Recent progress of energy transfer and luminescence intensity boosting mechanism in Nd3+-sensitized upconversion nanoparticles

查看全文 作　　者：Solomon Tiruneh [1]Dibaba;Xiaoqian [2]Ge;Wei [1]Ren;Lining [2]Sun

机构地区：[1]Physics Department,and International Centre for Quantum and Molecular Structures,Shanghai University,Shanghai 200444,China;[2]Research Center of Nano Science and Technology,and School of Material Science and Engineering,Shanghai University,Shanghai 200444,China

出　　处：《Journal of Rare Earths》索引2019年第37卷第8期,共16页

基　　金：Projects supported by the National Natural Science Foundation of China(21571125,51872183,51672171);National Key R&D Program of China(2016YFE0114800) 摘　　要：Rare earth doped upconversion nanoparticles can be considered as the spice of research in the field of luminescence nanomaterials due to their unique optical properties such as near-infrared excitation.Enormous works have been reported about biomedical applications of 980 nm excited and Yb^3+-sensitized upconversion nanoparticles.However,980 nm excitation wavelength overlaps with the absorption band of water molecules in the biological environment,leading to overheating effect that can induce thermal damages of normal cells and tissues.Recently,Nd^3+-sensitized upconversion nanoparticles which can be excited with 808 nm has been widely investigated as alternative nanoparticles that can surmount this issue of overheating effect.Even though Nd^3+-sensitized upconversion nanoparticles can reduce the overheating effect by 20 fold as compared to Yb^3+-sensitized counterpart,there are several factors that reduce the upconversion luminescence intensity.In this review article,photon energy harvesting and transferring mechanisms in Nd^3+,Yb^3+and emitter ions co-doped upconversion nanoparticles under 808 nm excitation are briefly discussed.Factors that affect upconversion luminescence intensity and quantum yield of Nd^3+-sensitized upconversion nanoparticles are also addressed.Besides,some of the important strategies that have been recently utilized to boost upconversion luminescence intensity of Nd^3+sensitized upco nversion nanoparticles are tho roughly summarized.Lastly,the future challenges in the area and our perspectives are in sight. 关键词：Rare earth UPCONVERSION NANOPARTICLES Nd^3+-sensitized Energy transfer

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Recent progress of energy transfer and luminescence intensity boosting mechanism in Nd3+-sensitized upconversion nanoparticles

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