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| 1 | A comparative study of Mn/CeO_2,Mn/ZrO_2 and Mn/Ce-ZrO_2 for low temperature selective catalytic reduction of NO with NH_3 in the presence of SO_2 and H_2O显示文摘Ce-ZrO2 is a widely used three-way catalyst support.Because of the large surface area and excellent redox quality,Ce-ZrO2 may have potential application in selective catalytic reduction(SCR) systems.In the present work,Ce-ZrO2 was introduced into a low-temperature SCR system and CeO2 and ZrO2 supports were also introduced to make a contrastive study.Mn/CeO2,Mn/ZrO2 and Mn/Ce-ZrO2 were prepared by impregnating these supports with Mn(NO3)2 solution,and have been characterized by N2-BET,XRD,TPR,TPD,XPS,FT-IR and TG.The activity and resistance to SO2 and H2O of the catalysts were investigated.Mn/Ce-ZrO2 and Mn/CeO2 were proved to have better low-temperature activities than Mn/ZrO2,and yielded 98.6% and 96.8% NO conversion at 180°C,respectively.This is mainly because Mn/Ce-ZrO2 and Mn/CeO2 had higher dispersion of manganese oxides,better redox properties and more weakly adsorbed oxygen species than Mn/ZrO2.In addition,Mn/Ce-ZrO2 showed a good resistance to SO2 and H2O and presented 87.1% NO conversion,even under SO2 and H2O treatment for 6 hours,and the activity of Mn/Ce-ZrO2 was almost restored to its original level after cutting off the injection of SO2 and H2O.This was due to the weak water absorption and weak sulfation process on the surface of the catalyst. | Boxiong Shen Xiaopeng Zhang Hongqing Ma Yan Yao Ting Liu | 2013 | Journal of Environmental Sciences2013，25，4： | 30 |
| 2 | 茶园——土壤系统的物质循环对土壤酸化的影响显示文摘基于植茶后土壤酸度逐渐增高,盐基含量降低,铝饱和度增加,土壤呈现酸化现象。本文通过茶园—土壤系统中铝、锰、钙、镁等矿质元素循环,探讨了茶园土壤酸化的原因。在江苏省金坛县茅麓茶场的黄棕壤上,对不同植茶年限(9龄、29龄、80龄)茶园的茶树茎流、透冠水和土壤渗漏水的化学成分进行了分析研究。茶树是富集铝和锰的植物,茶树茎流与透冠水相比,具有含铝多、含盐基少、pH 值较低的特点。茶园土壤酸化受茶树群体分布的影响而存在着不均一性,植茶初期离茶树根颈近的土壤率先酸化,随着植茶年限的延长和茶树群体覆盖度的增加,茶树落叶对土壤酸化起主导作用,导致离根颈远的土壤 pH 值更低。茶园土壤的整体酸化是与茶园生态系统中物质的生物循环有关,随着植茶年限增长,土壤中的钙、镁淋溶增多,土壤酸化加强,土壤铝、锰的淋溶也随土壤酸化程度的增加而增强,其中锰的淋溶尤为明显。但由于茶园土壤中铝的溶出量比钙、镁少得多,各层土壤的铝饱和度随植茶年限的增加而升高,使茶园土壤具有聚积铝的倾向,这就是茶园土壤酸化的基本原因。 | 宋木兰 刘友林 | 1990 | 茶叶科学1990，10，2： | 20 |
| 3 | EFFECT OF CHEMICAL COMPOSITION ON RETAINED AUSTENITE IN TRIP STEEL显示文摘The systematic chemical compositions including common C, Si, Mn, Al, and micro- alloying elements of Ti and Nb were designed for high volume fraction of retained austenite as much as possible. The thermo-cycle experiments were conducted by using Gleeble 2000 thermo-dynamic test machine for finding the appropriate composition. The experimental results showed that chemical composition had a significant effect on retained austenite, and the appropriate compositions were determined for commercial production of TRIP steels. | Y. Chen and X. ChenWuhan University of Science and Technology, Wuhan 430081, ChinaQ.F. Wang, G.L. Yuan and. C. Y. LiTechnical Center of Wuhan Iron and Steel Co., Wuhan 430080, ChinaX. Y. Li and Y.X. WangCentral Iron and Steel Research Institute, Beijing 1 | 2002 | Acta Metallurgica Sinica(English Letters)2002，15，4： | 19 |
| 4 | Effect of manganese oxide-modified biochar addition on methane production and heavy metal speciation during the anaerobic digestion of sewage sludge显示文摘Low organic matter content and high heavy metal levels severely inhibit the anaerobic digestion(AD) of sewage sludge. In this study, the effect of added manganese oxidemodified biochar composite(MBC) on methane production and heavy metal fractionation during sewage sludge AD was examined. The MBC could increase the buffering capacity,enhance the methane production and degradation of intermediate acids, buffer the pH of the culture, and stabilize the sewage sludge AD process. The application of MBC positively impacted methane production and the cumulative methane yield increased up to 121.97%,as compared with the control. The MBC addition can improve metal stabilization in the digestate. An optimum MBC dose of 2.36 g was recommended, which would produce up to 121.1 L/kg volatile solids of methane. After the AD process, even though most of the metals accumulated in the residual solids, they could be transformation from the bio-available fractions to a more stable fraction. The total organic-and sulfide-bound and residual fraction content at a 3 g dose of MBC that is 0.12 g/g dry matter were 51.06% and 35.11% higher than the control, respectively. The results indicated that the application of MBC could improve the performance of AD and promote stabilization of heavy metals in sewage sludge post the AD process. | Jianhua Li Min Zhang Zhiyin Ye Changming Yang | 2019 | Journal of Environmental Sciences2019，31，2： | 17 |
| 5 | THE APPLICATION OF THE LAW OF MASS ACTION IN COMBINATION WITH THE COEXISTENCE THEORY OF SLAG STRUCTURE TO THE MULTICOMPONENT SLAG SYSTEMS显示文摘It is shown by the the law of mass action in combination with the coexistence theory of slag structure that KMn n =NMno /(NFeo [%Mn] does not change with basicities and maintains constant at constant temperature; the oxidizing capabilities of multicomponent slag systems containing CaO, MgO etc., can be expressed by NFe tO =NFeO + 6NFe2 O3 + 8NFe3O4; the desulfurizing capabilities of various basic oxides for multicomponent slag systems can be calculated by Ls=8(KCaSNCaO+KMgsNMgo +KFeSNFeO)∑n/[%O]; the dephosphorizing capabili- ties of CaO-MgO-FeO-FeO O3-P2 O5 as well as CaO-FeO-Fe2 O3-A12 O3-P2 O5 molten slags expressed respectively by Lpo=(%P2O5)/[P]2 = 141.94[%O]5∑nK00(1 + K5N2Cao + K6N3CaO + K7N4CaO + K8N2MgO + K9N3MgO + K10N3FeO + K11N4Feo); LPO=(%P2O5)/[P]2= 141.94[%O]5∑nK00(1 + K10N2CaO+ K11N3CaO+ K12N4CaO + K13N3FeO + K14N4FeO) have good agreement with practical values. | J. Zhang (Metallurgical Engineering School, University of Science and Technology Beijing, Beijing 100083, China) | 2001 | Acta Metallurgica Sinica(English Letters)2001，14，3： | 14 |
| 6 | Integrated removal of NO and mercury from coal combustion flue gas using manganese oxides supported on TiO_2显示文摘A catalyst composed of manganese oxides supported on titania(MnO_x/TiO_2) synthesized by a sol–gel method was selected to remove nitric oxide and mercury jointly at a relatively low temperature in simulated flue gas from coal-fired power plants. The physico-chemical characteristics of catalysts were investigated by X-ray fluorescence(XRF), X-ray diffraction(XRD), and X-ray photoelectron spectroscopy(XPS) analyses, etc. The effects of Mn loading,reaction temperature and individual flue gas components on denitration and Hg^0 removal were examined. The results indicated that the optimal Mn/Ti molar ratio was 0.8 and the best working temperature was 240°C for NO conversion. O_2 and a proper ratio of [NH_3]/[NO]are essential for the denitration reaction. Both NO conversion and Hg^0 removal efficiency could reach more than 80% when NO and Hg^0 were removed simultaneously using Mn0.8 Tiat 240°C.Hg^0 removal efficiency slightly declined as the Mn content increased in the catalysts. The reaction temperature had no significant effect on Hg^0 removal efficiency. O_2 and HCl had a promotional effect on Hg^0 removal. SO2 and NH_3were observed to weaken Hg^0 removal because of competitive adsorption. NO first facilitated Hg^0 removal and then had an inhibiting effect as NO concentration increased without O_2, and it exhibited weak inhibition of Hg^0 removal efficiency in the presence of O_2. The oxidation of Hg^0 on Mn O x/TiO_2 follows the Mars–Maessen and Langmuir–Hinshelwood mechanisms. | Shibo Zhang Yongchun Zhao Zonghua Wang Junying Zhang Lulu Wang Chuguang Zheng | 2017 | Journal of Environmental Sciences2017，29，3： | 11 |
| 7 | Effects of Root Penetration Restriction on Growth and Mn Nutrition of Different Winter Wheat Genotypes in Paddy Soils显示文摘 | LU Shi-hua, ZENG Xiang-zhong, LIU Xue-jun and ZHANG Fu-suo( Soil and Fertilizer Institute , Sichuan Academy of Agricultural Sciences , Chengdu 610066 , P.R.China Departmentof Plant Nutrition , Key Laboratory of Plant Nutrition , Ministry of Agriculture , Key Laboratory of Plant-SoilInteractions, Ministry of Education , China Agricultural University, Beijing 100094 , P.R.China) | 2002 | Agricultural Sciences in China2002，1，6： | 11 |
| 8 | Effects of uniconazole with or without micronutrient on the lignin biosynthesis,lodging resistance,and winter wheat production in semiarid regions显示文摘Lodging stress results in grain yield and quality reduction in wheat. Uniconazole, a potential plant growth regulator significantly enhances lignin biosynthesis and thus provides mechanical strength to plants in order to cope with lodging stress. A field study was conducted during the 2015–2016 and 2016–2017 growing seasons, to investigate the effects of uniconazole sole application or with micronutrient on the lignin biosynthesis, lodging resistance, and production of winter wheat. In the first experiment, uniconazole at concentrations of 0(CK), 15(US1), 30(US2), and 45(US3) mg L^-1 was applied as sole seed soaking, while in the second experiment with manganese(Mn) at concentration of 0.06 g L^-1 Mn, 0.06 g L^-1 Mn+ 15 mg L^-1 uniconazole(UMS1), 0.06 g L^-1 Mn+30 mg L^-1 uniconazole(UMS2), and 0.06 g L^-1 Mn+45 mg L^-1 uniconazole(UMS3), respectively. Uniconazole sole application or with micronutrient significantly increased the lignin content by improving the lignin-related enzyme activities of phenylalanine ammonia-lyase, cinnamyl alcohol dehydrogenase, tyrosine ammonialyase, and peroxidase, ameliorating basal internode characteristics, and breaking strength. The spike length, spike diameter, spikes/plant, weight/spike, yield/spike, and grain yield increased and then decreased with uniconazole application at a higher concentration, where their maximum values were recorded with UMS2 and US2 treatments. The lignin accumulation was positively correlated with lignin-related enzyme activities and breaking strength while, negatively correlated with lodging rate. Uniconazole significantly improved the lignin biosynthesis, lodging resistance, and grain yield of winter wheat and the treatments which showed the greatest effects were uniconazole seed soaking with micronutrient at a concentration of 30 mg L^-1 and 0.06 g L^-1 , and uniconazole sole seed soaking at a concentration of 30 mg L^-1 . | Irshad AHMAD MENG Xiang-ping Muhammad KAMRAN Shahzad ALI Shakeel AHMAD LIU Tie-ning CAI Tie HAN Qing-fang | 2020 | Journal of Integrative Agriculture2020，19，1： | 8 |
| 9 | Discovery of low-mature hydrocarbon in manganese nodules and ooze from the Central Pacific deep sea floor显示文摘Extracts from manganese nodules and ooze from the Central Pacific deep sea floor were analyzed using the chromatogram-mass spectrum, and it was found that most of the biomarker molecules are of the low-mature type (some have characteristics of mature): the ratio of 'A'/C is high between 11.4%-19.75%; CPI is 1.22-1.23; C31-22S/ (22S+22R) hopane is 0.59-0.60, Tm/Ts is 0.99-1.99; pa moretane/(αβ+βα) hopane is 0.12-0.14; C29 sterane 20S/(20S+20R) is 0.35-0.41; ββ/(ββ+αα) is 0.38-0.45; arene TA(I)/TA(I+Ⅱ) is 0.16-0.21; methyl-phenanthrene index (MPI1) is 0.35-0.67. According to the geological settings of the sampling area and its organic geochemical characteristics, it is considered that the hydrothermal activities on the ocean floor facilitate the decomposition of organic matter in the sediment, which leads to the generation and migration of hydrocarbon into manganese nodules and ooze. This discovery is important for understanding the mechanisms of hydrocarbon generation in the ocean floor and | HU Wenxuan JIN Zhijun YAO Suping LU Xiancai CHEN Zhilin ZHANG Linye ZHANG Xuejun ZHOU Huaiyang | 2002 | Chinese Science Bulletin2002，47，11： | 7 |
| 10 | Effects of manganous sulphate on root growth,cell division,and nucleoli of Allium cepa显示文摘The effects of different concentrations of manganous sulphate on root growth,cell division, chromosome and nucleus morphplogy and nucleoli in root tip-cells of Allium cepa L. were studied. The concentrations of manganous sulphate used were 10-7,10-6,10-5 ,10-4,10-3, 10-2 and 10-1mol/L. The results indicated that manganese had a stimulatory effect on the root growth at lower concentrations (10-7 to 10-4mol/L). With increasing the concentration of Mn (10-3 to 10-1mol/L) and duration of treatment,manganese inhibited root growth and cell division, and had toxic effects on chromosomes,nuclei and nucleoli. Manganese Could induce mitotic irregularities,comprising c-mitosis,anaphase bridges and chromosome stickiness. The nuclei became irregular in shape and many micronuclei were scattered in the cytoplasm. Some similar silver-stained particulate materials were found scattered in the nucleus in root tip cells. The possible mechanism behind these phenomena is also briefly discussed. | 刘东华 蒋悟生 王威 翟林 | 1994 | 华北农学报1994，9，S2： | 6 |
| 11 | A new recombinant MS-superoxide dismutase alleviates 5-fluorouracil-induced intestinal mucositis in mice显示文摘Intestinal mucositis is a common side effect of anticancer regimens that exerts a negative impact on chemotherapy.Superoxide dismutase(SOD)is a potential therapy for mucositis but efficient product is not available because the enzyme is degraded following oral administration or induces an immune reaction after intravascular infusion.Multi-modified Stable Anti-Oxidant Enzymes?(MS-AOE?)is a new recombinant SOD with better resistance to pepsin and trypsin.We referred it as MS-SOD to distinguish from other SODs.In this study we investigated its potential to alleviate 5-FU-induced intestinal injury and the mechanisms.An intestinal mucositis model was established in C57/BL6 mice by 5-day administration of 5-FU(50 mg/kg every day,ip).MS-SOD(800 IU/10 g,ig)was given once daily for 9 days.5-FU caused severe mucositis with intestinal morphological damage,bodyweight loss and diarrhea;MS-SOD significantly decreased the severity.5-FU markedly increased reactive oxygen species(ROS)and inflammatory cytokines in the intestine which were ameliorated by MS-SOD.Furthermore,MS-SOD modified intestinal microbes,particularly reduced Verrucomicrobia,compared with the 5-FU group.In Caco2 cells,MS-SOD(250–1000 U/mL)dose-dependently decreased tBHP-induced ROS generation.In RAW264.7 cells,MS-SOD(500 U/mL)had no effect on LPS-induced inflammatory cytokines,but inhibited iNOS expression.These results demonstrate that MS-SOD can scavenge ROS at the initial stage of injury,thus play an indirect role in anti-inflammatory and barrier protein protection.In conclusion,MS-SOD attenuates 5-FU-induced intestinal mucositis by suppressing oxidative stress and inflammation,and influencing microbes.MS-SOD may exert beneficial effect in prevention of intestinal mucositis during chemotherapy in clinic. | Xiao-xia Yan Hai-long Li Yi-ting Zhang Shou-yan Wu Heng-lei Lu Xiao-lu Yu Fan-guo Meng Jian-hua Sun Li-kun Gong | 2020 | Acta Pharmacologica Sinica2020，41，3： | 6 |
| 12 | The simultaneous removal of ammonium and manganese from surface water by MeO_x:Side effect of ammonium presence on manganese removal显示文摘Manganese and ammonium pollution in surface water sources has become a serious issue.In this study, a pilot-scale filtration system was used to investigate the effect of ammonium on manganese removal during the simultaneous removal of ammonium and manganese from surface water using a manganese co-oxide filter film(MeO_x ). The results showed that the manganese removal efficiency of MeO_x in the absence of ammonium was high and stable, and the removal efficiency could reach 70% even at 5.5 °C. When the influent ammonium concentration was lower than 0.7 mg/L, ammonium and manganese could be removed simultaneously. However, at an ammonium concentration of 1.5 mg/L, the manganese removal efficiency of the filter gradually decreased with time(from 96% to 46.20%). Nevertheless, there was no impact of manganese on ammonium removal. The mechanism by which ammonium negatively affected manganese removal was investigated, demonstrating that ammonium affected manganese removal mainly through two possible mechanisms. On one hand, the decreased p H caused by ammonium oxidation was unfavorable for the oxidation of manganese by MeO_x ; on the other hand, the presence of ammonium slowed the growth of new MeO_x and retarded the increase in the specific surface area of the Me Ox-coated sand, and induced changes in the morphology and crystal structure of Me Ox. Consequently, the manganese removal efficiency of the filter decreased when ammonium was present in the inlet water. | Xuan Tian Ruifeng Zhang Tinglin Huang Gang Wen | 2019 | Journal of Environmental Sciences2019，31，3： | 6 |
| 13 | Binding of transition metals to S100 proteins显示文摘The S100 proteins are a unique class of EF-hand Ca^(2+) binding proteins distributed in a cell-specific, tissue-specific, and cell cycle-specific manner in humans and other vertebrates. These proteins are distinguished by their distinctive homodimeric structure, both intracellular and extracellular functions, and the ability to bind transition metals at the dimer interface. Here we summarize current knowledge of S100 protein binding of Zn^(2+), Cu^(2+) and Mn^(2+) ions, focusing on binding affinities, conformational changes that arise from metal binding, and the roles of transition metal binding in S100 protein function. | Benjamin A.Gilston Eric P.Skaar Walter J.Chazin | 2016 | Science China(Life Sciences)2016，59，8： | 6 |
| 14 | Spinel Phases LiRE_xMn_(2-x)O_4(RE=Nd, Ce) as Cathode for Rechargeable Lithium Batteries显示文摘Several series of LiRE x Mn 2-x O 4(RE=Ce, Nd) samples prepared at different contents and in different rare earth metals substitution were studied in order to further understand the dependence of the electrochemical performance on the doping rare earth metals. These cathodes were more tolerant to repeat lithium extraction and insertion than a standard LiMn 2O 4 spinel electrode in spite of a small reduction in the initial capacity. X ray photoelectron spectroscopy results show that the Mn 4+ contents for spinel LiMn 2O 4 directly affected the initial capacity and cyclability of LiMn 2O 4. | 彭正顺 江泱 金增媛 | 2000 | Journal of Rare Earths2000，18，2： | 5 |
| 15 | Synthesis and Electrochemical Studies on Spinel Phase LiMn_2O_4 Cathode Materials Prepared by Different Processes显示文摘1IntroductionIthasbeendemonstratedthatspinelstructurelithiummanganeseoxideisthemostpromisingcathodefor“lithiumion”bateriesbe... | 彭正顺 | 1999 | Rare Metals1999，18，2： | 5 |
| 16 | Growth mechanisms and environmental implications of carbonate concretions from the ~ 1.4Ga Xiamaling Formation, North China显示文摘Carbonate concretions provide unique records of ancient biogeochemical processes in marine sediments, and have the potential to reflect seawater chemistry indirectly. In fine-siliciclastic settings, they preferentially form in organicrich mudstones, owing to a significant fraction of the bicarbonate required for carbonate precipitation resulted from the decomposition of organic matter in sediments. In the Member IV of the Xiamaling Formation(ca. 1.40–1.35 Ga), North China, however, carbonate concretions occur in organic-poor green silty shales(avg. TOC = ~ 0.1 wt%).In order to elucidate the mechanism of the concretion formation and their environmental implications, a thorough study on the petrographic and geochemical compositions of the concretions and their host rocks was conducted.Macro-to microscopic fabrics, including deformed shale laminae surrounding the concretions, 'cardhouse'structures of clay minerals and calcite geodes in the concretions, indicate that these concretions are of early diagenetic origin prior to the significant compaction of clay minerals. The carbon isotope compositions of the concretions(-1.7‰ to + 1.5‰) are stable and close to or slightly lower than that of the contemporaneous seawater, indicating that the bicarbonates required for the concretion formation were mainly sourced from seawater by diffusion rather than produced by methanogenesis or anoxic oxidation of methane(AOM); the rare occurrence of authigenic pyrite grains in the concretions likely indicates that bacterial sulfate reduction(BSR) did not play a significant role in their formation either. Almost all the calcite in the concretions has low Mn–Fe in nuclei but high Mn–Fe in rims with average Mn/Fe ratio close to 3.3. The calcite shows positive Ce anomalies(avg. 1.43)and low Y/Ho ratios(avg. 31). This evidence suggests that Mn reduction is the dominant process responsible for the formation of calcite rims while nitrate reduction probably triggered the precipitation of calcite nuclei.Prominence of Mn reduction in the porewater likely indicates that there was sufficient oxygen to support active Mn-redox cycling in the overlying seawater. | An-Qi Liu Dong-Jie Tang Xiao-Ying Shi Li-Min Zhou Xi-Qiang Zhou Mo-Han Shang Yang Li Hu-Yue Song | 2019 | Journal of Palaeogeography2019，8，3： | 5 |
| 17 | Effect of rare earth and alloying elements on the thermal conductivity of austenitic medium manganese steel显示文摘The influence of different contents of Cr, Mo, and rare earth element(RE) additives on the thermal conductivity of austenitic medium manganese steel was studied and discussed. The results show that the addition of Cr in medium manganese steel can improved the ordering of C–Mn atomic clusters, so as to improve the steel's thermal conductivity. However, Cr will lead to precipitation of a great deal of carbides in medium manganese steel when its content is greater than 4wt%. These carbides would aggregate around the grain boundary, and as a result, the thermal conductivity is decreased. By the addition of Mo whose content is about 2wt%, spherical carbides will be formed, thus improving the thermal conductivity of the medium manganese steel. The interaction between rare earth elements and alloying elements will raise both the thermal conductivity and the wear-resisting property of medium manganese steel. | Shao-chun Chen Hong-xiang Ye Xin-qiang Lin | 2017 | International Journal of Minerals,Metallurgy and Materials2017，24，6： | 5 |
| 18 | Facile synthesis of Ag-modified manganese oxide for effective catalytic ozone decomposition显示文摘O3 decomposition catalysts with excellent performance still need to be developed. In this study, Ag-modified manganese oxides(AgMnOx) were synthesized by a simple co-precipitation method. The effect of calcination temperature on the activity of MnOx and AgMnOxcatalysts was investigated. The effect of the amount of Ag addition on the activity and structure of the catalysts was further studied by activity testing and characterization by a variety of techniques. The activity of 8%AgMnOxfor ozone decomposition was significantly enhanced due to the formation of the Ag1.8 Mn8 O16 structure, indicating that this phase has excellent performance for ozone decomposition.The weight content of Ag1.8 Mn8 O16 in the 8%AgMnOxcatalyst was only about 33.76%, which further indicates the excellent performance of the Ag1.8 Mn8 O16 phase for ozone decomposition. The H2 temperature programmed reduction(H2-TPR) results indicated that the reducibility of the catalysts increased due to the formation of the Ag1.8 Mn8 O16 structure.This study provides guidance for a follow-up study on Ag-modified manganese oxide catalysts for ozone decomposition. | Xiaotong Li Jinzhu Ma Changbin Zhang Runduo Zhang Hong He | 2019 | Journal of Environmental Sciences2019，31，6： | 5 |
| 19 | Dendritic BiVO4 decorated with MnOx co-catalyst as an efficient hierarchical catalyst for photocatalytic ozonation显示文摘An appropriate co-catalyst can significantly promote the photocatalytic efficacy, but this has been seldom studied in the visible-light photocatalysis combined with ozone, namely photocatalytic ozonation. In this work, a dendritic bismuth vanadium tetraoxide (BiVO4) material composited with highly dispersed MnOv nanoparticles was synthesized, and its catalytic activity is 86.6% higher than bare BiVO4 in a visible light and ozone combined process. Catalytic ozonation experiments, ultraviolet- visible (UV-Vis) diffuse reflectance spectra and photoluminescence spectra jointly indicate that MnOA plays a triple role in this process. MnOv strengthens the light adsorption and promotes the charge separation on the composite material, and it also shows good activity in catalytic ozonation. The key reactive species in this process is OH, and various pathways for its generation in this process is proposed. This work provides a new direction of catalyst preparation and pushes forward the application of photocatalytic ozonation in water treatment. | Jin Yang Xuelian Liu Hongbin Cao Yanchun Shi Yongbing Xie Jiadong Xiao | 2019 | Frontiers of Chemical Science and Engineering2019，13，1： | 5 |
| 20 | Lanthanum-doped Cu-Mn composite oxide catalysts for catalytic oxidation of toluene显示文摘CuMn mixed oxides catalysts doped with La were prepared following a co-precipitation method and used for the catalytic oxidation of toluene. Catalysts properties of the catalysts were investigated by X-ray diffraction, N_2 adsorption/desorption,scanning electron microscopy, H_2-temperature-programmed reduction(H_2-TPR), O_2-temperature-programmed desorption(O_2-TPD) and X-ray photoelectron spectroscopy techniques. Characterization data reveal that the phase change and decrease in crystallinity of the La-doped catalysts increase the number of oxygen vacancies. Improvements in reducibility and an increase in the amount of chemisorbed oxygen of the La-doped catalysts were also verified by H_2-TPR and O_2-TPD. The activity of the CuMn mixed oxides catalysts is significantly improved by the addition of a nominal amount of La. The CuMn/La-4 mol% catalyst exhibits the best catalytic activity, with a 90%conversion temperature of 255 ℃,attributed to a high Mn^(3+)ratio, superficial chemisorbed oxygen,and high surface area. This study indicates La to be a promising dopant for Cu-Mn catalysts toward toluene oxidation. | Jing Pan Wentao Du Yongjun Liu Yan Cheng Shandong Yuan | 2019 | Journal of Rare Earths2019，37，6： | 5 |
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