| 16 | (Online First)Synthesis,Structural,Thermal and Luminescence Studies of new DABCO bismuthate(III)hybrid material显示文摘The title compound Bis(1,4-diazabicyclo[2.2.2]octane)octachlorido-di-bismuthate(III)dihydrate was obtained by slow evaporation at room temperature of a hydrochloric aqueous solution(pH=1)containing bismuth(III)nitrate and the 1,4-diazabicyclo[2.2.2]octane(DABCO)in a 1:2 molar ratio.This material crystallizes in the P21/c monoclinic space group with a=7.875(1)A,b=18.380(2)A,c=10.445(2)A,β=105.95(1)°and Z=2.The structure exhibits a zero-dimensional(0D)periodic arrangement of bioctahedra(Bi2Cl10)4-surrounded by organic cations 1,4-diazabicyclo[2.2.2]octane(DABCO).The crystal cohesion is achieved by N-H…Cl,N-H…O and O-H…Cl hydrogen interaction linking the different parts of the structure.This compound was characterized by different techniques such as IR,DSC,TGA-DTA,XRD,XPRD and photoluminescence(PL)at room temperature. | Marwen Chouri Habib Boughzala | 2018 | Journal of Chemical Research and Application2018，1，2： | 0 |
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