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Geochemical Characters of Water Coproduced with Coalbed Gas and Shallow Groundwater in Liulin Coalfield of China

查看全文 作  者:YANG [1]Mei;JU [2]Yiwen;LIU [3]Guijian;TONG [4,5]Li;KANG [3]Yu;HOU [2]Quanlin 高影响力作者 机构地区:[1]College of Resources and Environment, University of Chinese Academy Sciences;[2]Key Lab of Computational Geodynamics of Chinese Academy of Sciences, College of Earth Science, University of Chinese Academy Sciences;[3]School of Earth and Space Sciences, University of Science and Technology of China;[4]Research Center for Process Pollution Control, National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Institute of Process Engineering,Chinese Academy of Sciences;[5]University of Chinese Academy Sciences高影响力机构 出  处:《Acta Geologica Sinica(English Edition)》索引2013年第87卷第6期,共11页高影响力期刊 基  金:funded by the National Science and Technology Major Project (2011ZX05060-005; 2009ZX05039-003) 摘  要:To reveal the geochemical characters of water coproduced with coalbed gas and shallow groundwater,water samples were collected from 12 wells of coalbed methane and 7 wells of shallow groundwater.The pH,CODMn,fCO2,total dissolved solids(TDS),total hardness,and concentrations of metasilicic acid,sodium and kalium,calcium ion,magnesium ion,ammonium iron,bicarbonate ion,carbonate,chloride,sulfate ion,nitrate ion,fluoride,lithium,zinc,nickel,manganese,iron,boron,barium,etc.of the samples were measured.Research results showed the following:(1)Concentrations of TDS,chloride,fluoride,sodium and kalium,ammonium,iron,and barium in the water coproduced with coalbed gas exceeded the national standards of China;however,physical,chemical,and biological properties of shallow groundwater could meet the national standard.(2)The water produced from coalbed contained mainly Na–Cl·HCO3,with average TDS of 4588.5 ppm,whereas shallow groundwater contained a mixture of chemicals including Na·Mg·Ca-HCO3·SO4and Na·MgHCO3·SO4,with average TDS of 663.8 ppm.(3)In general,it was observed that bicarbonate and sodium accumulated in a reducing environment and deeper system,while depletion of hydrogen ions and dissolution of sulfate,calcium,and magnesium occurred in a redox environment and shallow system.(4)Sodium and kalium,ammonium,chloride,and bicarbonate ions were the main ions found in the study area. 关 键 词:浅层地下水 地球化学特征 煤层气 中国 高锰酸盐指数 碳酸氢根离子 氧化还原环境 总溶解固体
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