Study on adsorption behavior of cesium using ammonium tungstophosphate(AWP)-calcium alginate microcapsules

查看全文 作　　者：WU [1]Yan;MIMURA [2]Hitoshi;NIIBORI [2]Yuichi;OHNISHI [3]Takashi;KOYAMA [3]Shinichi;WEI [1]YueZhou

机构地区：[1]School of Nuclear Science and Engineering,Shanghai Jiao Tong University,Shanghai 200240,China;[2]Graduate School of Engineering,Tohoku University Aramaki-Aza-Aoba 6-6-01-2,Sendai,980-8579,Japan;[3]Japan Atomic Energy Agency,4002 Narita,O-arai-machi,Ibaraki,311-1393,Japan

出　　处：《Science China Chemistry》索引2012年第55卷第9期,共7页

摘　　要：A functional microcapsule was prepared by encapsulating the fine crystalline ammonium tungstophosphate(AWP) in calcium alginate polymer(CaALG).The characterization of AWP-CaALG microcapsule was examined by SEM and EPMA.The adsorption behavior of Cs(I),Rb(I),Sr(II),Pd(II),Ru(III),Rh(III),La(III),Ce(III),Dy(III) and Zr(IV) was investigated by the batch method.The batch experiments were carried out by varying the shaking times,HNO 3 concentration,and initial concentration of metal ions.Relatively large K d values above 10 5 cm 3 /g for Cs(I) were obtained in the range of 0.1-5 M HNO 3,resulting in a separation factor of Cs/Rb exceeding 10 2.In contrast,the K d values of Sr(II),Pd(II),Ru(III),La(III),Dy(III),Ce(III) and Zr(IV) were considerably lower than 50 cm 3 /g.The K d value of Cs(I) decreased in the order of the coexisting ions,H + > Na + >> NH 4 +,and a linear relationship with a slop of about 1 was obtained between log K d and log [NH 4 + ]([NH 4 + ] > 0.01 M).The adsorption of Cs(I) was found to be controlled by chemisorption mechanism,and followed a Langmuir-type adsorption equation.A high uptake percentage of 99.4% for Cs(I) was obtained by using the dissolved solutions of spent fuel from FBR-JOYO(JAEA). 关键词：吸附行为海藻酸钙微胶囊行为研究铯钨铵钯(Ⅱ)

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Study on adsorption behavior of cesium using ammonium tungstophosphate(AWP)-calcium alginate microcapsules

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