Determination of trace and rare-earth elements in Chinese soil and clay reference materials by ICP-MS

查看全文 作　　者：LIU [1]Ye;DIWU [1]Chunrong;ZHAO [1]Yan;LIU [1]Xiaoming;YUAN [1]Honglin;WANG [1]Jianqi

机构地区：[1]State Key Laboratory of Continental Dynamics,Department of Geology,Northwest University

出　　处：《Chinese Journal Of Geochemistry》索引2014年第33卷第1期,共8页

基　　金：supported by the National Natural Science Foundation of China (41272004);the MOST Special Funds from the State Key Laboratory of Continental Dynamics 摘　　要：Inductively coupled plasma mass spectrometry(ICP-MS) has become a powerful tool for providing reliable analytical results in many laboratories around the word. In this study, the mixture of HF and HNO3 acids in high-temperature and high-pressure closed-vessel digestion technique were used to decompose some Chinese reference materials, and thirty seven elements were determined by ICP-MS. Most of the results for Chinese soil reference materials were found to be in reasonable agreement with the reference values, except Cs, Ta, Li, Ge, Zn, Nd, Tb and Ta whose values need to be revised. Their precisions were typically lower than 5% RSD. However, the Precisions of Chinese clay reference materials, especially for GBW03102 and GBW03102a, were significantly different with reference values, probably reflecting the existence of a coarser-grained fraction(>70 μm) in samples, and the formation of fluorides in Al-rich samples during sample decomposition by using the mixture of HF and HNO3 acids. Moreover, thirty-seven trace elements covering the mass range from Li to U in four Chinese clay reference materials were firstly provided with good precision and accuracy in this study. 关键词：ICP-MS 中国土壤参考资料稀土元素粘土测定电感耦合等离子体质谱样品分解

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Determination of trace and rare-earth elements in Chinese soil and clay reference materials by ICP-MS

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引证文献(7)

耦合文献(847)

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