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Biodiesel preparation from transesterification of glycerol trioleate catalyzed by basic ionic liquids

查看全文 作  者:Shuai [1]Zhou;Lu [1]Liu;Bo [1]Wang;Feng [1]Xu;Run Cang [1,2]Sun 高影响力作者 机构地区:[1]Institute of Biomass Chemistry and Technology,College of Materials Science and Technology,Beijing Forestry University,Beijing 100083,China;[2]State Key Laboratory of Pulp and Paper Engineering,South China University of Technology,Guangzhou 510640,China高影响力机构 出  处:《Chinese Chemical Letters》索引2012年第23卷第4期,共4页高影响力期刊 基  金:Financial supports from the Fundamental Research Funds for the Central Universities (No.TD2010-1,YX2011-36,TD2011-11);the National Natural Science Foundation of China(No.31170556);Research Fund for the Doctoral Program of Higher Education of China(No.20100014120007);China Postdoctoral Science Foundation(No.20110490303);Beijing Forestry University Young Scientist Fund(No.BLX2009003);Major State Basic Research Development Program of China(973 Program,No.2010CB732204) 摘  要:In the present study,the transesterification of glycerol trioleate was carried out over a basic ionic liquid,1-butyl-3- methylimidazolium hydroxide([Bmim]OH) and an 87.2%yield of methyl ester was achieved.The product was isolated through simple decantation from the biphasic system due to the immiscibility of[BmimJOH with ester.[Bmim]OH can be easily recovered and reused six times without dramatic decrease in ester yield. 关 键 词:酯交换反应 离子液体 油酸酯 生物柴油 甘油 制备 催化 碱性
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