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Chlorinated Conjugated Polymer Based on Chlorine- and Cyano-substituted (E)-1,2-Di(thiophen-2-yl)ethane for Ambipolar and n-Type Organic Thin-film Transistors

查看全文 作  者:Yulong [1,2]Zhang;Chan [1,2]Zhang;Yunran [1,2]Su;Weijia [3]Dong;Yanru [1,2]Li;Zhongwei [1,2]Liu;Xiang [1,2]Yao;Yang [3]Han;Zhuping [1,2]Fei 高影响力作者 机构地区:[1]Institute of Molecular Plus,Department of Chemistry and Tianjin Key Laboratory of Molecular Optoelectronic Science,Tianjin University,Tianjin,300072 China;[2]Haihe Laboratory of Sustainable Chemical Transformations,Tianjin,300192 China;[3]School of Materials Science and Engineering,Tianjin University,Tianjin 300072,China高影响力机构 出  处:《Chinese Journal of Chemistry》索引2022年第40卷第16期,共7页高影响力期刊 基  金:the National Key Research and Development Program(No.2018YFA0703200);the National Natural Science Foundation of China(No.21975176)。 摘  要:Chlorinated conjugated polymers are rarely reported in ambipolar and n-type organic thin-film transistors(OTFTs),mainly due to the lack of chlorinated strong electron-deficient building blocks.Herein,we report three new chlorine(Cl)-and cyano(CN)-substituted(E)-1,2-di(thiophen-2-yl)ethane building blocks and their copolymers P2Cl1CNTVT-DPP,P4Cl1CNTVT-DPP and P2Cl2CNTVT-DPP. 关 键 词:Organic thin-film transistors Semiconductors CHLORINATION CROSS-COUPLING C-H activation
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