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| 1 | Low-cost high entropy alloy(HEA)for high-efficiency oxygen evolution reaction(OER)显示文摘Oxygen evolution reaction(OER)is the key step involved both in water splitting devices and rechargeable metal-air batteries,and hence,there is an urgent need for a stable and low-cost material for efficient OER.In the present investigation,Co-Fe-Ga-NiZn(CFGNZ)high entropy alloy(HEA)has been utilized as a low-cost electrocatalyst for OER.Herein,after cyclic voltammetry activation,CFGNZ-nanoparticles(NPs)are covered with oxidized surface and form high entropy(oxy)hydroxides(HEOs),exhibiting a low overpotential of 370 mV to achieve a current density of 10 mA/cm^(2)with a small Tafel slope of 71 mV/dec.CFGNZ alloy has higher electrochemical stability in comparison to state-of-the art RuO2 electrocatalyst as no degradation has been observed up to 10 h of chronoamperometry.Transmission electron microscopy(TEM)studies after 10 h of long-term chronoamperometry test showed no change in the crystal structure,which confirmed the high stability of CFGNZ.The density functional theory(DFT)based calculations show that the closeness of d(p)-band centers to the Fermi level(EF)plays a major role in determining active sites.This work highlights the tremendous potential of CFGNZ HEA for OER,which is the primary reaction involved in water splitting. | Lalita Sharma Nirmal Kumar Katiyar Arko Parui Rakesh Das Ritesh Kumar Chandra Sekhar Tiwary Abhisek K.Singh Aditi Halder Krishanu Biswas | 2022 | Nano Research2022,15,6: | 5 |
| 2 | Elevated serum values of procollagen Ⅲ peptide (PIIIP)in patients with ulcerative colitis who will develop pseudopolyps显示文摘AIM: To assess the impact of procollagen Ⅲ peptide as a marker of collagenesis in the development of pseudopolyps in patients with ulcerative colitis.METHODS: Development of pseudopolyps was monitored in 25 patients with ulcerative colitis classified according to Powell-Tuck index as mild (n=12) or moderate (n=13) form of disease. Patients with a mild form of disease were treated with oral mesalazine medication (2-4 g/day) and local mesalazine preparation (suppository). Patients with a moderate form of disease received oral mesalazine medication (2-4 g/day), local mesalazine preparation(suppository) and local methylprednisolone at an initial dose of 60 rag/day, followed by dose tapering. How many significant variables (previously determined by analysis of variance) were elevated in the groups with and without pseudopolyp developement was observed. ROC analysis for calculation of new index was made.RESULTS: Serum values of procollagen Ⅲ peptide (PⅢP), C-reactive protein (CRP) and C4 complement component (C4)were statistically significantly lower in the group of patients flee from pseudopolyp development bhan bhose who developed one or more pseudopolyps (0.45±0.12 vs 1.42±0.70,P<0.0027; 7.6±4.7 vs 17.8±9.17, P<0.035, and 0.46±0.11 vs 0.34±0.16, P<0.068, respectively) at endoscopic conrtrols with patohistologically samples during 13 months. There were no statistically significant differences in the values of C3, ceruloplasmin and IgM between the two groups (P>0.05).Discrimination function analysis yielded highest standardized cannon coefficients for PⅢP (0.876), CRP (0.104), C3 (-0.534) and C4 (0.184) (P<0.036). The elevation in two of three laboratory variables (PⅢP, CRP and C4) reached sensitivity of 93 % and specificity of 90 % in the development of pseudopolyps.CONCLUSION: It is proposed that an increase in two of the three laboratory parameters (PⅢP, CRP and C4) could improve the accuracy of prediction of the development of pseudopolyps. When using PⅢP, CRP and C4 on decision making, the positive predictive value and accuracy were 90 % and 92 %, respectively. | ■arko Babi Vjekoslav Jagi Zvonko Petrovi Ante Bili KapetanoviDinko Goranka Kubat Rosana Troskot Mira Vukeli | 2003 | World Journal of Gastroenterology2003,9,3: | 2 |
| 3 | Elevation of matrix metalloprotei-nases 3 and 9 in cerebrospinal fluid and blood in patients with severetraumatic brain injury显示文摘 | Grosstete M Phelps J Arko L | 2009 | Neurosurgery2009,65,4: | 1 |
| 4 | What is the signifi- cance of endoleaks and endotension显示文摘 | Heikkinen MA Arko FR Zarins CK | 2004 | Surg Clin North Am2004,84,5: | 1 |
| 5 | Surgical management of mesenteric ischemia 显示文摘 | Karwowski J Arko F | 2004 | Techniques in Vascular and Interventional Radiology2004,7,3: | 1 |
| 6 | Early and late functional outcome assessments following endovascular and open aneurysm repair显示文摘 | Arko FR Hill BB Reeves TR | 2003 | J Endovasc Ther2003,10,: | 1 |
| 7 | Intrasac flow velocities predict sealing of type II endoleaks after endovascular abdominal aortic aneurysm repair 显示文摘 | Arko FR Filis KA Siedel SA | 2003 | J Vasc Surg2003,37,1: | 1 |
| 8 | Intravascular ultrasound scanning improves long-term patency of iliac lesions treated with balloon angioplasty and primary stenting显示文摘 | Buckley CJ Arko FR Lee S | 2002 | J Vase Surg2002,35,2: | 1 |
| 9 | Explant analysis ofAneuRx stent grafts : relationship between structural findings andclinical outcome 显示文摘 | Zarins CK Arko FR Crabtree T | 2004 | Joumal of Vascular Surgery2004,40,1: | 1 |
| 10 | Aggressive percutaneous mechanical thrombectomy of deep venous thrombosis:early clinical results显示文摘 | Arko FR Davis CM 3rd Murphy EH | 2007 | Arch Surg2007,142,6: | 1 |
| 11 | Management of a chronic carotid artery pseudoaneurysm 显示文摘 | Baker AC Arko FR 3rd Zarins CK et at | 2010 | Vasc Endovascular Surg2010,44,1: | 1 |
| 12 | Sequence variations in the osteopretegerin gene promoter in patients with post- menopauzal osteoporesis显示文摘 | Arko B Prezelj J Komel R | 2002 | J Clin Endocrinol Metab2002,87,: | 1 |
| 13 | Scale to predict survival 'after surgery for recurrent glioblastoma multiforme 显示文摘 | Park JK Hodges T Arko L | 2010 | J Clin Oncol2010,28,24: | 1 |
| 14 | Quantification of vessel wall motion and cyclic strain using cine phase contrast MRI:in vivo validation in the porcine aorta显示文摘 | Draney MT Arko FR Alley MT | 2004 | Magn Reson Med2004,52,2: | 1 |
| 15 | Scale to predict survival after surgery for recurrent glioblastoma muhiforme 显示文摘 | Park JK Hodges T Arko L | 2010 | J Clin Oncol2010,28,24: | 1 |
| 16 | Texture-based classi cation of sub-Antarctic vegetation communities on Heard Island 显示文摘 | HUMPHREY M ARKO L RAYMOND W | 2010 | International Journal of Applied Earth Observation and Geoinformation2010,12,3: | 1 |
| 17 | Surgical management of mesenteric isch- emia显示文摘 | Karwowski J Arko F | 2004 | Tech Vasc Intcrv Radiol2004,7,3: | 1 |
| 18 | Immune evasion of tumor cell using membrane - bound complement regulatory proteins 显示文摘 | Arko Gorter Seppo Meri | 1999 | Immunology Today1999,20,12: | 1 |
| 19 | Preoperative diagnosis of fallopian tube malignancy with transvaginal color Doppler ultrasonography and magnetic resonance imaging after negative hysteroscopy for postmenopausal bleeding 显示文摘 | Arko D Zegura B Virag M | 2014 | Coll Antropol2014,38,3: | 1 |
| 20 | Animal chamber models for study of host-para- site interactions 显示文摘 | Genco CA Arko RJ | 1994 | Methods Enzymol1994,235,: | 1 |