| 1 | Oxygen Atom Exchange Mechanism in Reaction of OH Radical with AsO显示文摘Oxygen atom exchange reaction mechanism in the reaction of OH radicals with AsO was investigated by means of the density functional theory (DFT) with 6 311++G( 3df,3pd ) and 6 311++G( d,p ) basis sets. The calculated results suggest that the reaction between OH and AsO should make the oxygen atoms exchange rapidly because the barrier to isomerization is significantly less than the HO-AsO bond dissociation energy. | CHI Yu-juan 1, YU Hai tao 1,2** , FU Hong gang 1,2 HUANG Xu ri 2, LI Ze sheng 2 and SUN Chia chung 21. College of Chemistry and Chemical Engineering, Heilongjiang University, Harbin 150080, P. R. China 2. State Key Laboratory of T | 2002 | Chemical Research in Chinese Universities2002，18，3： | 3 |
| 3 | A numerical method for spherical particle motion in turbulent flow with large Reynolds number显示文摘A new mathematical model, fluctuation spectrum random trajectory model (FSRTM) for the particle motion in environmental fluid was developed using Lagrangian method, in which the time mean velocity of the fluid was calculated by a time mean velocity formula for two dimensional homogeneous shear turbulent flows in open channel, the velocity fluctuation of the fluid was determined by Fourier expansion and fluctuation spectrum, and the particle motion equation was solved using Ronge Kutta method. For comparison, the spherical cation exchange resins with a density of 1 44 g/cm\+3 and diameters ranging from 0 50—0 60 mm, 0 60—0 70 mm and 0 80—0 90 mm were selected as the experimental solid particles, and their moving velocities and trajectories in shear turbulent flows with the flow Reynolds number of 4710, 10240, 11900 and 20760 were investigated. The comparing analyses of the modeled results with the measured results have shown that the model developed in this paper can describe the motions of the particles in shear turbulent flow. | ZHANG Yong\|ze\+1, LI Jia\+2, LI Ke feng\+2, WANG Xuan\+3 (1. Chinese Research Academy of Environmental Sciences, Beijing 100012, China 2. Sichuan University, Chengdu 610065, China 3. Beijing Normal University, Beijing 100875, China) | 1999 | Journal of Environmental Sciences1999，11，4： | 0 |
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