Oxidation and detection of L-cysteine using a modified Au/Nafion/glass carbon electrode

查看全文 作　　者：WANG XueJi ZHANG LiLi MIAO LiXiao KAN MeiXiu KONG LinLin ZHANG [1]HuiMin

机构地区：[1]School of Science, Beijing Institute of Technology, Beijing 100081, China

出　　处：《Science China Chemistry》索引2011年第54卷第3期,共5页

基　　金：supported by the National Natural Science Foundation of China(20875008) 摘　　要：In this work,the electrochemical oxidation of L-cysteine(CySH)was investigated on a composite film modified electrode with Au nanoparticles dispersed in the fluorocarbon polymer(Nafion).The excellent electrocatalytic effect on CySH oxidation was attributed to the role of Au nanoparticles.The voltammetric studies revealed two anodic peaks for the oxidation of CySH in the pH range of 2.0–8.0.The electrode was used to detect cysteine at pH 2.0 and pH 7.0.At pH 2.0,a determination range of 3.0–50.0?mol/L was obtained with the detection sensitivity of 22.7A/(mmol L1),while at pH 7.0,a determination range of 2.0–80.0mol/L was obtained with the detection sensitivity of 4.08A/(mmol L1).The detection limits were estimated to be as low as 1.0?mol/L at both pH 7.0 and pH 2.0.Additionally,at pH 7.0,the interferences of ascorbic acid and uric acid were reduced for the detection of cysteine.These made the Au/Nafion/GC electrode a promising candidate for efficient electrochemical sensors for the detection of CySH. 关键词：NAFION膜金纳米粒子电化学氧化半胱氨酸玻碳电极检测限改良 AU纳米粒子

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Oxidation and detection of L-cysteine using a modified Au/Nafion/glass carbon electrode

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