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    题名 作者 年代 出处 被引量
1通过4-磺基苯甲酸单钾盐抑制离子迁移以实现效率为22.7%的稳定钙钛矿太阳能电池显示文摘晶界处的深能级缺陷和严重的卤素离子迁移对进一步提高钙钛矿太阳能电池的稳定性和效率以及消除迟滞现象提出了严峻的挑战.本文报道了一种大尺寸强配位的有机阴离子晶界锚定策略来抑制离子迁移并钝化薄膜缺陷.本策略通过将含有大尺寸有机阴离子的钾盐(4-磺基苯甲酸单钾盐,SAMS)加入到钙钛矿前驱液中来实现.研究表明,阴离子两端的C=O和/或S=O能够与未配位的Pb^(2+)离子和/或卤化物空位之间发生强配位作用,阴离子中的–OH能够与甲脒阳离子形成氢键,以上化学作用使阴离子紧紧锚定在晶界处.SAMS不仅能够钝化浅能级缺陷,而且能够更有效地钝化深能级缺陷.该晶界锚定策略能降低钙钛矿薄膜的缺陷密度、延长载流子寿命和抑制离子迁移,提高电池的效率和稳定性以及消除迟滞效应.结果表明,基于SAMS改性的电池实现了22.7%的效率,而对照器件显示了20.3%的效率.未封装改性的器件在60℃加热老化1320小时后几乎没有发生衰减.白乐 姚方 王锐 刘白白 何冬梅 周倩 王文奇 徐寸云 胡小波 陈少强 宋群梁 周廷伟 Donghwa Lee 赵鹏君 陈聪 杨华 林乾乾 臧志刚 陈江照 2022Science China Materials2022,65,12:2
2Body-centered-cubic martensite and the role on room-temperature tensile properties in Si-added SiVCrMnFeCo high-entropy alloys显示文摘We present a new class of metastable high-entropy alloys(HEAs),triggering deformation-induced martensitic transformation(DIMT)from face-centered-cubic(FCC)to body-centered-cubic(BCC),i.e.,BCC-DIMT.Through the ab-initio calculation based on 1 st order axial interaction model and combined with the Gibbs free energy calculation,the addition of Si is considered as a critical element which enables to reduce the intrinsic stacking fault energy(ISFE)in Si_xV_((9-x))Cr_(10)Mn_5 Fe_(46)Co_(30)(x=2,4,and 7 at.%)alloy system.The ISFE decreases from-30.4 to-35.5 mJ/m^(2)as the Si content increases from 2 to 7 at.%,which well corresponds to the reduced phase stability of FCC against HCP.The BCC-DIMT occurs in all the alloys via intermediate HCP martensite,and the HCP martensite provides nucleation sites of BCC martensite.Therefore,the transformation rate enhances as the Si content increases in an earlier deformation ra nge.However,the BCC-DIMT is also affected by the phase stability of FCC against BCC,and the stability is the highest at the Si content of 7 at.%.Thus,the 7Si alloy presents the moderate transformation rate in the later deformation range.Due to the well-controlled transformation rate and consequent strain-ha rdening rate,the 7Si alloy possesses the superior combination of strength and ductility beyond 1 GPa of tensile strength at room temperature.Our results suggest that the Si addition can be a favorable candidate in various metastable HEAs for the further property improvement.Yong Hee Jo Junha Yang Won-Mi Choi Kyung-Yeon Doh Donghwa Lee Hyoung Seop Kim Byeong-Joo Lee Seok Su Sohn Sunghak Lee 2021Journal of Materials Science & Technology2021,,17:1
3Vision-based object detection and tracking for autonomous navigation of underwater robots显示文摘Donghwa Lee Gonyop Kim Donghoon Kim Hyun Myung Hyun-Taek Choi 2012Ocean Engineering2012,,:1
4Aluminum nitride waveguide beam splitters for integrated quantum photonic circuits显示文摘We demonstrate integrated photonic circuits for quantum devices using sputtered polycrystalline aluminum nitride(Al N)on insulator.On-chip Al N waveguide directional couplers,which are one of the most important components in quantum photonics,are fabricated and show the output power splitting ratios from 50:50 to 99:1.Polarization beam splitters with an extinction ratio of more than 10 d B are also realized from the Al N directional couplers.Using the fabricated Al N waveguide beam splitters,we observe Hong–Ou–Mandel interference with a visibility of 91.7%±5.66%.HYEONG-SOON JANG DONGHWA LEE HYUNGJUN HEO YONG-SU KIM HYANG-TAG LIM SEUNG-WOO JEON SUNG MOON SANGIN KIM SANG-WOOK HAN HOJOONG JUNG 2023Photonics Research2023,11,7:0
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