki polycondensation(SPC).The intramolecularly stacked arrangement of polymers can be supported by either X-ray structural analysis or computational analysis.In all cases,polymers were obtained with modest to good yields,as determined by GPC and 1 H-NMR.MALDI-TOF analysis has proven the speculation of the step-growth process of this polymerization.The computational study of ab initio and DFT calculations based on trimer and pentamer models gives details of the structures and the electronic transition.Experimental results of optical and AIE research confirmed by calculation indicates that the present work would facilitate the research and applications in materials. | Guanzhao Wu Yangxue Liu Zhen Yang Liulei Ma Yao Tang Xianliang Zhao Hossein Rouh Qixuan Zheng Peng Zhou Jia-Yin Wang Farhan Siddique Sai Zhang Shengzhou Jin Daniel Unruh Adelia JAAquino Hans Lischka Kristin M.Hutchins Guigen Li | 2021 | Research2021，，1： | 0 |
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