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2篇 您的检索式:作者名="Alexander F.Shestakov"
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1New luminescent 10-oxybenzoquinolate complexes of rare earth metals显示文摘A series of Sc,Y,Ce,Pr,Nd,Sm,Eu,Gd,Tb,Ho,Er,Tm and Yb complexes with oxybenzoquinoline ligands(BQ) was synthesized by the reactions of 10-hydroxybenzo[h]quinoline with cyclopentadienides or tris(trimethylsilyl)amides of rare earth metals.The structure,as well as the photo-and electroluminescent(PL,EL) properties of these complexes in solutions and solid state were studied.In solutions,complexes of sodium and lanthanides exhibit double peaked ligand-centered PL of enol and keto forms of BQ with a quantum yield of 1%-8%.In the solid state the complexes of Sm,Eu,Ho,Nd,Er,and Yb along with the ligand-centered PL also exhibit a moderate-intensity metal-centered PL which is characteristic of the corresponding Ln^(3+) ions.Sc(BQ)_(3) complex shows bright green EL which has intensity comparable to the best results observed for scandium complexes with other organic ligands.Tatyana V.Balashova Svetlana K.Polyakova Vasily A.Ilichev Andrey A.Kukinov Roman V.Rumyantcev Georgy K.Fukin Ivan D.Grishin Artem N.Yablonskiy Alexander F.Shestakov Mikhail N.Bochkarev 2023Journal of Rare Earths2023,41,8:1
2Facile Synthesis of Amino Acid Decorated Water-Soluble Fullerene Derivatives with Anti-influenza Activity显示文摘Comprehensive Summary Herein,we present a facile synthesis of amide-type water-soluble fullerene derivatives decorated with five residues of amino acids.As compared to the previously developed approaches,the proposed method enables usage of a broad range of amino acids,including those unstable under Friedel-Crafts reaction conditions.Furthermore,it is fully tolerant to the nature of the sixth addend X in C60R5X precursor compounds and allows one to obtain fullerene derivatives with X=Cl,H,alkyl.The synthesized amide-type water-soluble fullerene derivatives demonstrated promising antiviral activities against rimantadine-resistant influenzaА/Puerto Rico/8/34(Н1N1)virus in vitro.Valeriya S.Bolshakova Ekaterina O.Sinegubova Yana L.Esaulkova Alexander S.Peregudov Ekaterina A.Khakina Nikita A.Slesarenko Alexander F.Shestakov Vladimir V.Zarubaev Pavel A.Troshin Olga A.Kraevaya 2023Chinese Journal of Chemistry2023,41,15:0
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